Organo-monomers coated slow-release fertilizers: Current understanding and future prospects.

The increasing urge to make an impactful contribution towards attaining nutritional security amidst the ever-rising demand for food, changing climate and maintaining environmental health and safety has become the main focal point for today's researchers globally. Slow-release fertilizers (SRFs) are a broad, dynamic, and advance category of fertilizers but despite its environmental benefits and scientifically proven results it often faces some critical challenges, primarily due to its high cost, often stemming from synthetic coatings, deteriorating soil health and with unrevealed potential environmental impacts. Organo-monomers have gained immense popularity due to their organic origin, biodegradable nature, biocompatibility, bio-sustainability and as a targeted delivery of nutrients in the plant system leading to increase in nutrient use efficiency (NUE). They can form strong bond with other monomers, fertilizers elements and improve the soil quality, carbon sequestration and holistically the environment. This review emphasizes on organo-monomers based SRFs, its synthesis, application and deliberate mechanism of nutrient release; boosting crop productivity and global economy. In conclusion, provided the significant challenges posed by the classical or synthetically coated fertilizers; the application of organo-monomers based SRFs demonstrates immense potential for achieving sustainable yield, to help build a global nutritionally secure population.

Long-term fertilization and manuring effects on the nexus between sulphur distribution and SOC in an Inceptisol over five decades under a finger millet-maize cropping system.

Our investigation revealed that alterations in sulphur (S) pools are predominantly governed by soil organic carbon (SOC), soil nitrogen (N), microbial biomass, and soil enzyme activities in sandy clay loam (Vertic Ustropept) soil. We employed ten sets of nutrient management techniques, ranging from suboptimal (50% RDF) to super-optimal doses (150% RDF), including NPK + Zn, NP, N alone, S-free NPK fertilizers, NPK + FYM, and control treatments, to examine the interrelation of S with SOC characteristics. Fourier-transform infrared (FT-IR) spectroscopy was utilized to analyze the functional groups present in SOC characterization across four treatments: 100% NPK, 150% NPK, NPK + FYM, and absolute control plots. Principal component analysis (PCA) was then applied to assess 29 minimal datasets, aiming to pinpoint specific soil characteristics influencing S transformation. In an Inceptisol, the application of fertilizers (100% RDF) in conjunction with 10 t ha-1 of FYM resulted in an increase of S pools from the surface to the subsurface stratum (OS > HSS > SO42--S > WSS), along with an increase in soil N and SOC. FT-IR spectroscopy identified cellulose and thiocyanate functional groups in all four plots, with a pronounced presence of carbohydrate-protein polyphenol, sulfoxide (S=O), and nitrate groups specifically observed in the INM plot. The PCA findings indicated that the primary factors influencing soil quality and crop productivity (r2 of 0.69) are SOC, SMBC, SMBN, SMBS, and the enzyme activity of URE, DHA, and AS. According to the study, the combined application of fertilizer and FYM (10 t ha-1) together exert a positive impact on sulphur transformation, SOC accumulation, and maize yield in sandy clay loam soil.