Heterogeneous catalytic ozonation for the removal of antibiotics in water: A review.

Antibiotics with pseudo-persistence in water have been regarded as emerging pollutants, which have obvious biological toxicity even at trace levels. On account of high reactivity, heterogeneous catalytic ozonation has been widely applied to remove antibiotics. Among the heterogeneous catalysts, with well-developed pores and regulable surface defects, carbon-based materials can act as both adsorbents and catalysts. Metal cations, surface hydroxyl (-OH) groups and oxygen vacancies (OVs) serve as primary active sites in metal oxides. However, composites (perovskite, apatite, etc.) with special crystalline structure have more crystallographic planes and abundant active sites. The unsaturated bonds and aromatic rings which have dense structure of the electron cloud are more likely to be attacked by ozone (O3) directly. Sulfonamides (SAs) can be oxidized by O3 directly within a short time due to the structure of activated aromatic rings and double bonds. With the existence of catalysts, almost all antibiotics can attain fair removal effects. The presence of water matrix can greatly influence the removal rate of pollutants via changing the surface properties of catalysts, competing active sites with O3, etc. Correspondingly, the application of diverse heterogeneous catalysts was introduced in details, based on modification including metal/non-metal doping, surface modification and carrier composite. The degradation pathways of SAs, fluoroquinolones (FQNs), tetracyclines (TCs) and ß-lactams were summarized founded on the functional group structures. Furthermore, the effects of water matrix (pH, coexisting ions, organics) for catalytic ozonation were also debated. It is expected to proffer advanced guidance for researchers in catalytic ozonation of antibiotics.

Mitigating N2O emissions in land treatment systems: Mechanisms, influences, and future directions.

Land treatment systems (LTS) are widely used in decentralized domestic wastewater treatment due to low energy requirements and effective treatment outcomes. However, LTS operations are also a significant source of N2O emissions, a potent greenhouse gas threatening the ozone layer and posing risks to human health. Despite the importance of understanding and controlling N2O emissions, existing literature lacks comprehensive analyses of the mechanisms driving N2O generation and effective control strategies within LTS. This study addresses this gap by reviewing current research and identifying key factors influencing N2O emissions in LTS. This review reveals that in addition to traditional nitrification and denitrification processes, co-denitrification and complete ammonia oxidation are crucial for microbial nitrogen removal in LTS. Plant selection is primarily based on their nitrogen absorption capacity while using materials such as biochar and iron can provide carbon sources or electrons to support microbial activities. Optimizing operational parameters is essential for reducing N2O emissions and enhancing nitrogen removal efficiency in LTS. Specifically, the carbon-to­nitrogen ratio should be maintained between 5 and 12, and the hydraulic loading rate should be kept within 0.08-0.2 m3/(m2·d). Dissolved oxygen and oxidation-reduction potential should be adjusted to meet the aerobic or anaerobic conditions the microorganisms require. Additionally, maintaining a pH range of 6.5-7.5 by adding alkaline substances is crucial for sustaining nitrous oxide reductase activity. The operating temperature should be maintained between 20 and 30 °C to support optimal microbial activity. This review further explores the relationship between environmental factors and microbial enzyme activity, community structure changes, and functional gene expression related to N2O production. Future research directions are proposed to refine N2O flux control strategies. By consolidating current knowledge and identifying research gaps, this review advances LTS management strategies that improve wastewater treatment efficiency while mitigating the environmental and health impacts of N2O emissions.

Influence of different stalks on the metallization degree of FeCl3-derived magnetic biochar through pyrolysis behavior and compositional differences.

