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Application of palladium-catalyzed allylic arylation to the synthesis of a (+/-)-7-deoxypancratistatin analogue.
Shukla, Krupa H; Boehmler, Debra J; Bogacyzk, Suzanne; Duvall, Bridget R; Peterson, William A; McElroy, William T; Deshong, Philip.
Org Lett ; 8(19): 4183-6, 2006 Sep 14.
Article in English | MEDLINE | ID: mdl-16956182

ABSTRACT

Palladium-catalyzed coupling of an aryl siloxane and an allylic carbonate proceeded in good yield to give an adduct that was converted to an analogue of (+/-)-7-deoxypancratistatin.


Subject(s)
Amaryllidaceae Alkaloids/chemical synthesis , Isoquinolines/chemical synthesis , Palladium/chemistry , Catalysis , Cyclization , Stereoisomerism
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