Construction of 2D/2D ZnIn2S4/Nb2CTx (MXene) hybrid with hole transport highway and active facet exposure boost photocatalytic hydrogen evolution.

In this study, leveraging the tunable surface groups of MXene, the two-dimensional (2D) Nb2CTx with OH terminal (NC) was synthesized. 2D ZnIn2S4 (ZIS) nanosheets were prepared with the aid of sodium citrate, enhancing the exposure ratio of active (110) facet. On this basis, 2D/2D ZnIn2S4/Nb2CTx heterojunctions were fabricated to improve photocatalytic hydrogen evolution reaction (HER) performance. The optimized 6 wt%Nb2CTx/ZnIn2S4-450 (6NC/ZIS-450) photocatalyt exhibits a remarkable HER rate of 3603 µmol g-1h-1, which is 10 times superior to that of the original ZnIn2S4. Its apparent quantum efficiency (AQE) at 380 nm reaches 14.9 %. Meanwhile, even after 5 rounds of HER, the activity of 2D/2D ZnIn2S4/Nb2CTx heterojunction remained at 90 %, far superior to that of pure ZnIn2S4 (34 % and 31 %). Energy band structure analysis and density functional theory (DFT) calculation indicate that Nb2CTx adsorbed with OH exhibit a low work function. By serving as a hole cocatalyst, it effectively boosts the photocatalytic HER rate of ZnIn2S4/Nb2CTx heterojunction and inhibits the photocorrosion of ZnIn2S4. This unique insight, via hole transport highways and increased exposure of active facets, effectively enhances the activity and stability of sulfides photocatalysts.

Quantitative detecting low concentration polystyrene nanoplastics in aquatic environments via an Ag/Nb2CTx (MXene) SERS substrate.

In this study, the plasmonic Ag nanoparticles (Ag NPs) were uniformly anchored on the high conductivity Nb2CTx (MXene) nanosheets to construct an Ag/Nb2CTx substrate for surface-enhanced Raman spectroscopy (SERS) detection of polystyrene (PS) nanoplastics. The KI addition (0.15 mol/L), the volume ratio between substrate colloid and nanoplastic suspension (2:1), and the mass ratio of Nb2CTx in substrate (14%) on SERS performance were optimized. The EM hot spots of Ag/Nb2CTx are significantly enlarged and enhanced, elucidated by FDFD simulation. Then, the linear relationship between the PS nanoplastics concentration with three different sizes (50, 300, and 500 nm) and the SERS intensity was obtained (R2 > 0.976), wherein, the detection limit was as low as 10-4 mg/mL for PS nanoplastic. Owing to the fingerprint feature, the Ag/Nb2CTx-14% substrate successfully discerns the mixtures from two-component nanoplastics. Meanwhile, it exhibits excellent stability of PS nanoplastics on different detection sites. The recovery rates of PS nanoplastics with different sizes in lake water ranged from 94.74% to 107.29%, with the relative standard deviation (RSD) ranging from 2.88% to 8.30%. Based on this method, the expanded polystyrene (EPS) decomposition behavior was evaluated, and the PS concentrations in four water environments were analyzed. This work will pave the way for the accurate quantitative detection of low concentration of nanoplastics in aquatic environments.

Room-temperature highly sensitive triethylamine detection by few-layer Nb2CTxMXene nanosheets.

MXene, a class of two-dimensional materials that are emerging as rising stars in the field of materials, are receiving much attention in sensing. Ti3C2TxMXene, the most maturely researched MXene, is widely used in energy, biomedical, laser, and microwave shielding applications and has also been expanded to gas sensing and wearable electronics applications. Compared with Ti3C2Tx, Nb2CTxMXene is more difficult to etch and has higher resistances at room temperature; so, few studies have been reported on their use in the sensing field. Based on the preparation of few-layer Nb2CTxMXene by intercalation, this study thoroughly examined their gas-sensing properties. The successfully prepared few-layer Nb2CTxshowed good selectivity and high sensitivity to triethylamine at room temperature, with response values up to 47.2% for 50 ppm triethylamine and short response/recovery time (22/20 s). This study opens an important path for the design of novel Nb-based MXene sensors for triethylamine gas detection.