To investigate the effect of stalk type on the metallization degrees in FeCl3-derived magnetic biochar (MBC), MBC was synthesized via an impregnation-pyrolysis method using six different stalks. The Fe0 content in MBC significantly influenced its magnetic properties and ostensibly governed its catalytic capabilities. Analysis of the interaction between stalks and FeCl3 revealed that the variation in metallization degrees, resulting from FeCl2 decomposition (6.1%) and stalk-mediated reduction (20.7%), was directly responsible for the observed differences in MBC metallization. The presence of oxygen-containing functional groups and fixed carbon appeared to promote metallization in MBC induced by reduction. A series of statistical analyses indicated that the cellulose, lignin, and hemicellulose content of the stalks were key factors contributing to differences in MBC metallization degrees. Further exploration revealed that hemicellulose and cellulose were more effective than lignin in enhancing metallization through FeCl2 decomposition and reduction. Constructing stalk models demonstrated that the variance in the content of these three biomass components across the six stalk types could lead to differences in the metallization degree attributable to reduction and FeCl2 decomposition, thereby affecting the overall metallization degree of MBC. A prediction model for MBC metallization degree was developed based on these findings. Moreover, the elevated Si content in some stalks facilitated the formation of Fe2(SiO4), which subsequently impeded the reduction process. This study provides a theoretical foundation for the informed selection of stalk feedstocks in the production of FeCl3-derived MBC.

Joint effect of black carbon deriving from wheat straw burning and plastic mulch film debris on the soil biochemical properties, bacterial and fungal communities.

Black carbon (BC) formed after straw burning remains in farmland soil and coexists with plastic mulch film (PMF) debris. It is unclear how BC influences soil multifunctionality in the presence of PMF debris. In this study, we determined the joint effects of BC and PMF debris on soil biochemical properties and microbial communities. We conducted a soil microcosm experiment by adding BC formed by direct burning of wheat straw and PMF debris (polyethylene (PE) and biodegradable PMF (BP)) into soil at the dosages of 1 %, and soils were sampled on the 15th, 30th, and 100th day of soil incubation for high-throughput sequencing. The results showed that the degradation of PMF debris was accompanied by the release of microplastics (MPs). BC decreased NH4+-N (PE: 68.63 %; BP: 58.97 %) and NO3--N (PE: 12.83 %; BP: 51.37 %) and increased available phosphorus (AP) (PE: 79.12 %; BP: 26.09 %) in soil containing PMF debris. There were significant differences in enzyme activity among all the treatments. High-throughput sequencing indicated that BC reduced bacterial and fungal richness and fungal diversity in PMF debris-exposed soil, whereas PMF debris and BC resulted in significant changes in the proportion of dominant phyla and genera of bacteria and fungi, which were affected by incubation time. Furthermore, BC affected microorganisms by influencing soil properties, and pH and N content were the main influencing factors. In addition, FAPRPTAX analysis indicated that BC and PMF debris affected soil C and N cycling. These findings provide new insights into the response of soil multifunctionality to BC and PMF debris.

Advancing toxicity studies of per- and poly-fluoroalkyl substances (pfass) through machine learning: Models, mechanisms, and future directions.

Perfluorinated and perfluoroalkyl substances (PFASs), encompassing a vast array of isomeric chemicals, are recognized as typical emerging contaminants with direct or potential impacts on human health and the ecological environment. With the complex and elusive toxicological profiles of PFASs, machine learning (ML) has been increasingly employed in their toxicity studies due to its proficiency in prediction and data analytics. This integration is poised to become a predominant trend in environmental toxicology, propelled by the swift advancements in computational technology. This review diligently examines the literature to encapsulate the varied objectives of employing ML in the toxicity studies of PFASs: (1) Utilizing ML to establish Quantitative Structure-Activity Relationship (QSAR) models for PFASs with diverse toxicity endpoints, facilitating the targeted toxicity prediction of unidentified PFASs; (2) Investigating and substantiating the Adverse Outcome Pathway (AOP) through the synergy of ML and traditional toxicological methods, with this refining the toxicity assessment framework for PFASs; (3) Dissecting and elucidating the features of established ML models to advance Open Research into the toxicity of PFASs, with a primary focus on determinants and mechanisms. The discourse extends to an in-depth examination of ML studies, segregating findings based on their distinct application trajectories. Given that ML represents a nascent paradigm within PFASs research, this review delineates the collective challenges encountered in the ML-mediated study of PFAS toxicity and proffers strategic guidance for ensuing investigations.

Metabolomic reveals the responses of sludge properties and microbial communities to high nitrite stress in denitrifying phosphorus removal systems.

