What lies underneath: Comparison among beach litter in the underwater bathing area and exposed beach.

The standard techniques for monitoring beach litter focus on the litter that is accumulated on beaches. Therefore, the underwater bathing area is usually overlooked. Our study aims to start the discussion about the litter in the bathing area, an important connection between the exposed beach and the ocean. We aimed to compare sampling methodologies between the underwater bathing area and the exposed beach. We highlighted litter's similarities and differences regarding the amount, material, possible sources, and interaction with the biota. We also performed a brand audit on the underwater bathing area litter. In the underwater region, 106 items were collected while 1706 items were collected from the exposed beach region. Plastic was the dominant type of material in both sites, exposed beach (89.92 %) and bathing area (83.96 %). The litter's possible source was different. In the underwater bathing area was more related to food packages (couscous, rice). On the other hand, litter on the exposed beach was associated with beach use (single-use plastic such as plastic cups). The brand audit identified 21 companies, whereby most brands were Brazilian and food-related. Regarding interactions with the biota, the litter in the bathing area had more bio-fouling (87.73 %) than the litter collected on the exposed beach (10.00 %). Information about bathing area litter can be useful to draw different management strategies. Due to the differences in litter types and behavior between the two sites, the same mitigation strategies might not be equally efficient.

Coastal plastic pollution: A global perspective.

Coastal ecosystems have ecological importance worldwide and require control and prevention measures to mitigate human pollution. The objective of this study was to perform a systematic review to provide a comprehensive overview of the global issue of coastal plastic pollution. 689 articles were eligible for qualitative synthesis and 31 were considered for quantitative analysis. There was an exponential increase in articles addressing coastal plastic pollution over the past 50 years. Studies were mainly carried out on beaches, and plastic bottles were the most found item, followed by cigarette butts. Polyethylene was the predominant plastic polymer, and white microplastic fragments stood out. China published most articles on the topic and Brazil had the highest number of sites sampled. Meta-analysis had significant effect sizes based on the reported data. These findings carry significant implications for environmental policies, waste management practices, and targeted awareness campaigns aimed at mitigating plastic pollution.

How natural and anthropogenic factors should drive microplastic behavior and fate: The scenario of Brazilian urban freshwater.

Brazil maintains its position at the top of the global ranking of plastic producers, yet recycling efforts have been incipient. Recent data reveals an annual production of approximately 14 million tons of plastic waste, not accounting for the surge in the usage of plastic masks and related materials due to the COVID-19 pandemic. However, what remains largely unreported is that over half of post-consumer plastic packaging in Brazil is managed without any monitoring, and it remains unclear how this will contribute to the occurrence of plastic waste and microplastics in Brazilian freshwaters. This scenario requires the consideration of several other crucial factors. Studies have been carried out mainly in marine and estuarine waters, while data on freshwaters are lacking. Brazil has continental dimensions and the highest water availability on the planet, yet the demand for water is greatest in regions with medium to low supply. Many densely populated Brazilian urban areas face chronic flood problems, possess inadequate levels of wastewater treatment, and display inadequate solid waste management practices. Consequently, urban freshwater with tropical characteristics in Brazil presents an intriguing scenario and is complementary to the most commonly studied marine environments. In this study, we explore the nuances of pollution in Brazilian urban freshwater and discuss how various parameters, such as organic matter, suspended solids, temperature, and pH, among others, influence the behavior of microplastics and their interactions with organic and inorganic contaminants. Furthermore, we address how microplastic conditions, such as biofouling, the type of plastic, or degradation level, may impact their behavior. By analyzing how these conditions change, we propose priority themes for investigating the occurrence of microplastics in Brazilian urban freshwater systems under different degrees of human impact. Ultimately, this study aims to establish a network dedicated to standardized monitoring of microplastic pollution in Brazilian urban freshwaters.

Sustainable energy and waste management: How to transform plastic waste into carbon nanostructures for electrochemical supercapacitors.

