High entropy alloying strategy for accomplishing quintuple-nanoparticles grafted carbon towards exceptional high-performance overall seawater splitting.

High entropy alloys (HEAs), a novel class of material, have been explored in terms of their excellent mechanical properties. Seawater electrolysis is a step towards sustainable production of carbon-neutral fuels such as H2, O2, and industrially demanding Cl2. Herein, we report a practically viable FeCoNiMnCr HEA nanoparticles system grafted on a conductive carbon matrix for promising seawater electrolysis. The comprehensive kinetics analysis of the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and chlorine evolution reaction (CER) confirms the effectiveness of our system. As an electrocatalyst, HEAs grafted on carbon black show trifunctionality with promising kinetics, selectivity and enduring performance, towards seawater splitting. We optimize high entropy alloy decorated/grafted carbon black (HEACB) catalysts, studying their synthesis temperature to scrutinize the effect of alloy formation variation on the catalysis efficacy. During the catalysis, selectivity between two mutually competing reactions, CER and OER, in the electrochemical catalysis of seawater is controlled by the reaction media pH. We employ Mott-Schottky measurements to probe the band structure of the intrinsically induced metal-semiconductor junction in the HEACB catalyst, where the carrier density and flat band potential are optimized. The HEACB sample provides promising results towards overall seawater electrolysis with a net half-cell potential of about 1.65 V with good stability, which strongly implies its broad practical applicability.

FeCoNiMnCr High-Entropy Alloy Nanoparticle-Grafted NCNTs with Promising Performance in the Ohmic Polarization Region of Fuel Cells.

We report a user-friendly methodology for the successful designing of targeted single-phased face-centered cubic (fcc) FeCoNiMnCr high-entropy alloy (HEA) nanoparticle-grafted N-doped carbon nanotubes (CNTs). The nanostructure assimilates the advantages of N-doped carbon and HEA nanoparticles as a core for the efficient promotion of electrochemical oxygen reduction reaction (ORR). It emulates the commercial Pt-C electrocatalyst for ORR and shows promise for better performance in the Ohmic polarization region of fuel cells. In addition, it ensures superior efficacy over those of numerous recently reported transition metal-based traditional alloy composites for ORR. The presented methodology has the potential to pave the way for the effective designing of a variety of targeted HEA systems with ease, which is necessary to widen the domain of HEA for numerous applications.