Nitrite, as an electron acceptor, plays a good role in denitrifying phosphorus removal (DPR); however, high nitrite concentration has adverse affects on sludge performance. We investigated the precise mechanisms of responses of sludge to high nitrite stress, including surface characteristics, intracellular and extracellular components, microbial and metabolic responses. When the nitrite stress reached 90 mg/L, the sludge settling performance was improved, but the activated sludge was aging. FTIR and XPS analysis revealed a significant increase in the hydrophobicity of the sludge, resulting in improve settling performance. However, the intracellular carbon sources synthesis was inhibited. In addition, the components in the tightly bound extracellular polymeric substances (TB-EPS) of sludge were significantly reduced and indicated the disturb of metabolism. Notably, Exiguobacterium emerged as a new genus when face high nitrite stress that could maintaining survival in hostile environments. Moreover, metabolomic analysis demonstrated strong biological response to nitrite stress further supported above results that include the inhibited of carbohydrate and amino acid metabolism. More importantly, some lipids (PS, PA, LysoPA, LysoPC and LysoPE) were significantly upregulated that related enhanced membrane lipid remodeling. The comprehensive analyses provide novel insights into the high nitrite stress responses mechanisms in activated sludge systems.

Influence of soil composition and environmental factors on the adsorption of per- and polyfluoroalkyl substances: A review.

Per- and polyfluoroalkyl substances (PFASs) have garnered considerable scientific and regulatory scrutiny due to their widespread distribution across environments and their potential toxicological impacts on human health. The pedosphere serves as a vital reservoir for these chemicals, significantly determining their environmental trajectory and chemical transformations. This study offers a comprehensive synthesis of the current understanding regarding the adsorption mechanics of PFASs in soil matrices. Due to their unique molecular structure, PFASs predominantly engage in hydrophobic and electrostatic interactions during soil adsorption. This work thoroughly evaluates the influence of various factors on adsorption efficiency, including soil properties, molecular characteristics of PFASs, and the prevailing environmental conditions. The complex nature of soil environments complicates isolating individual impacts on PFAS behavior, necessitating an integrated approach to understanding their environmental destinies better. Through this exploration, we seek to clarify the complex interplay of factors that modulate the adsorption of PFASs in soils, highlighting the urgent need for future research to disentangle the intricate and combined effects that control the environmental behavior of PFAS compounds.

Biochar and nano-hydroxyapatite combined remediation of soil surrounding tailings area: Multi-metal(loid)s fixation and soybean rhizosphere soil microbial improvement.

The soil near tailings areas is relatively barren and contaminated by multi-metal(loid)s, seriously threatening the safety of crop production. Here, biochar and nano-hydroxyapatite (nHAP) were combined to improve the sterilized and unsterilized polymetallic contaminated soil, and soil incubation and soybean pot experiments were designed. Results showed that biochar and nHAP not only increased soil C, N, and P but also effectively reduced multi-metal bioavailability, wherein the combined application of the two amendments had the best effect on metal immobilization. The synergistic effect of the two amendments decreased the acid-soluble contents of Co, Cu, Fe, and Pb in rhizosphere soils up to 86.75%, 80.69%, 89.09%, and 96.70%, respectively. The ameliorant reduced the accumulation of metal(loid)s in soybean plants, and rhizosphere microorganisms inhibited the migration of soil metals to plants. Additionally, biochar and nHAP regulated the rhizosphere soil microbial community. The rhizosphere soil of the sterilization group tended to prioritize the restoration of the original dominant bacteria. As, Pb, Fe, Urease, OM, TN, and TP were the critical environmental variables affecting rhizosphere soil bacterial communities. Therefore, combining biochar and nHAP is an environmentally friendly strategy to reduce polymetallic mobility in tailings soil and crops and improve soil microbial community structure.

Extracellular polymeric substances altered the physicochemical properties of molybdenum disulfide nanomaterials to mitigate its toxicity to Chlorella vulgaris.