Plastic waste consumption increases exponentially every year, mainly in the last three years due to the COVID-19 pandemic. The rapid growth of plastic products has exceeded the world's capacity to deal with this type of trash. Thus, it has become a substantial environmental concern in modern society. Another dire concern is the improper disposal of used supercapacitors, leading to serious environmental impacts. Consequently, critical action to tackle this issue is to transform trash into high-valued materials, such as carbon nanomaterial supercapacitors. Considering several methodologies of recycling, pyrolysis stands out due to its simplicity and easy handling of mixed plastic waste to produce carbonaceous materials with different dimensions (0, 1, 2, and 3D). Thus, from this technology, it is possible to create new opportunities for using plastic waste and other types of waste to produce cheaper carbon-based materials for supercapacitors. This review aims to provide readers with a sustainability-driven view regarding the reutilization of plastic trash, discusses the environmental consequences of not doing so, and shows plastic waste solutions. Despite the broad scope of the topic, this review focuses on identifying the currently studied strategies to convert plastic waste into carbon-based electrodes, using less expensive and more efficient competitive protocols, besides emphasizing the diverse types (0, 1, 2, and 3D) of nanostructures. This review also proposes promising options for a sustainable cycle of plastic waste and supercapacitor.

A multi-jurisdictional study on the quantification of COVID-19 household plastic waste in six Latin American countries.

This study examines urban plastic waste generation using a citizen science approach in six Latin American countries during a global pandemic. The objectives are to quantify generation rates of masks, gloves, face shields, and plastic bags in urban households using online survey and perform a systematic cross-jurisdiction comparisons in these Latin American countries. The per capita total mask generation rates ranged from 0.179 to 0.915 mask cap-1 day-1. A negative correlation between the use of gloves and masks is observed. Using the average values, the approximate proportion of masks, gloves, shields, and single-use plastic bags was 34:5:1:84. We found that most studies overestimated face mask disposal rate in Latin America due to the simplifying assumptions on the number of masks discarded per person, masking prevalence rate, and average mask weight. Unlike other studies, end-of-life PPE quantities were directly counted and reported by the survey participants. Both of the conventional weight-based estimates and the proposed participatory survey are recommended in quantifying COVID waste. Participant' perception based on the Likert scale is generally consistent with the waste amount generated. Waste policy and regulation appear to be important in daily waste generation rate. The results highlight the importance of using measured data in waste estimates.

Characteristics and fluxes of plastic debris based on socio-economic data for Patos Lagoon-a choked coastal Lagoon in South Brazil.

Patos Lagoon, located in southern Brazil, is the world's largest choked coastal lagoon. Studies have revealed that plastic pollution affects lagoons; however, to date, they have only focused on a few limited regions of the lagoon. Top-down quantification methods based on socio-economic data from 2010 to 2017 were used to measure the amount of plastic reaching Patos Lagoon, thus broadening the perspective of plastic pollution in this area. According to the findings, Patos Lagoon's hydrographic regions produced an average of 4.54 Mton of plastic during the studied period. 1.86 Mton was consumed on average. High- and low-density polyethylene (HDPE and LDPE, respectively), polypropylene (PP), and polyvinyl chloride (PVC) were the main resins produced. Food-related activities were the largest consumer of plastic (17.98%), indicating a higher amount of single-use plastics being used in the basin. The preforms for plastic bottles, bags, and packaging were the most commonly manufactured plastic utensils. An estimated 8 to 14% of all plastics used to end up as mismanaged waste in the Patos Lagoon hydrographic basin. This resulted in 1.73 and 10.72 Kton, or 0.5 and 3.2 g/per person/per day, of plastic waste flowing into the waters of Patos Lagoon throughout the study period. These findings can help focus on management efforts by providing managers and policymakers with information for better plastic pollution mitigation in this environment.

Study of Metakaolinite Geopolymeric Mortar with Plastic Waste Replacing the Sand: Effects on the Mechanical Properties, Microstructure, and Efflorescence.