MXene-based polysaccharide aerogel with multifunctional enduring antimicrobial effects for infected wound healing.

Wound infection is a predominant etiological factor contributing to delayed wound healing in open wounds. Hence, it holds paramount clinical significance to devise wound dressings endowed with superior antibacterial properties. In this study, a Schiff base-crosslinked aerogel comprising sodium alginate oxide (OSA), carboxymethyl chitosan (CMCS), and Nb2C@Ag/PDA (NAP) was developed. The resultant OSA/CMCS-Nb2C@Ag/PDA (OC/NAP) composite aerogel exhibited commendable attributes including exceptional swelling characteristics, porosity, biocompatibility, and sustained antimicrobial efficacy. In vitro antimicrobial assays unequivocally demonstrated that the OC/NAP composite aerogel maintained nearly 100 % inhibition of Staphylococcus aureus and Escherichia coli under an 808 nm laser even after 25 h. Crucially, the outcomes of in vivo infected wound healing experiments demonstrated that the wound healing rate of the OC/NAP composite aerogel group reached approximately 100 % within a span of 14 days, which was significantly greater than that of the blank control group. In vitro and in vivo hemostatic experiments also revealed that the composite aerogel had excellent hemostatic properties. The results of this study demonstrate the remarkable potential of OC/NAP aerogel as a multifunctional clinical wound dressing, especially for infected wounds.

Endogenous Nb2CTx/Nb2O5 Schottky heterostructures for superior lithium-ion storage.

Schottky heterostructures have significant advantages for exciting charge transfer kinetics at material interfaces. In this work, endogenous Nb2CTx/Nb2O5 Schottky heterostructures with a large active surface area were constructed using an in-situ architectural strategy. The semiconductor Nb2O5 has a low work function, and during the construction of Nb2CTx/Nb2O5 Schottky heterostructures, there was an interfacial electron transfer, which resulted in a built-in electric field. The electrochemical reaction kinetics of Nb2CTx/Nb2O5 Schottky heterostructures were enhanced due to the rapid transfer of charge driven by the electric field. The Nb2CTx/Nb2O5 Schottky heterostructures have a large active surface area, which contributes to excellent electrolyte diffusion kinetics. Therefore, Nb2CTx/Nb2O5 Schottky heterostructures have excellent lithium-ion storage capacity with 575 mAh/g after 200 cycles at 0.10 A/g, and 290 mAh/g after 1000 cycles at 2.00 A/g, without capacity fading. Furthermore, in-situ X-ray diffraction and ex-situ X-ray photoelectron spectroscopy analyses reveal the mechanisms for structure evolution and lithium-ion storage optimization of Nb2CTx/Nb2O5 Schottky heterostructures during the electrochemical reaction. The construction of Schottky heterostructures with excited charge transport kinetics provides a novel idea for optimizing the lithium-ion storage activity of MXenes materials.

In-situ growth of SnO2 nanoparticles on Nb2CTx nanosheets as highly sensitive electrochemical sensing platform for organophosphorus pesticide detection.

In this study, the SnO2/Nb2CTx MXene nanocomposite containing 0D/2D interfaces was prepared by situ growth strategy of one-step hydrothermal method. A SnO2/Nb2CTx MXene based acetylcholinesterase (AChE) biosensor was constructed for pesticide detection. Highly conductive Nb2CTx MXene, acting as substrate material, restrained the agglomeration of nanoparticles (NPs) and accelerated electron migration due to the confinement effect and well-known accordion-like layered structure. In addition, SnO2 anchored on both sides of the Nb2CTx MXene nanosheets effectively provided a large surface area, abundant surface groups and active sites, which preserved numbers of electrons at the interface of the heterojunction. The SnO2/Nb2CTx MXene hybrids with outstanding conductivity, good biocompatibility and structural stability were beneficial for AChE immobilization. Under the optimized conditions, as-fabricated electrochemical biosensor demonstrated superior performance with linear detection range of 5.1 × 10-14 - 5.1 × 10-7 M for chlorpyrifos, along with the limit of detection (LOD) down to 5.1 × 10-14 M (calculated for 10% inhibition). Furthermore, it is highly expected that this biosensor can be applied for the detection of other organophosphorus pesticides in the environment, providing an effective nanoplatform in biosensing field.