Although the toxic effects of two-dimensional nanomaterials (2D-NMs) have been widely reported, the influence of extracellular polymeric substances (EPS) on the environmental fate and risk of 2D-NMs in aquatic environments is largely unknown, and the processes and mechanisms involved remain to be revealed. Herein, we investigated the impact of EPS secreted by microalgae (Chlorella vulgaris (C. vulgaris)) on the environmental transformation and risk of molybdenum disulfide (MoS2). We found that the attachment of EPS increased the thickness of MoS2 (from 2 nm to 5 nm), changed it from a monolayer sheet to a fuzzy multilayer structure, and promoted the formation of defects on MoS2. The blue-shift of the peak associated with the plasmon resonances in the 1 T phase and the generation of electron-hole pairs suggested that EPS altered the surface electronic structure of MoS2. EPS interacted mainly with the S atoms on the 1 T phase, and the attachment of EPS promoted the oxidation of MoS2. The reduction in hydrodynamic diameter (Dh) and the decrease in zeta potential indicated that EPS inhibited the agglomeration behavior of MoS2 and enhanced its dispersion and stability in aqueous media. Notably, EPS reduced the generation of free radicals (superoxide anion (•O2-), singlet oxygen (1O2), and hydroxyl radicals (•OH-)). Furthermore, EPS mitigated the toxicity of MoS2 to C. vulgaris, such as attenuated reduction in biomass and chlorophyll content. Compared to pristine MoS2, MoS2 + BG11 + EPS exhibited weaker oxidative stress, membrane damage and lipid peroxidation. The adsorption of EPS on MoS2 surface reduced the attachment sites of MoS2, making MoS2 less likely to be enriched on the cell surface. The findings have significant contribution for understanding the interactions between EPS and MoS2 in aquatic ecosystems, providing scientific guidance for risk assessment of 2D-NMs.

Influence mechanisms of different stalks on iron species type of magnetic biochar prepared from Fe2O3.

The current selection of biomass feedstock for magnetic biochar (MBC) catalysts is highly blind. Consequently, this study delves into understanding how the types of biomass influence the iron species present in MBC catalysts. The process involved the creation of MBC through simulated impregnation-pyrolysis, utilizing six types of stalks and Fe2O3. The type of iron species significantly impacted magnetic properties and likely influenced catalytic properties of MBC. MBC's iron species type was shaped by the reduction effects of the diverse stalks on Fe2O3. During the pyrolysis, discrepancies were observed in the release of reducing gases and direct reduction for the different stalks. These differences in reduction behavior directly accounted for the distinct reduction effects. To delve deeper, the reduction behavior and effect of the main components of the stalk (hemicellulose, cellulose, and lignin) on Fe2O3 were analyzed, highlighting lignin as the most effective. Nonetheless, the absolute values of Pearson's r between lignin content in the stalk and reduction behavior/effect ranged only from 0.078 to 0.421. In contrast, the values for K, Ca, and Si content in the stalks and their influence on reduction behavior and MBC's reduction/metallization degree ranged from 0.410 to 0.910. The catalytic impacts of K and Ca were confirmed through their incorporation into cotton and reed stalks. The disparities in K, Ca, and Si content among the six stalks appeared to be the primary driver behind the diverse iron species in MBC. This work provides a scientific basis for the rational selection of biomass feedstock for MBC catalysts.

Preparation of wavy three-dimensional graphene-like biochar and its adsorption mechanism of embedded separation for dimethoate.

In this study, graphene-like biochar (IZBC) was prepared by pyrolysis of wheat straw in the presence of catalyst and activator. The formation of graphene in IZBC could be divided into three stages: shell core generation, carburization, and carbon precipitation. When the pyrolysis temperatures were in the ranges of 500-600 â„ƒ, 600-700 â„ƒ, 700-800 â„ƒ and 800-900 â„ƒ, 17%, 32%, 13% and 38% of graphene were produced, respectively. The contribution ratios of graphene by FeCl3, ZnCl2 and HCl were 64%, 23% and 13%, respectively. Moreover, IZBC was filled with porous wavy three-dimensional graphene nanosheets that enabled self-aggregation to be effectively prevented, which was superior to the striped two-dimensional structure. The adsorption of IZBC for dimethoate was a spontaneous exothermic reaction with the adsorption capacity of 980 µmol/g, which was consistent with the pseudo-second-order and intraparticle diffusion models. The adsorption was inhibited by coexisting cations, anions, and humic acid in water. Dimethoate was adsorbed on graphene through embedded separation, with pore filling, cation-π and electrostatic attraction as the key driving forces. In addition, the adsorbed saturated IZBC could be effectively regenerated for many times by 2 mol/L HCl solution.

