ABSTRACT
Redox flow batteries (RFBs) are one of the most promising long-term energy storage technologies which utilize the redox reaction of active species to realize charge and discharge. With the decoupled power and energy components, RFBs exhibit high battery pile construction flexibility and long lifespan. However, the inherent slow electrochemical kinetics of the current widely applied redox active species severely impedes the power output of RFBs. Developing high performance electrocatalysts for these redox active species would boost the power output and energy efficiency of RFBs. Here, we present a critical review of nanoelectrocatalysts to improve the sluggish kinetics of different redox active species, mainly including the chemical components, structure and integration methods. The relationship between the physicochemical properties of nanoelectrocatalysts and the power output of RFBs is highlighted. Finally, the future design of nanoelectrocatalysts for commercial RFBs is proposed.
ABSTRACT
The aqueous polysulfides is an important Earth-abundant and multielectron redox couple to construct high capacity density and low-cost aqueous redox flow batteries (RFB) ; nevertheless, the sluggish conversion and kinetic behavior of S2-/Sx2- result in a low power density output and poor active material utilizations. Herein, we present nanoconfined self-assembled ordered hierarchical porous Co and N codoped carbon (OHP-Co/NC) as an electrocatalytic reactor to enhance the mass transfer and redox activity of aqueous polysulfides. Finite element method simulation proves that the OHP-Co/NC with interconnected macropores and mesopores exhibits an enhanced mass transfer and delivers a larger redox electrolyte utilization of 50.1% compared to 23.3% of conventional Co/NC. Notably, the OHP-Co/NC obtained at 850 °C delivers the smallest redox peak potential difference (ΔE = 99 mV). Comparison studies of in operando Raman for aqueous polysulfides in the redox electrolyte and in situ electrochemical Raman on the single OHP-Co/NC particle for the adsorbed polysulfides were carried out. And it confirms that the OHP-Co/NC-850 catalyst has a strong adsorption of S42- and can retard the strong disproportionation and hydrolysis behavior of polysulfides on the electrocatalyst interface. Therefore, the polysulfide/ferrocyanide RFB with an OHP-Co/NC-850 based membrane-electrode assembly (MEA) exhibited a high power density of 110 mW cm-2, as well as a steady capacity retention over 99.7% in 300 cycles.
ABSTRACT
Polyoxometalates (POMs) are a class of metal-oxygen cluster molecular materials formed by covalently linking transition metal atoms and oxygen atoms. Those molecular cluster materials also shows multiple electron reversible redox capabilities and high solubility in solution. Thus, POMs also recently present interesting applications as redox active electrolyte in redox flow batteries (RFBs). In this review, we mainly focus on the structural design of POMs and analysis factors affecting the electrochemical properties of POMs. Spectroscopic characterizations are introduced to deeply explore the structural changes of POMs during the redox process. Furthermore, we summarize the cases of POMs used as liquid-phase redox couple in aqueous or non-aqueous redox flow batteries and discuss the advantages and deficiency of POMs with various configurations.
