Mildly Peeling Off and Encapsulating Large MXene Nanosheets with Rigid Biologic Fibrils for Synchronization of Solar Evaporation and Energy Harvest.

Efficient and nondestructive liquid exfoliation of MXene with large lateral size has drawn growing research interest due to its outstanding properties and diverse potential applications. The conventional sonication method, though enabling a high production yield of MXene nanosheets, broke them down into submicrometric sizes or even quantum dots, and thus sacrificed their size-dependent properties, chemical stability, and wide applications. Herein, rigid biological nanofibrils in combination of mild manual shake were found to be capable of peeling off MXene nanosheets by attaching on MXene surfaces and localizing the shear force. With comparison to sonication, this efficient and nondestructive exfoliation approach produced the MXene nanosheets with the lateral size up to 4-6 µm and a comparable yield of 64% within 2 h. The resultant MXene nanosheets were encapsulated with these biological fibrils, and thus enabled super colloidal and chemical stability. A steam generation efficiency of ∼86% and a high evaporation rate of 3.3 kg m-2 h-1 were achieved on their aerogels under 1-Sun irradiation at ∼25 °C. An evaporation rate of 0.5 kg m-2 h-1 still maintained even at the atmospheric temperature of -5 °C. More importantly, an electricity generation up to ∼350 mV also accompanied this solar evaporation under equivalent 5-Sun irradiation. Thus, this fibrous strategy not only provides an efficient and nondestructive exfoliation method of MXene, but also promises synchronization of solar-thermal evaporation and energy harvest.

Interfacial Electrochemical Polymerization for Spinning Liquid Metals into Core-Shell Wires.

Metal wires are of great significance in applications such as three-dimensional (3D) printing, soft electronics, optics, and metamaterials. Ga-based liquid metals (e.g., EGaIn), though uniquely combining metallic conductivity, fluidity, and biocompatibility, remain challenging to be spun due to their low viscosity, high surface tension, and Rayleigh-Plateau instability. In this work, we showed that EGaIn as a working electrode could induce the oxidization of EGaIn and interfacial electrochemical polymerization of electroactive monomers (e.g., acrylic acid, dopamine, and pyrrole), thus spinning itself from an opening of a blunt needle. During the spinning process, the high surface tension of EGaIn was reduced by electrowetting and electrocapillarity and stabilized by polymer shells (tunable thickness of ∼0.6-30 µm on wires with a diameter of 90-300 µm), which were chelated with metal ions. The polymeric shells offered EGaIn wires with an enhanced endurance to mechanical force and acidity. By further encapsulating into elastomers through a facile impregnation process, the resultant elastic EGaIn wires showed a combination of high stretchability (up to 800%) and metallic conductivity (1.5 × 106 S m-1). When serving as wearable sensors, they were capable of sensing facial expressions, body movements, voice recognition, and spatial pressure distributions with high sensitivity, good repeatability, and satisfactory durability. Machine-learning algorithms further assisted to detect gestures with high accuracy.