Mechanisms of ZnO Nanoparticles Enhancing Phototransformation of Biologically Derived Organic Phosphorus in Aquatic Environments.

Zinc oxide nanoparticles (ZnO NPs), as the highly efficient photocatalysts, could enhance the transformation of biogenic organic phosphorus (OP) to orthophosphate (PO43-) by photodegradation, accelerating eutrophication. Conversely, orthophosphate can also transform ZnO NPs and thus potentially alter their catalytic and chemical properties. Here, we investigated the transformation mechanisms of three biogenic OP compounds and ZnO NPs under ultraviolet light (UV) illumination: inositol phosphates (IHPs), nucleic acids (DNA), and aminoethylphosphonic acid (AEP). The physicochemical characteristics of the resulting products were systematically characterized. Results show that ZnO NPs accelerated the transformation of IHPs, DNA, and AEP to inorganic phosphorus with the direct photolysis efficiencies of 98.14, 87.68, and 51.76%, respectively. The main component of the precipitates remained ZnO NPs, and Zn3(PO4)2 was identified. Zinc phytate was determined in the ZnO NP-IHP system. 31P NMR and FTIR further confirmed that the aquatic phase contained orthophosphate. Photoproduced hydroxyl (·OH) and superoxide (·O2-) were proved to play a dominant role in the OP photomineralization. Furthermore, ZnO NPs significantly enhanced the intensity of ·OH and ·O2- compared to the OP and Zn2+ solution alone. This work explored the light-induced mineralization processes of OP with ZnO NPs indicating that nanophotocatalysts may play a positive role in transformation of OP species in aquatic environments to further contribute to eutrophication.

Application and improvement methods of sludge alkaline fermentation liquid as a carbon source for biological nutrient removal: A review.

Alkaline fermentation can reduce the amount of waste activated sludge and prepare sludge alkaline fermentation liquid (SAFL) rich in short-chain fatty acids (SCFAs), which can be used as a high-quality carbon source for the biological nutrient removal (BNR) process. This review compiles the production method of SAFL and the progress of its application as a BNR carbon source. Compared with traditional carbon sources, SAFL has the advantages of higher efficiency and economy, and different operating conditions can influence the yield and structure of SCFAs in SAFL. SAFL can significantly improve the nutrient removal efficiency of the BNR process. Taking SAFL as the internal carbon source of BNR can simultaneously solve the problem of carbon source shortage and sludge treatment difficulties in wastewater treatment plants, and further reduce the operating cost. However, the alkaline fermentation process results in many refractory organics, ammonia and phosphate in SAFL, which reduces the availability of SAFL as a carbon source. Purifying SCFAs by removing nitrogen and phosphorus, directly extracting SCFAs, or increasing the amount of SCFAs in SAFL by co-fermentation or combining with other pretreatment methods, etc., are effective measures to improve the availability of SAFL.

Nutrient dynamics and microbial community response in macrophyte-dominated lakes: Implications for improved restoration strategies.

Although lakes dominated by macrophytes are conducive to ecological balance, this balance is easily disrupted by excessive nutrients flowing into the lake. However, knowledge of whether excessive nutrients lead to different microbial environmental vulnerabilities in the lake sediment between macrophyte-dominated areas and macrophyte-free areas is a prerequisite for the implementation of targeted protection measures. In this study, we investigated bacterial communities in sediments using high-throughput sequencing of 16S rRNA genes. Our results showed that the sources of total nitrogen (TN) and organic matter (OM) were related to the macrophytes. The structure, drivers, and interspecific associations of bacterial community, which were more susceptible to increased changes in TN and OM, differed significantly between macrophyte-dominated areas and macrophyte-free areas. More precisely, the lake edge, where was occupied by macrophytes, had a higher proportion of deterministic phylogenetic turnover (88.89%) than other sites, as well as a wider ecological niche and a tighter network structure. Further, as the difference in TN increased, the main assembly processes in surface sediments changed from stochastic to deterministic. However, the majority of phyla from the lake edge showed a greater correlation with excessive nutrients, and the selection of the community by excessive nutrients was more obvious at the edge of the lake. In addition, our results demonstrated that the stability of the bacterial community in macrophyte-free areas is greater than in macrophyte-dominated areas, while an excessively high deterministic process ratio and nutrient (TN and OM) concentration significantly reduced bacterial community stability at macrophyte-dominated areas. Taken together, these results provide a better understanding of the effects of excessive nutrients derived from macrophytes on bacterial community patterns, and highlight the importance of avoiding the accumulation of TN and OM in macrophyte-dominated areas to enhance the sustainability of the ecosystem after restoration of lakes with macrophytes.

