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1.
Nanotechnology ; 35(17)2024 Feb 05.
Article in English | MEDLINE | ID: mdl-38181437

ABSTRACT

Development of bulk acoustic wave filters with ultra-wide pass bands and operating at high frequencies for 5thand 6thgeneration telecommunication applications and micro-scale actuators, energy harvesters and sensors requires lead-free piezoelectric thin films with high electromechanical coupling and compatible with Si technology. In this paper, the epitaxial growth of 36°Y-X and 30°X-Y LiNbO3films by direct liquid injection chemical vapour deposition on Si substrates by using epitaxial SrTiO3layers, grown by molecular beam epitaxy, has been demonstrated. The stability of the interfaces and chemical interactions between SrTiO3, LiNbO3and Si were studied experimentally and by thermodynamical calculations. The experimental conditions for pure 36°Y-X orientation growth have been optimized. The piezoelectricity of epitaxial 36°Y-X LiNbO3/SrTiO3/Si films was confirmed by means of piezoelectric force microscopy measurements and the ferroelectric domain inversion was attained at 85 kV.cm-1as expected for the nearly stoichiometric LiNbO3. According to the theoretical calculations, 36°Y-X LiNbO3films on Si could offer an electromechanical coupling of 24.4% for thickness extension excitation of bulk acoustic waves and a comparable figure of merit of actuators and vibrational energy harvesters to that of standard PbZr1-xTixO3films.

2.
Macromol Rapid Commun ; 44(2): e2200586, 2023 Jan.
Article in English | MEDLINE | ID: mdl-36107158

ABSTRACT

Orthogonal photoreactions provide a unique way to locally and independently control (thermo)mechanical properties and functionality of polymer networks simply by choice of the wavelength. Herein, a library of acrylate functional coumarin monomers is synthesized, which are cured by sequence-dependent wavelength orthogonality. In the presence of a long wavelength absorbing photoinitiator, the monomers undergo rapid curing by visible light induced radical chain growth polymerization. Subsequent irradiation with light in the UV-A region selectively initiates the [2+2] photocycloaddition of the coumarin chromophores, which is confirmed by FTIR and UV-vis experiments. Through a well-targeted design, acrylate-based and thiol-acrylate resin formulations are prepared, whose fast curing rate, low viscosity, and prolonged storage stability enable the one-step fabrication of multi-material structures by digital light processing (DLP) 3D printing. By using a dual-wavelength printer, which operates at two different wavelengths (405 and 365 nm), objects comprising soft (ε = 22%, σ = 7.5 MPa) and stiff (ε = 2%, σ = 8.3 MPa) domains are printed with a single resin vat. Along with tensile properties, the wavelength selective change in the network structure features a local control of the glass transition temperature (ΔTg  = 17 °C) in the 3D-printed objects. Soft active devices are fabricated by dual-wavelength DLP 3D printing, with distinct domains having a higher Tg and the local programming of multi shapes is demonstrated.


Subject(s)
Acrylates , Printing, Three-Dimensional , Drug Compounding , Polymers
3.
J Phys Condens Matter ; 34(26)2022 Apr 28.
Article in English | MEDLINE | ID: mdl-35390773

ABSTRACT

Surface plasmon polaritons (SPPs) are interactions between incident electromagnetic waves and free electrons on the metal-dielectric interface in the optical regime. To mimic SPPs in the microwave frequency, spoof SPPs (SSPPs) on ultrathin and flexible corrugated metallic strips were proposed and designed, which also inherit the advantages of lightweight, conformal, low profile, and easy integration with the traditional microwave circuits. In this paper, we review the recent development of SSPPs, including the basic concept, design principle, and applications along with the development from unwieldy waveguides to ultrathin transmission lines. The design schemes from passive and active devices to SSPP systems are presented respectively. For the passive SSPP devices, the related applications including filters, splitters, combiners, couplers, topological SSPPs, and radiations introduced. For the active SSPP devices, from the perspectives of transmission and radiation, we present a series of active SSPP devices with diversity and flexibility, including filtering, amplification, attenuation, nonlinearity, and leaky-wave radiations. Finally, several microwave systems based on SSPPs are reported, showing their unique advantages. The future directions and potential applications of the ultra-thin SSPP structures in the microwave and millimeter-wave regions are discussed.

