ABSTRACT
The clean water oxygen transfer efficiency (OTE) of a full scale non-porous hollow fibre gas permeable (GP) membrane (surface area of 500 m(2)) was evaluated at inlet air pressures of 1.2, 1.4, and 1.8 atm using two established testing methods. To form a basis of comparison with traditional aeration technologies, additional testing was done with conventional aerators (fine bubble and coarse bubble diffusers) replacing the GP membrane. OTE can be established based on the re-aeration of deoxygenated water or by monitoring the catalytic oxidation of a sodium sulphite (Na(2)SO(3)) solution. In this study, OTE values determined by sulphite oxidation (SOTE(S)) were consistently higher than those established during re-aeration (SOTE(R)) suggesting that the chemical reaction was enhancing the mass transfer. The chemical reaction was sufficiently fast in the case of the GP membrane, that the gas phase limited the mass transfer. The GP membrane operating at 1.2 atm had a SOTE(S) of 70.6% and a SOTER of 52.2%. SOTE(R) for the coarse bubble and fine bubble diffusers were 3.8% and 23.6%, respectively. This is comparable to the manufacturer's values, corrected for depth of 3.4% and 18.3%, respectively. Particularly, the derived OTE values were used to evaluate differences in energy consumption for a conventional treatment plant achieving carbon removal and nitrification. This analysis highlights the potential energy efficiency of GP membranes, which could be considered for the design of the membrane modules.
Subject(s)
Bioreactors , Oxygen/chemistry , Waste Disposal, Fluid/instrumentation , Water Purification/methods , Catalysis , Equipment Design , Fermentation , Gases , Membranes, Artificial , Porosity , Pressure , Sulfates/chemistry , Time Factors , Water/chemistry , Water Pollutants, Chemical/chemistryABSTRACT
Between 1978 and 1996, egg and chick samples of little terns (Sterna albifrons) breeding at different colony sites along the eastern coast of Schleswig-Holstein, Germany, were annually gathered by chance in the framework of a long-term ringing programme. Analyses of polychlorinated biphenyls (PCBs), dichlorodiphenyltrichloroethane (DDT), hexachlorobenzene (HCB), hexachlorocyclohexane (HCHs), and mercury were carried out on eggs, chicks, and down (only mercury). In all matrices, pollutant concentrations decreased over the 19-year period. The mixture compositions of Sigma PCB, Sigma DDT, and Sigma HCH changed during the previous decades indicating decreasing releases of PCB mixtures, DDT, and technical HCH mixtures. The pollutant concentrations currently found in the tern eggs are compared with those of other bird species from other Baltic Sea subregions, suggesting a relatively low pollution of the Belt Sea. The temporal trends in contamination are related to international measurements and conventions on bans of pollutants. Since individually known females were recaptured up to three times, inter-individual variation in pollutant burdens could be studied. Remarkable variation among individuals as well as between breeding seasons were found that were not explainable by general temporal trends. Influences of individually and seasonally varying feeding habits on this phenomenon are discussed. Compositions of individual PCB mixtures varied in relation to total PCB concentrations found in eggs suggesting a concentration-dependent metabolization of PCBs as with other species. Amounts of particular organochlorines varied between matrices possibly indicating metabolization of low chlorinated PCBs, beta-HCH, and HCB during embryogenesis. In mercury, body detoxification via down is assumed. As indicated by eggshell parameters (thickness and index) being not related to organochlorine concentrations and being similar to that found in historical studies, respectively, effects of recent organochlorine contamination on eggshell thickness seem to be improbable. In conclusion, influences of contamination on declining little tern stocks observed in Germany are discussed. Negative influences of contamination in the 1960s and 1970s are assumed to be probable.