ABSTRACT
Biomimetic human skinlike materials with preferably self-healing ability, high sensitivity for external stimuli, and good adhesiveness against diverse substrates under a wide range of temperatures are of great importance in various applications such as wearable devices, human-motion devices, and soft robotics. However, most of the reported biomimetic human skinlike materials lack memory function, i.e., they cannot memorize the external stimuli once the stimuli disappear. This drawback hinders their applications in mimicking the human skin in real world. Here, a polyacrylamide/Au@polydopamine glycerol-water (GW) hydrogel has been designed to address this challenge. The as-prepared GW hydrogel exhibits a fast self-healing efficiency and good adhesiveness against diverse substrates under a wide range of temperatures (from -15 to 37 °C). Additionally, our GW hydrogel also possesses good perceived ability for external stimuli and subtle/large human motions. Most importantly, resistance memory function has been realized based on our GW hydrogel. These outstanding properties make it potentially significant in mimicking the human skin in real world.
ABSTRACT
Many living tissues possess excellent mechanical properties and water retention which enable them to self-heal at room temperature even below the freezing temperature of water. To mimic the unique features of living tissue, a poly(acrylic acid-co-maleic acid) composite hydrogel with enhanced mechanical properties and remarkable water retention was fabricated under accessible conditions. The hydrogel is functionalized by amino group modified boron nitride nanosheets (BNNS-NH2)/glycerol and exhibits self-healing abilities at low temperature. The self-healing process occurs through the re-establishing of hydrogen bonds and metal coordination interactions at the damaged surfaces. Its anti-freezing abilities enable the hydrogel to self-heal at -15 °C, and the self-healing efficiency based on tensile strength reaches up to â¼70%. Moreover, glycerol also endows the hydrogel with long-lasting water retention, which remains a water content of â¼99 wt% for more than 30 days. Meanwhile, the simultaneous introduction of BNNS-NH2 and glycerol significantly improved the mechanical properties of the hydrogel, which displays great stretchability (â¼474%), tensile strength (â¼151.3 kPa), stiffness (Young's modulus of â¼62.75 kPa) and toughness (â¼355.13 kJ m-3). It is anticipated that these novel hydrogels will develop many fields and be exploited for new applications in extensive external environments.