In this study, the production of a mortar was proposed in which plastic waste replaced sand by 0%, 50%, and 100% in order to create a sustainable alternative for construction. The performance of the mortars was tested with two types of activators, one with NaOH, as a simple activator, and the other with NaOH and Na2SiO3, as a compound activator. The effects of the LDPE plastic bag waste and the activators on compressive strength, porosity, microstructure analysis, and efflorescence formation were correlated and discussed. The results showed that the replacement of sand with plastic waste at 50% and 100% proportionally reduced the compressive strength due to the increase in porosity caused by the waste, especially in the group of mortars with the simple activator, and included the formation of efflorescence. On the other hand, the compound activator increased the packing of the particles in the mortar, as observed in the images of the microstructure. This reduced porosity inhibited efflorescence and resulted in higher resistances that reached a maximum value of 22.68 MPa at 28 days in the group of 50% mortars with the compound activator. Therefore, the study showed that there is potential for the replacement of sand with plastic waste for the production of mortars, which can be considered a more sustainable building material.

Beneficios ambientales del reciclaje de residuos plásticos posconsumo para la producción de postes en Mendoza, Argentina / Environmental benefits of recycling: A case study on post-consumer plastic waste to produce poles in Mendoza, Argentina

RESUMEN Argentina, se encuentra entre los países de Latinoamérica con el mayor consumo de plásticos por habitante, con un valor de 42 kg, por año. El reciclaje mecánico de plástico, se presenta como una estrategia para recuperar los residuos y, de esta manera, evitar el uso de materia prima virgen, contribuyendo en la reducción de emisiones de gases de efecto invernadero. El objetivo de este trabajo es evaluar el desempeño ambiental del reciclaje de plástico para la elaboración de postes en Mendoza, Argentina. En la evaluación, se utilizó el indicador tasa de beneficio de la reciclabilidad, adaptado para ciclo abierto y para su cálculo, se utilizaron los resultados del análisis de ciclo de vida de dos escenarios (vertedero y reciclaje). El valor del indicador resultó, para este caso de estudio, en 22 %. Este resultado positivo indica un ahorro ambiental de reciclar residuos plásticos posconsumo con respecto a la producción del producto, a partir de materia prima virgen (madera) y la disposición final de los residuos plásticos en el vertedero. Posteriormente, se realizó un análisis de sensibilidad, para el parámetro del indicador que considera la vida útil de los productos y los resultados mostraron la necesidad de evitar su suposición, mediante su correcta determinación, con base a aspectos técnicos, económicos o de la calidad.

ABSTRACT Argentina is one of the largest consumers of plastic materials in Latin America; the average consumption is 42 kg per capita per year. Mechanical recycling of plastics is a process for recovering plastic materials, and this practice produces recycled plastics substituting virgin materials. Substituting virgin materials with recycling plastics is a common practice that contributes to reducing greenhouse gas emissions. This work aims to assess the environmental performance of a case study on plastic waste recycling in Mendoza, Argentina. We applied the open-loop recyclability benefit rate indicator in the plastic waste treatment, which is based on an LCA approach. The indicator results in 22 %, this result indicates a potential environmental saving related to the recycling of the post-consumer plastic waste compared to the production of virgin material (wood) and landfilling of waste in terms of GHG emissions. Furthermore, a sensitivity analysis was performed to study the effect of the parameter that considers the lifetime of the products. There is a need to account for the lifetime of the product made from recycled material and the one made from virgin material. The accounting could be determined based on economic aspects, technical aspects, or material quality.

The emerging risk of microplastics and nanoplastics on the microstructure and function of reproductive organs in mammals: A systematic review of preclinical evidence.

AIMS: Plastic particles (PP) pollution is a global environmental concern. Although the reproductive toxicity of PP is primarily understood for invertebrates, the evidence for mammals is still fragmented. We used a systematic review framework to investigate the reproductive impact of microplastics and nanoplastics (MNP) on mammals. MATERIALS AND METHODS: Research records were screened from Embase, Medline, Scopus and Web of Science. Twelve original papers were identified and reviewed. Immunological, oxidative and morphofunctional outcomes, and the risk of bias in all studies reviewed were analyzed. KEY FINDINGS: These studies indicated that PP can accumulate in the gonads, triggering seminiferous degeneration, Sertoli cells death, blood-testis barrier disruption, sperm degeneration, malformation, reduced number and mobility, ovarian cysts, reduced follicular growth and granulosa cells death. Gonadal damage was associated with upregulation of prooxidant mediators (oxygen reactive species, lipid and DNA oxidation), cell death, proinflammatory molecular pathways and cytokines, as well as inhibition of enzymatic and non-enzymatic antioxidant defense mechanisms. Spermatogenesis, folliculogenesis, testosterone, progesterone and estrogen levels were also impaired in PP-treated animals, which were potentially associated with down-regulation of molecules involved in germ cells microstructural organization (occludin, N-cadherin, ß-catenin and connexin 43) and steroidogenesis, such as hydroxysteroid dehydrogenases, steroidogenic acute regulatory proteins, follicle stimulating and luteinizing hormones. Selection, performance and detection bias were the main limitations identified. SIGNIFICANCE: Current evidence indicates that PP can induce dose-dependent microstructural and functional gonadal damage, which is orchestrated by pro-oxidant and pro-inflammatory mechanisms that disrupt genes, molecular effectors, and hormones that control spermatogenesis and folliculogenesis.

