ABSTRACT
Miniaturization and mass-production of potentiometric sensor systems is paving the way towards distributed environmental sensing, on-body measurements and industrial process monitoring. Inkjet printing is gaining popularity as a highly adaptable and scalable production technique. Presented here is a scalable and low-cost route for flexible solid-contact ammonium ion-selective electrode fabrication by inkjet printing. Utilization of inkjet-printed melamine-intercalated graphene nanosheets as the solid-contact material significantly improved charge transport, while evading the detrimental water-layer formation. External polarization was investigated as a means of improving the inter-electrode reproducibility: the standard deviations of E0 values were reduced after electrode polarization, the linear region of the response was extended to the range 10-1-10-6 M of NH4Cl and LODs reduced to 0.88 ± 0.17 µM. Finally, we have shown that the electrodes are adequate for measurements in a complex real sample: ammonium concentration was determined in landfill leachate water, with less than 4 % deviation from the reference method.
ABSTRACT
The large-scale manufacturing of flexible electronics is nowadays based on inkjet printing technology using specially formulated conductive inks, but achieving adequate wetting of different surfaces remains a challenge. In this work, the development of a silver nanoparticle-based functional ink for printing on flexible paper and plastic substrates is demonstrated. Amphiphilic silver nanoparticles with narrow particle size distribution and good dispersibility were prepared via a two-step wet chemical synthesis procedure. First, silver nanoparticles capped with poly(acrylic acid) were prepared, followed by an amidation reaction with 3-morpholynopropylamine (MPA) to increase their lipophilicity. Density functional theory (DFT) calculations were performed to study the interactions between the particles and the dispersion medium in detail. The amphiphilic nanoparticles were dispersed in solvents of different polarity and their physicochemical and rheological properties were determined. A stable ink containing 10 wt% amphiphilic silver nanoparticles was formulated and inkjet-printed on different surfaces, followed by intense pulsed light (IPL) sintering. Low sheet resistances of 3.85 Ω sq-1, 0.57 Ω sq-1 and 19.7 Ω sq-1 were obtained for the paper, coated poly(ethylene terephthalate) (PET) and uncoated polyimide (PI) flexible substrates, respectively. Application of the nanoparticle ink for printed electronics was demonstrated via a simple flexible LED circuit.
ABSTRACT
With the growing number of flexible electronics applications, environmentally benign ways of mass-producing graphene electronics are sought. In this study, we present a scalable mechanochemical route for the exfoliation of graphite in a planetary ball mill with melamine to form melamine-intercalated graphene nanosheets (M-GNS). M-GNS morphology was evaluated, revealing small particles, down to 14 nm in diameter and 0.4 nm thick. The M-GNS were used as a functional material in the formulation of an inkjet-printable conductive ink, based on green solvents: water, ethanol, and ethylene glycol. The ink satisfied restrictions regarding stability and nanoparticle size; in addition, it was successfully inkjet printed on plastic sheets. Thermal and photonic post-print processing were evaluated as a means of reducing the electrical resistance of the printed features. Minimal sheet resistance values (5 kΩ/sq for 10 printed layers and 626 Ω/sq for 20 printed layers) were obtained on polyimide sheets, after thermal annealing for 1 h at 400 °C and a subsequent single intense pulsed light flash. Lastly, a proof-of-concept simple flexible printed circuit consisting of a battery-powered LED was realized. The demonstrated approach presents an environmentally friendly alternative to mass-producing graphene-based printed flexible electronics.