Rapid Determination of Cr3+ and Mn2+ in Water Using Laser-Induced Breakdown Spectroscopy Combined with Filter Paper Modified with Gold Nanoclusters.

Excessive emissions of heavy metals not only cause environmental pollution but also pose a direct threat to human health. Therefore, rapid and accurate detection of heavy metals in the environment is of great significance. Herein, we propose a method based on laser-induced breakdown spectroscopy (LIBS) combined with filter paper modified with bovine serum albumin-protected gold nanoclusters (LIBS-FP-AuNCs) for the rapid and sensitive detection of Cr3+ and Mn2+. The filter paper modified with AuNCs was used to selectively enrich Cr3+ and Mn2+. Combined with the multi-element detection capability of LIBS, this method achieved the simultaneous rapid detection of Cr3+ and Mn2+. Both elements showed linear ranges for concentrations of 10-1000 µg L-1, with limits of detection of 7.5 and 9.0 µg L-1 for Cr3+ and Mn2+, respectively. This method was successfully applied to the determination of Cr3+ and Mn2+ in real water samples, with satisfactory recoveries ranging from 94.6% to 105.1%. This method has potential application in the analysis of heavy metal pollution.

Dual-wavelength dispersion characterization of confocal Fabry-Perot interferometers.

Optical resonators simultaneously resonating at different wavelengths are of interest in passive as well as active optical cavities. Dual-wavelength lasers, optical parametric amplifiers and spectrometers, e.g., in high spectral resolution lidar (HSRL) are effectively improved by employing multiply resonant cavities. In particular, HSRL allows us to measure aerosol optical properties without a priori hypotheses. Here we analyze optical dispersion in a HSRL prototype, based on a confocal Fabry-Perot interferometer (CFPI), developed to work at 532 nm (the lidar excitation wavelength). The presence of dispersion should be accounted for when realizing an effective HSRL because a second beam is required to obtain sufficient locking stability. We have performed an experiment in order to measure the dispersion contributions coming from cavity mirror coating and air and evaluate the stability of the transmission peaks in order to optimize the performances of HSRL.