4.
Magn Reson Med ; 85(5): 2904-2914, 2021 05.
Article in English | MEDLINE | ID: mdl-33347642

ABSTRACT

PURPOSE: This work aims to demonstrate the use of an "active" acousto-optic marker with enhanced visibility and reduced radiofrequency (RF) -induced heating for interventional MRI. METHODS: The acousto-optic marker was fabricated using bulk piezoelectric crystal and π-phase shifted fiber Bragg grating (FBGs) and coupled to a distal receiver coil on an 8F catheter. The received MR signal is transmitted over an optical fiber to mitigate RF-induced heating. A photodetector converts the optical signal into electrical signal, which is used as the input signal to the MRI receiver plug. Acousto-optic markers were characterized in phantom studies. RF-induced heating risk was evaluated according to ASTM 2182 standard. In vivo real-time tracking capability was tested in an animal model under a 0.55T scanner. RESULTS: Signal-to-noise ratio (SNR) levels suitable for real-time tracking were obtained by using high sensitivity FBG and piezoelectric transducer with resonance matched to Larmor frequency. Single and multiple marker coils integrated to 8F catheters were readout for position and orientation tracking by a single acousto-optic sensor. RF-induced heating was significantly reduced compared to a coax cable connected reference marker. Real-time distal tip tracking of an active device was demonstrated in an animal model with a standard real-time cardiac MR sequence. CONCLUSION: Acousto-optic markers provide sufficient SNR with a simple structure for real-time device tracking. RF-induced heating is significantly reduced compared to conventional active markers. Also, multiple RF receiver coils connected on an acousto-optic modulator can be used on a single catheter for determining catheter orientation and shape.


Subject(s)
Magnetic Resonance Imaging, Interventional , Magnetic Resonance Imaging , Animals , Catheters , Equipment Design , Phantoms, Imaging
5.
Eur Radiol ; 30(5): 2571-2582, 2020 May.
Article in English | MEDLINE | ID: mdl-31974690

ABSTRACT

OBJECTIVES: Radio frequency (RF) pulses in magnetic resonance imaging (MRI) can interact with implanted devices and cause tissue damage. However, there are new devices that can safely perform measurements with liberal MRI conditions such as an RF transmission field B1+rms ≤ 2.0 µT. We investigated whether MRI in this case is limited for these technical reasons. METHODS: We selected typical MRI protocols of six body regions (brain, cervical spine, lumbar spine, knee, liver, heart) using two typical 1.5T MRI scanners. Overall, we adapted 62 sequences to B1+rms conditions and evaluated their diagnostic quality. For this, we measured signal-to-noise-ratio (SNR), contrast-to-noise-ratio (CNR), and geometric deviation (GD) as quality parameters, using phantom studies. For questionnaire studies, we selected pairs of original and adapted sequences in healthy volunteers. Blinded radiologists rated the images as single sequence rating and in direct comparison. RESULTS: Roughly one-third of the checked sequences were below the B1+rms limit. Here, 56 of the 62 adapted sequences showed at least the same image quality in single ratings. A reduction in SNR and/or CNR was found with 31 sequences and only one sequence with considerably increased GD. Especially, sequences with original high B1+rms values, PD sequences, and sequences of the Siemens knee and heart protocol were difficult to adapt, whereas most TSE and IR sequences had no clinical limitations. CONCLUSION: By limiting the transmission field to B1+rms ≤ 2.0 µT, clinically relevant MR sequences can be adapted with nearly no reduction in image quality. Despite limiting the transmission field, high-quality MR imaging is possible. We could derive strategies for adaptation. KEY POINTS: • Despite limiting the transmission field, high-quality MRI is possible. • We could derive strategies for adapting the sequences to B1+rms≤ 2.0 µT. • This enables high-quality MRI of different body regions for patients with AD.


Subject(s)
Brain/diagnostic imaging , Liver/diagnostic imaging , Lumbar Vertebrae/diagnostic imaging , Magnetic Resonance Imaging/methods , Phantoms, Imaging , Prostheses and Implants , Radio Waves , Healthy Volunteers , Humans
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