Nb2 CTx MXene Derived Polymorphic Nb2 O5.

Previously, heat treatment was the only feasible route for tuning the crystal phases of niobium pentoxide (Nb2 O5 ). With the use of Nb2 CTx MXene precursors, the first case of phase tuning of Nb2 O5 in the low-temperature hydrothermal synthesis using sulfuric acid regulating agents is presented. By varying the amount of the agent, four pure-phase Nb2 O5 crystals and mixed phases in-between are obtained. The required amount is found to be related to the H-covered surface energy calculated based on density functional theory. Overall, MXene-derived B-phase Nb2 O5 is of particular interest due to its exceptionally high capacities as lithium-ion battery anodes, which are three times higher than the routine synthesized one. Oxygen vacancies induced by crystallographic shear would be responsible for the extraordinary performance. The proposed phase tuning strategy encourages the prudent synthesis of difficult-to-obtain crystal phases.

In-situ decoration of tin sulfide on Niobium carbide MXene with robust electronic coupling for improved sodium storage performance.

Tin sulfide (SnS) has been considered as one of the most promising sodium storage materials because of its excellent electrochemical activity, low cost, and low-dimensional structure. However, owing to the serious volume change upon discharging/charging and poor electronic conductivity, the SnS-based electrodes often suffer from electrode pulverization and sluggish reaction kinetics, thus resulting in serious capacity fading and degraded rate capability. In this work, SnS nanoparticles uniformly distributed on the surface of the layered Niobium carbide MXene (SnS/Nb2CTx) were fabricated through a facile solvothermal approach followed by calcination, endowing the SnS/Nb2CTx with a three-dimensional interconnected framework as well as fast charge transfer. Benefitting from the excellent electronic/ionic conductivity, efficient buffering matrix, abundant active sites, and high sodium storage activity inherited from the structure design, the robust electronic coupling between SnS nanoparticle and Nb2CTx MXene results in excellent electrochemical output, which demonstrates superior reversible capacities of 479.6 (0.1 A/g up to 100 cycles) and 278.9 mAh/g (0.5 A/g up to 500 cycles) upon sodium storage, respectively. The excellent electrochemical performance manifests the promise of the combination of metal sulfides with Nb2CTx MXene to fabricate high-performance electrodes for sodium storage.

Synergy of copper Selenide/MXenes composite with enhanced solar-driven water evaporation and seawater desalination.

Despite significant of solar energy to power water evaporation in seawater desalination, the commercial application of this technology is limited by the poor light absorption and low photothermal conversion of existing photothermal materials. Herein, we report a simple method for solar-driven water evaporation using a device comprising Cu2-xSe/Nb2CTx nanocomposites supported by a glass microfiber membrane, which utilizes cotton thread as water transport pathway. The proposed device demonstrates excellent light absorption, water transportation, and thermal management. Benefiting from the strong synergetic photothermal effect of Cu2-xSe and Nb2CTx, the Cu2-xSe/Nb2CTx nanocomposites function as an efficient solar absorber with excellent photothermal conversion efficiency. The rough surface, low thermal conductivity and good hydrophilicity of glass microfiber membrane could maximize light capture, limit heat loss, and timely replenish water during the water evaporation process. When evaluated as a water evaporation system for outdoor seawater desalination, the system achieved a water evaporation of 12.60 kg·m-2 within 6 h. High fresh water generation rate is an important embodiment of high photothermal conversion efficiency. This study demonstrates a new route for designing solar desalination devices with high photothermal conversion properties.

Charge controlled capture/release of CH4 on Nb2CTx MXene: A first-principles calculation.