A Perspective of the COVID-19 Pandemic in the Plastic Waste Management and Cooperatives of Waste Pickers in Brazil.

Brazil is the fourth largest producer of plastic waste in the world. Among all the challenges the country had faced in the development of public policies for the banning of single-use plastics, the new coronavirus pandemic scenario determined the suspension of these laws indefinitely. In 2020, Brazil became the global epicenter of COVID-19. This scenario changed the habit and behavior of Brazilian consumers, who increased the consumption of plastics due to their importance in applications as protective material. The country also has social problems related to waste management that depend mainly on waste pickers. These workers need social visibility and protection not only to face the current health crisis but also to guarantee their income and survival. This work aims to discuss the increase in single-use plastics that are not intended for recycling and the respective environmental, economic, and social impacts for the country. We demonstrate the lack of data on waste management in Brazil and highlight the importance of the social inclusion of waste pickers for a circular economy. Especially after the change of scenario with the COVID-19 pandemic, the country must have adequate planning and improvements in waste management, recycling programs, and political intervention to raising awareness among the population and guaranteeing social rights for waste pickers.

Microplastic pollution in Southern Atlantic marine waters: Review of current trends, sources, and perspectives.

Microplastics (MPs) are emerging and ubiquitous contaminants which have been gaining prominence since the last decade to nowadays. This is due to their possible adverse effects in aquatic ecosystems as well as the huge amount of plastic waste exponentially generated around the globe. Plastics may be introduced either directly to water bodies or indirectly to the aquatic systems by being carried by the wind, from emissions of contaminated effluents, and soil leaching, among other processes. In turn, these debris may interact with organic and inorganic contaminants, such as polycyclic aromatic hydrocarbons (PAHs), polybrominated diphenyl ethers (PBDEs) and trace constituents, and with microorganisms. Although the abundance of microplastics from South Atlantic waters is among the highest found worldwide, the number of studies in these marine waters regarding MP contamination is still scarce. Additionally, there still are no consensus on the best sampling conditions, which may be underestimating MPs. In this way, adequate MPs studies regarding their distribution, exposure levels, chemical and biological interactions are highly suggested in order to better understand both environmental and human health potential risks. This review assessed advances in sampling, analytical methodologies, characterization and understanding of MP sources in these marine waters in comparison to data from other regions around the globe.

Management of plastic waste: A bibliometric mapping and analysis.

This work aims to provide the first holistic and deep bibliometric mapping and analysis of the management of plastic waste. Data from the last five years were obtained from a Scopus database search. Relevant information on scientific production, contributions by country and institutions, sources, reference authors, and topic trends were obtained, being analysed using the VOSviewer and Bibliometrix R-package software programs. The results clearly have shown a significant increase in the number of publications over the years, depicting the great influence of the People's Republic of China, since the most relevant authors, publications, and institutes are Chinese. Regarding the topic trends, there is a massive concern about plastic pollution, especially related to plastic in water bodies (mainly microplastics), and the socio-environmental problems which plastic may cause/aggravate, with recycling and the circular economy emerging as possible solutions.

Identification and characterization of single use oxo/biodegradable plastics from Mexico City, Mexico: Is the advertised labeling useful?