Heterogeneous photocatalytic oxidation for the removal of organophosphorus pollutants from aqueous solutions: A review.

Organophosphorus pollutants (OPs), which are compounds containing carbon­phosphorus bonds or phosphate derivatives containing organic groups, have received much attention from researchers because of their persistence in the aqueous environment for long periods of time and the threat they pose to human health. Heterogeneous photocatalysis has been widely applied to the removal of OPs from aqueous solutions due to its better removal effect and environmental friendliness. In this review, the removal of OPs from aqueous matrices by heterogeneous photocatalysis was presented. Herein, the application and the heterogeneous photocatalysis mechanism of OPs were described in detail, and the effects of catalyst types on degradation effect are discussed categorically. In particular, the heterojunction type photocatalyst has the most excellent effect. After that, the photocatalytic degradation pathways of several OPs were summarized, focusing on the organophosphorus pesticides and organophosphorus flame retardants, such as methyl parathion, dichlorvos, dimethoate and chlorpyrifos. The toxicity changes during degradation were evaluated, indicating that the photocatalytic process could effectively reduce the toxicity of OPs. Additionally, the effects of common water matrices on heterogeneous photocatalytic degradation of OPs were also presented. Finally, the challenges and perspectives of heterogeneous photocatalysis removal of OPs are summarized and presented.

Nanoparticles and antibiotics stress proliferated antibiotic resistance genes in microalgae-bacteria symbiotic systems.

The comprehensive effect of exogenous pollutants on the dispersal and abundance of antibiotic-resistance genes (ARGs) in the phycosphere, bacterial community and algae-bacteria interaction remains poorly understood. We investigated community structure and abundance of ARGs in free-living (FL) and particle-attached (PA) bacteria in the phycosphere under nanoparticles (silver nanoparticles (AgNPs) and hematite nanoparticles (HemNPs)) and antibiotics (tetracycline and sulfadiazine) stress using high-throughput sequencing and real-time quantitative PCR. Meanwhile, the intrinsic connection of algae-bacteria interaction was explored by transcriptome and metabolome. The results showed that the relative abundance of sulfonamide and tetracycline ARGs in PA and FL bacteria increased 103-129 % and 112-134 %, respectively, under combined stress of nanoparticles and antibiotics. Antibiotics have a greater effect on ARGs than nanoparticles at environmentally relevant concentrations. Proteobacteria, Firmicutes, and Bacteroidetes, as the primary potential hosts of ARGs, were the dominant phyla. Lifestyle, i.e., PA and FL, significantly determined the abundance of ARGs and bacterial communities. Moreover, algae can provide bacteria with nutrients (carbohydrates and amino acids), and can also produce antibacterial substances (fatty acids). This algal-bacterial interaction may indirectly affect the distribution and abundance of ARGs. These findings provide new insights into the distribution and dispersal of ARGs in microalgae-bacteria symbiotic systems.

Iron mediated autotrophic denitrification for low C/N ratio wastewater: A review.

In recent years, iron mediated autotrophic denitrification has been a concern because it overcomes the absence of organic carbon and has been successfully used in denitrification for low C/N ratio wastewater. However, there is currently a lack of a more systematic summary of iron-based materials that can be used for denitrification, and no detailed overview about the mechanism of iron mediated autotrophic denitrification has been reported. In this study, the iron materials with different valence states that can be used for denitrification were summarized, and emphasized, as well as the mechanism in different interaction systems were emphasize. In addition, the contribution of various microorganisms in nitrate reduction were analyzed and the effects of operating conditions and water quality were evaluated. Finally, the challenges and shortcomings of the denitrification process were discussed aiming to find better practical engineering applications of iron-based denitrification.

