Improving the quantification of secondary organic aerosol using a microflow reactor coupled to HPLC-MS and NMR to manufacture ad hoc calibration standards.

Secondary organic aerosol (SOA) is a key uncertainty in quantifying the impact of humans on Earth's climate. SOA is a complex mixture of oxidized organic species, and a fundamental hurdle in determining its composition is the lack of authentic standards for comparison and quantification. Organic synthesis can be used to produce pure standards, but is limited to compounds for which there is a degree of confidence in the proposed structure and can be expensive and time-consuming. In this study, a flow reactor was developed to form SOA in sufficient quantities to be collected and pure compounds subsequently isolated from the mixture using semipreparative high performance liquid chromatography. The purity and yield of each isolated compound were obtained using proton nuclear magnetic resonance ((1)H NMR), whereas molecular formulas were confirmed by high resolution Fourier transform ion cyclotron mass spectrometry (FTICR-MS). The effectiveness of the methodology has been evaluated here by using α-pinene as the precursor because it is the monoterpene with the most well characterized SOA chemistry. Eleven individual α-pinene SOA compounds were produced from α-pinene oxidation experiments and used for quantitative analysis of SOA formed during chamber experiments carried out close to ambient conditions. These compounds represented 25% of the total SOA mass, a significant improvement in mass balance compared to previous studies. This relatively simple approach may be extended to produce other SOA components not available commercially to improve quantification of aerosol sources.

The psychological contract: is the UK National Health Service a model employer?

The UK National Health Service (NHS) is facing recruitment challenges that mean it will need to become an 'employer of choice' if it is to continue to attract high-quality employees. This paper reports the findings from a study focusing on allied health professional staff (n = 67), aimed at establishing the expectations of the NHS inherent in their current psychological contract and to consider whether the government's drive to make the NHS a model employer meets those expectations. The findings show that the most important aspects of the psychological contract were relational and based on the investment made in the employment relationship by both parties. The employment relationship was one of high involvement but also one where transactional contract items, such as pay, were still of some importance. Although the degree of employee satisfaction with the relational content of the psychological contract was relatively positive, there was, nevertheless, a mismatch between levels of importance placed on such aspects of the contract and levels of satisfaction, with employees increasingly placing greater emphasis on those items the NHS is having the greatest difficulty providing. Despite this apparent disparity between employee expectation and the fulfilment of those expectations, the overall health of the psychological contract was still high.