The compositional characterization of single-use plastics (SUPs), often advertised as biodegradable (B) and oxo-biodegradable (OB), is an important step towards plastic pollution mitigation through the formulation of appropriate (re) use and disposal strategies. We present here the very first study to screen daily SUPs in Mexico through comprehensive characterizations of 33 randomly collected samples (B and OB) of high consumption, with or without food contact, from the markets (n = 80), bakeries (n = 5), pharmacies (n = 5) and near public transportation systems (n = 2) across 16 municipalities of Mexico City, using the polymer composition, metal contents and thermal properties. These SUPs are composed of 85% high-density polyethylene and 15% low-density polyethylene, with significant inorganic additives, and all of them show variable thermal degradation behavior. Among the twenty five different metals identified, most of the SUPs exceed the standard international norms (94/62/EC; EN 13432; 2016/1416; ASTM D6400-04) for Cu, Cr, Mo, Zn, Fe and Pb with the maximum concentrations of 1898 mg/kg, 1586 mg/kg, 95 mg/kg, 1492 mg/kg, 1900 mg/kg and 7528 mg/kg, respectively. Our findings uncovered that the collected SUPs from Mexico City did not have the suitable physicochemical characteristics and they might end up adding to the exponentially growing solid waste in the immediate future. Hence, we recommend the implementation of strict norms to certify the SUPs.

Effects of Plastic Waste on the Heat-Induced Spalling Performance and Mechanical Properties of High Strength Concrete.

This paper investigates a potential application of hard-to-recycle plastic waste as polymeric addition in high strength concrete, with a focus on the potential to mitigate heat-induced concrete spalling and the consequent effects on the mechanical properties. The waste corresponds to soft and hard plastic, including household polymers vastly disposed of in landfills, although technically recyclable. Mechanical and physical properties, cracking, mass loss, and the occurrence of spalling were assessed in high strength concrete samples produced with either plastic waste or polypropylene fibers after 2-h exposure to 600 °C. The analysis was supported by Scanning Electron Microscopy and X-Ray Computed Tomography images. The plastic waste is composed of different polymers with a thermal degradation between 250 to 500 °C. Polypropylene (PP) fibers and plastic waste dispersed in concrete have proved to play an essential role in mitigating heat-induced concrete spalling, contributing to the release of internal pressure after the polymer melting. The different morphology of plastic waste and polypropylene fibers leads to distinct mechanisms of action. While the vapor pressure dissipation network originated by polypropylene fibers is related to the formation of continuous channels, the plastic waste seems to cause discontinuous reservoirs and fewer damages into the concrete matrix. The incorporation of plastic waste improved heat-induced concrete spalling performance. While 6 kg/m3 of plastic increased the mechanical performance after exposure to high temperature, the incorporation of 3 kg/m3 resulted in mechanical properties comparable to the reference concrete.

Massive plastic pollution in a mega-river of a developing country: Sediment deposition and ingestion by fish (Prochilodus lineatus).

The aim of this study was to determine the amount, composition and origin of plastic debris in one of the world largest river, the Paraná River in Argentina (South America), focusing on the impact of urban rivers, relationships among macro, meso and microplastic, socio-political issues and microplastic ingestion by fish. We recorded a huge concentration of macroplastic debris of domestic origin (up to 5.05 macroplastic items per m2) dominated largely by bags (mainly high- and low-density polyethylene), foodwrapper (polypropylene and polystyrene), foam plastics (expanded polystyrene) and beverage bottles (polyethylene terephthalate), particularly downstream from the confluence with an urban stream. This suggests inadequate waste collection, processing and final disposal in the region, which is regrettably recurrent in many cities of the Global South and Argentina in particular. We found an average of 4654 microplastic fragments m-2 in shoreline sediments of the river, ranging from 131 to 12687 microplastics m-2. In contrast to other studies from industrialized countries from Europe and North America, secondary microplastics (resulting from comminution of larger particles) were more abundant than primary ones (microbeads to cosmetics or pellets to the industry). This could be explained by differences in consumer habits and industrialization level between societies and economies. Microplastic particles (mostly fibres) were recorded in the digestive tract of 100% of the studied Prochilodus lineatus (commercial species). Contrary to recently published statements by other researchers, our results suggest neither macroplastic nor mesoplastics would serve as surrogate for microplastic items in pollution surveys, suggesting the need to consider all three size categories. The massive plastic pollution found in the Paraná River is caused by an inadequate waste management. New actions are required to properly manage waste from its inception to its final disposal.