Methane is not only the main cause of coal mine accidents but also a contributor to global warming, meanwhile, it is clean energy. It is necessary to find an advanced material which can capture methane efficiently for its utilization. In this paper, the adsorption of CH4 gas molecules on Nb2CTx(T = O, F, Cl, OH) is studied by first-principles calculation. The results indicate that the adsorption of CH4 on Nb2CTx(T = O, F, Cl, OH) is weak, and the adsorption of CH4 on Nb2C(OH)2 is the best. The calculation results of binding energy and cohesive energy show that Nb2CO2 has the best stability. The adsorption behavior of CH4 on Nb2CO2 under charge control is further studied. With the increase of negative charge state in the system, the adsorption of CH4 on Nb2CO2 is significantly enhanced, from physical adsorption to chemical adsorption; when the charge state of the system is greater than or equal to -2, Nb2CO2 can capture CH4 effectively, and the charges transferred from Nb2CO2 to CH4 mainly come from Nb atom. After the removal of the extra charge, the adsorption of CH4 on Nb2CO2 becomes weak and returns to physical adsorption state; CH4 gas molecules are easy to desorb. Therefore, Nb2CO2 can capture and release CH4 molecules by regulating the charge state of Nb2CO2, and Nb2CO2 is expected to become an excellent candidate material for CH4 capture/release.

Theoretical and experimental investigations on Nb2CTxMXene Q-switched Tm:YAP laser at 2µm for the nonlinear optical response.

In this paper, the Nb2CTxMXene nanosheets were fabricated and the corresponding microstructures were investigated. The nonlinear optical response was illustrated by open aperture Z-scan and I-scan methods. The ground and the excited state absorption cross-sections of 2D Nb2CTxMXene were also investigated. As the saturable absorber (SA), the Nb2CTxMXene was applied in the passively Q-switched Tm:YAP laser. 1.96µs Q-switched pulses with 3.97 W peak power were achieved at the repetition frequency of 80 kHz. Further theoretical model was built by using the coupled rate equations in simulating the dynamic process of the passively Q-switched Tm:YAP laser. The numerical simulation results are fundamentally in agreement with the experimental results, which proves the Nb2CTxMXene can be a good potential nanomaterial for further optoelectronic applications.

Facile hydrothermal synthesis of rod-like Nb2O5/Nb2CTx composites for visible-light driven photocatalytic degradation of organic pollutants.

The MXene-based transition metal oxide composite is a potential candidate for photocatalysts. Rod-like pseudohexagonal phase Nb2O5/Nb2CTx composites were synthesized by a simple hydrothermal oxidation of 2D layered Nb2CTx. The Nb2O5/Nb2CTx composites show superior photocatalytic activity for 98.5% of degradation of Rhodamine B (RhB) for 120 min and 91.2% of tetracycline hydrochloride (TC-HCl) for 180 min under visible light irradiation. The Schottky junction is formed between Nb2O5 nanorods and Nb2CTx and the photo-generated carriers are effectively separated, enhancing the photocatalytic activity of the Nb2O5/Nb2CTx. High photoactivity and cycle stability of Nb2O5/Nb2CTx composites indicate that hydrothermal oxidation of 2D layered Nb2CTx is an alternative to prepare efficient photocatalyst for degradation of organic pollutants.

Ultra-efficient electromagnetic wave absorption with ethanol-thermally treated two-dimensional Nb2CTx nanosheets.

Nb2CTx, an emerging type of MXene, should be a promising electromagnetic wave (EMW) absorbing material to overcome the EMW pollution nowadays due to its unique layered structure and extremely thin monolayer thickness, but was lack of systematic study till now. Meanwhile, Nb2CTx nanosheets obtained upon HF etching of Nb2AlC MAX was unfortunately found with limited absorption performance due to its mainly dielectric loss mechanism herein. Therefore, the Nb2CTx nanosheets were further treated with solvothermal strategy in various solvents. As a result, the absorption performance of the as-treated Nb2CTx nanosheets could be significantly improved, while the ones in ethanol showed much more superior absorption capability, especially in the low-frequency band (2.0-4.0 GHz). The minimum reflection loss value could reach -52.2 dB at 3.93 GHz with the thickness of only 2.90 mm, indicating more than 99.999% EMW was absorbed. These should be due to the multi-loss mechanism including dielectric, interfacial, and multiple reflection ones resulting from the enlarged interlayer spacing, and increased surface functional groups on the Nb2CTx nanosheets upon the ethanol-based solvothermal treatment.