A comprehensive review on agricultural waste utilization through sustainable conversion techniques, with a focus on the additives effect on the fate of phosphorus and toxic elements during composting process.

The increasing trend of using agricultural wastes follows the concept of "waste to wealth" and is closely related to the themes of sustainable development goals (SDGs). Carbon-neutral technologies for waste management have not been critically reviewed yet. This paper reviews the technological trend of agricultural waste utilization, including composting, thermal conversion, and anaerobic digestion. Specifically, the effects of exogenous additives on the contents, fractionation, and fate of phosphorus (P) and potentially toxic elements (PTEs) during the composting process have been comprehensively reviewed in this article. The composting process can transform biomass-P and additive-born P into plant available forms. PTEs can be passivated during the composting process. Biochar can accelerate the passivation of PTEs in the composting process through different physiochemical interactions such as surface adsorption, precipitation, and cation exchange reactions. The addition of exogenous calcium, magnesium and phosphate in the compost can reduce the mobility of PTEs such as copper, cadmium, and zinc. Based on critical analysis, this paper recommends an eco-innovative perspective for the improvement and practical application of composting technology for the utilization of agricultural biowastes to meet the circular economy approach and achieve the SDGs.

Organic matter stabilization and phosphorus activation during vegetable waste composting: Multivariate and multiscale investigation.

The conversion of organic matter and P in the waste composting process affects the efficiency of the composted product. However, the addition of microbial inoculants may improve the conversion characteristics of organic matter and P. In this study, straw-decomposing microbial inoculant (SDMI) was added to investigate its effects on the organic matter stabilization and phosphorus activation during the composting of vegetable waste (VWs). Aliphatic carboxyl-containing compounds were degraded during composting, but the stability of the organic matter and P was improved. The addition of SDMI promoted the degradation of dissolved organic carbon by 81.7 % and improved P stability and thermal stability of organic matter. Hedley sequential P fractionation showed a decrease in the H2O-P proportion by >12 % and increased in the HCl-P proportion by >4 % by the end of composting. Stable forms of P, such as AlPO4 and iron-containing phosphate, were the main forms of P in the final compost. The results provide a basis for producing high-quality vegetable compost products and improving the reutilization potential of VWs.

Impact of catalytic hydrothermal treatment and Ca/Al-modified hydrochar on lability, sorption, and speciation of phosphorus in swine manure: Microscopic and spectroscopic investigations.

The effects of catalytic hydrothermal (HT) pretreatment on animal manure followed by the addition of hydrochar on the nutrients recovery have not yet been investigated using a combination of chemical, microscopic, and spectroscopic techniques. Therefore, a catalytic HT process was employed to pretreat swine manure without additives (manure-HT) and with H2O2 addition (manure-HT- H2O2) to improve the conversion efficiency of labile or organic phosphorus (P) to inorganic phase. Then, a Ca-Al layered double hydroxide hydrochar (Ca/Al LDH@HC) derived from corn cob biomass was synthesized and applied to enhance P sorption. Scanning electron microscopy (SEM), and three-dimensional excitation emission matrix (3D-EEM), X-ray photoelectron spectroscopy (XPS), P k-edge X-ray absorption near edge structure (XANES), were used to elucidate the mechanisms of P release and capture. The H2O2 assisted HT treatment significantly enhanced the release of inorganic P (251.4 mg/L) as compared to the untreated manure (57.2 mg/L). The 3D-EEM analysis indicated that the labile or organic P was transformed and solubilized efficiently along with the deconstruction of manure components after the H2O2 assisted HT pretreatment. Application of Ca/Al LDH@HC improved the removal efficiency of P from the derived P-rich HT liquid. This sorption process was conformed to the pseudo-second-order model, suggesting that chemisorption was the primary mechanism. The results of SEM and P k-edge XANES exhibited that Ca, as the dominated metal component, could act as a reaction site for the formation of phosphate precipitation. These results provide critical findings about recovering P from manure waste, which is useful for biowastes management and nutrients utilization, and mitigating unintended P loss and potential environmental risks.