Development of biodegradation process for Poly(DL-lactic acid) degradation by crude enzyme produced by Actinomadura keratinilytica strain T16-1

Background: Plastic waste is a serious problem because it is difficult to degrade, thereby leading to global environment problems. Poly(lactic acid) (PLA) is a biodegradable aliphatic polyester derived from renewable resources, and it can be degraded by various enzymes produced by microorganisms. This study focused on the scale-up and evaluated the bioprocess of PLA degradation by a crude microbial enzyme produced by Actinomadura keratinilytica strain T16-1 in a 5 L stirred tank bioreactor. Results: PLA degradation after 72 h in a 5 L bioreactor by using the enzyme of the strain T16-1 under controlled pH conditions resulted in lactic acid titers (mg/L) of 16,651 mg/L and a conversion efficiency of 89% at a controlled pH of 8.0. However, the PLA degradation process inadvertently produced lactic acid as a potential inhibitor, as shown in our experiments at various concentrations of lactic acid. Therefore, the dialysis method was performed to reduce the concentration of lactic acid. The experiment with a dialysis bag achieved PLA degradation by weight loss of 99.93%, whereas the one without dialysis achieved a degradation of less than approximately 14.75%. Therefore, the dialysis method was applied to degrade a commercial PLA material (tray) with a conversion efficiency of 32%, which was 6-fold more than that without dialysis. Conclusions: This is the first report demonstrating the scale-up of PLA degradation in a 5 L bioreactor and evaluating a potential method for enhancing PLA degradation efficiency.

Effect of different degradation types on properties of plastic waste obtained from espresso coffee capsules.

In terms of large use of plastic products, a necessity exists to minimize effects of the waste produced on environment by recycling, reuse and application in new products. In Brazil, the espresso coffee capsules are an emerging plastic waste, representing 0.9% of the coffee consumed in 2017. Therefore, Nescafé Dolce Gusto espresso coffee capsules were chosen in order to understand the polypropylene stabilization and degradation initiators with the purpose of recycling by applying in a composite material, as home composting product. In this context, the plastic capsule wastes were exposed to chemical, thermal, accelerated weathering (ultraviolet radiation + humidity) and natural weathering in order to analyze the influence of exposure and possibilities of a real application in a composting environment. Masses of the samples were monitored before and during the weathering conditions. Thermal (TGA and DSC) and chemical (FTIR) analysis were carried out before and after exposure. No changes in thermal stability were observed, however, samples conditioned in acid solution presented thermal degradation event beginning at 131 °C. In addition, all samples presented a similar behavior of melting and crystallization points, which did not change with exposure. FTIR analysis showed a disappearance of CC and CO bonds on samples exposed to natural weathering and basic solution conditioning. It also showed formation of chromophores groups on samples exposed to accelerated weathering. The visual analysis showed huge differences in samples exposed to accelerated weathering and acid solution, which were the most damaged. On the other hand, samples exposed to natural weathering, thermal and basic conditioning did not presented significantly changes supported by the TGA and FTIR results.

Physico-chemical characterisation of material fractions in household waste: Overview of data in literature.

State-of-the-art environmental assessment of waste management systems rely on data for the physico-chemical composition of individual material fractions comprising the waste in question. To derive the necessary inventory data for different scopes and systems, literature data from different sources and backgrounds are consulted and combined. This study provides an overview of physico-chemical waste characterisation data for individual waste material fractions available in literature and thereby aims to support the selection of data fitting to a specific scope and the selection of uncertainty ranges related to the data selection from literature. Overall, 97 publications were reviewed with respect to employed characterisation method, regional origin of the waste, number of investigated parameters and material fractions and other qualitative aspects. Descriptive statistical analysis of the reported physico-chemical waste composition data was performed to derive value ranges and data distributions for element concentrations (e.g. Cd content) and physical parameters (e.g. heating value). Based on 11,886 individual data entries, median values and percentiles for 47 parameters in 11 individual waste fractions are presented. Exceptional values and publications are identified and discussed. Detailed datasets are attached to this study, allowing further analysis and new applications of the data.