Diurnal pattern of Poaceae and Betula pollen flight in Central Europe.

In Central Europe the most common allergies are provoked by grass or birch pollen allergens. We determined the intra-daily behavior of airborne pollen grains of grasses (Poaceae) and birch (Betula ssp.) in Central Europe, based on data obtained from a network of automatic pollen monitors over Europe (www.pollenscience.eu). Our aim was to determine the time of day when the lowest concentrations occur, to provide allergic individuals the optimal time to ventilate their homes. The study was carried out in three Central European capitals, Berlin (Germany), Paris-Saclay (France), and Luxembourg (Luxembourg), as well as in eight stations in Germany (Altötting, Feucht, Garmisch-Partenkirchen, Hof, Marktheidenfeld, Mindelheim, Munich and Viechtach). The diurnal rhythm of these eleven locations was analyzed for either the complete, first week, peak week, peak day and last week of the pollen season. The data studied were reported as pollen/m3 measured in 3 h periods. Stations were classified as city, semi-populated or countryside areas using land-use and population density criteria. Grass pollen has a more pronounced diurnal rhythm than birch pollen concentrations. A significant difference was observed when comparing day (6-21 h) versus night (21-6 h) for all stations. No difference was detected between city and countryside for both pollen types, although for Poaceae a longer period of maximum concentrations was observed in big cities and higher day/night-time differences were registered in the countryside (6.4) than in cities (3.0). The highest pollen concentrations were observed between 9 and 18 h for grass, but the rhythm was less pronounced for birch pollen. For allergic individuals who want to bring in fresh air in their homes, we recommend opening windows after 21 h, but even better early in the morning between 6 and 9 h before pollinations (re)starts.

A novel application of thermogravimetry-mass spectrometry for polystyrene quantification in the PM10 and PM2.5 fractions of airborne microplastics.

Microplastics have appeared as emerging pollutants due to the diverse applications of plastics in today's world. Growing evidence points to the negative impacts that airborne microplastics have on human health, as they can enter the human body through respiration. Our aim was to quantify polystyrene airborne microplastics in smaller fractions, thoracic (PM10) and alveolar (PM2.5), as they have scarcely been studied. In this work, we proposed a methodology based on thermogravimetric analysis coupled with mass spectrometry that requires minimal sample preparation and does not limit particle size. We applied this methodology to quantify the airborne polystyrene in PM10 and PM2.5 fractions in mass units of microplastics per m3 of air in an urban and agricultural region during the summer of 2021. The mean concentrations of polystyrene found in the PM10 and PM2.5 fractions were 2.09 and 1.81 ng m-3, respectively. Therefore, the majority of airborne polystyrene microplastics are found in the alveolar fraction which, is associated with severe cardiopulmonary and respiratory diseases. According to air mass backward trajectories, it was noted that the main sources of these emerging pollutants could be related to local agricultural practices.