The behavior, transport, and positive regulation mechanism of ZnO nanoparticles in a plant-soil-microbe environment.

ZnO nanoparticles (ZnO NPs) have been widely used in several fields, and they have the potential to be a novel fertilizer to promote plant growth. For the effective use of ZnO NPs, it is necessary to understand their influence mechanisms and key interactions with the soil physical and biological environment. In this review, we summarize the fate and transport of ZnO NPs applied via soil treatment or foliar spray in plant-soil systems and discuss their positive regulation mechanisms in plants and microbes. The latest research shows that the formation, bioavailability, and location of ZnO NPs experience complicated changes during the transport in soil-plant systems and that this depends on many factors. ZnO NPs can improve plant photosynthesis, nutrient element uptake, enzyme activity, and the related gene expression as well as modulate carbon/nitrogen metabolism, secondary metabolites, and the antioxidant systems in plants. Several microbial groups related to plant growth, disease biocontrol, and nutrient cycling in soil can be altered with ZnO NP treatment. In this work, we present a systematic comparison between ZnO NP fertilizer and conventional zinc salt fertilizer. We also fill several knowledge gaps in current studies with the hope of providing guidance for future research.

The advanced treatment of textile printing and dyeing wastewater by hydrodynamic cavitation and ozone: Degradation, mechanism, and transformation of dissolved organic matter.

The emission standards for textile printing and dyeing wastewater are stricter due to serious environmental issues. A novel technology, hydrodynamic cavitation combined with ozone (HC + O3), has attracted wide attention in wastewater advanced treatment, whereas the contaminants removal mechanism and transformation of dissolved organic matter (DOM) were rarely reported. This study investigated the removal efficiency and mechanism of HC + O3. The maximum removal rates of UV254, chrominance, CODCr, and TOC were 64.99%, 91.90%, 32.30%, and 36.67% in 60 min, respectively, at the inlet pressure of 0.15 MPa and O3 dosage of 6.25 mmol/L. The synergetic coefficient of HC + O3 was 2.77. The removal of contaminants was the synergy of 1O2, ·OH and ·O2-, and high molecular weight and strong aromaticity organic matters were degraded effectively. The main components in DOM were tryptophan-like and tyrosine-like, which were effectively removed after HC + O3. Meanwhile, most DOM had decreased to low apparent relative molecular weight (LARMW) compounds. Additionally, the HC + O3 effluent can reach the emission standard in 60 min for 8.07 USD/m3. It can be concluded that HC + O3 is an effective technology for the advanced treatment of industrial wastewater. This study will provide suggestions for the engineering application of HC + O3.

Impact of water matrices on oxidation effects and mechanisms of pharmaceuticals by ultraviolet-based advanced oxidation technologies: A review.

The binding between water components (dissolved organic matters, anions and cations) and pharmaceuticals influences the migration and transformation of pollutants. Herein, the impact of water matrices on drug degradation, as well as the electrical energy demands during UV, UV/catalysts, UV/O3, UV/H2O2-based, UV/persulfate and UV/chlorine processes were systemically evaluated. The enhancement effects of water constituents are due to the powerful reactive species formation, the recombination reduction of electrons and holes of catalyst and the catalyst regeneration; the inhibition results from the light attenuation, quenching effects of the excited states of target pollutants and reactive species, the stable complexations generation and the catalyst deactivation. The transformation pathways of the same pollutant in various AOPs have high similarities. At the same time, each oxidant also can act as a special nucleophile or electrophile, depending on the functional groups of the target compound. The electrical energy per order (EEO) of drugs degradation may follow the order of EEOUV > EEOUV/catalyst > EEOUV/H2O2 > EEOUV/PS > EEOUV/chlorine or EEOUV/O3. Meanwhile, it is crucial to balance the cost-benefit assessment and toxic by-products formation, and the comparison of the contaminant degradation pathways and productions in the presence of different water matrices is still lacking.