Enhancement of biological nitrogen removal performance using novel carriers based on the recycling of waste materials.

This study aims to enhance biological nitrogen removal performance by the innovative carbon-based carriers. The new carriers were produced based on recycling waste materials. In these carriers, the advantages of the hybrid system and physicochemical properties of activated carbon were integrated to promote microbial attachment. To verify the performance of the new carriers compared to the conventional moving carriers, the experiments were conducted in two parallel laboratory-scale sequencing batch reactors under various operating conditions. The analysis revealed that the specific surface area of the new carrier with a total pore volume of 0.0015cm3/gr was 10.9 times the specific surface area of a conventional carrier. Further, the comparative results indicated that the new highly porous carriers made a major contribution to increasing the attached active biomass up to 20.2%. From the data analysis (DO, ORP, and pH), it was also confirmed that the new carriers had a positive effect on the creation of a greater anoxic zone within the biofilm. Consequently, the simultaneous nitrification-denitrification and total nitrogen removal efficiencies enhanced significantly up to 14.3% and 16.8%, respectively. From the environmental and economic viewpoints, the benefits of the novel carrier showed that it is a practical alternative for the conventional carrier providing a cost-effective wastewater treatment technology.

Kinetics of organic removal in fixed-bed aerobic biological reactor.

The process kinetics of a lab-scale upflow aerobic immobilized biomass (UAIB) reactor using simulated sugar-manufacturing wastewater as feed was investigated. The experimental unit consisted of a 22l reactor filled with high porosity pumice stone. The UAIB reactor was tested under different organic loads and different hydraulic retention times (HRT) and the substrate loading removal rate was compared with prediction of Stover-Kincannon model, second-order model and the first order substrate removal model. After obtaining steady-state conditions, organic loading rate was increased from 750 to 4500 g COD/m(3) day to resemble wastewater from sugar production lines, and hydraulic retention time was decreased from 1 to 0.5 days, stepwise. Nine different operational conditions were applied changing these two parameters in a certain program. As a result of the calculations, Stover-Kincannon model and second-order model known as "Grau" model were found to be the most appropriate models for this reactor. Stover-Kincannon model and Grau second-order model gave high correlation coefficients, which were 99.7% and 99.4%, respectively. Therefore, these models could be used in predicting the behavior or design of the UAIB reactors.