Smartphone-based detection and discrimination of amine vapors by a single dye-adsorbed material.

Smartphone-assisted analysis has become widely utilized for detecting various species in recent years. In such studies, multiple dyes should be employed to ensure selectivity and analyte discrimination. In our research, we have demonstrated the capability of a specially synthesized dye to selectively detect and discriminate liquid amine vapors. The developed material employs meso-toluene-α,ß,α',ß'-tetrabromoBODIPY immobilized on a thin-layer chromatography plate, exhibiting structure-specific color changes in response to amine vapors. The hue values of these colors, observed under both ambient and UV light, enable discrimination even among closely related amine structures. A mobile application has also been developed for the rapid interpretation of test results.

Recent Advances in Chemodosimeters Designed for Amines.

The analysis of amines has long been a very important task in science, industry, and healthcare. To date, this task has been accomplished by using expensive and time-consuming methods. Colorimetric and fluorescent chemodosimeters enable the fast, accurate, and sensitive analysis of various species with inexpensive instruments or the naked eye. Accordingly, the studies on these probes have gained great momentum in the last 20 years. In this review, amine chemodosimeters developed in the last 10 years were investigated. The investigated chemodosimeters are metal-free structures based on small organic compounds. The strategies for the detection, differentiation, and quantification of amines were discussed by considering the reaction types.

The Stability of Unsubstituted BOPHY in Various Media.

In this communication, we report our findings on the stability of unsubstituted BOPHY in different media. Our studies showed that unsubstituted BOPHY is highly unstable in water, methanol, and DMSO. The dye was observed to be stable in aprotic and/or relatively apolar solvents (ACN, acetone, DCM, and toluene) for a routine application. The pH of the medium was shown to affect the stability of the dye dramatically. Herein, we also presented a one-pot procedure for the synthesis of the dye.

Rationally Designed Fluorescent pH Sensors for Measurements in Extremely Alkaline Media.

We investigated the pKa increasing effects on meso-phenol BODIPY to achieve fluorescent pH sensors working in extreme alkalinity. We demonstrated the effects of substituents on meso, α, γ and position of the hydroxyl group on pKa. By considering these parameters, we developed pH sensors working above 11.0 in aqueous medium (ethanol/water 1:1). One of these sensors had a pKa of 12.0 and enabled the measurement of pH up to 13.6. This highly photostable and bright sensor compound could be synthesized easily from cheap starting materials.