1.
Org Lett
; 24(39): 7222-7226, 2022 Oct 07.
Article
in English
| MEDLINE
| ID: mdl-36169201
ABSTRACT
Under mechanochemically induced conditions, a wide range of diarylphosphine oxides or H-phosphonates react with trisulfide dioxides to afford various thiophosphate derivatives in good yields. Selective S-S bond cleavage of trisulfide dioxides determined by connecting groups is proposed as the key step in the construction of P(O)-S or P(O)-S-S bonds, which is supported by calculations.