Groundwater contamination pathways of phthalates and bisphenol A: origin, characteristics, transport, and fate - A review.

Phthalic acid esters (PAEs) or phthalates and bisphenol A (BPA) are emerging organic contaminants (EOCs) that may harm biota and human health. Humans can be exposed to these contaminants by drinking water consumption from water sources such as groundwater. Before their presence in aquifer systems, phthalates and BPA can be found in many matrices due to anthropogenic activities, which result in long-term transport to groundwater reservoirs by different mechanisms and reaction processes. The worldwide occurrence of phthalates and BPA concentrations in groundwater have ranged from 0.1 × 10-3 to 3 203.33 µg L-1 and from 0.09 × 10-3 to 228.04 µg L-1, respectively. Therefore, the aim of this review is to describe the groundwater contamination pathways of phthalates and BPA from the main environmental sources to groundwater. Overall, this article provides an overview that integrates phthalate and BPA environmental cycling, from their origin to human reception via groundwater consumption. Additionally, in this review, the readers can use the information provided as a principal basis for existing policy ratification and for governments to develop legislation that may incorporate these endocrine disrupting compounds (EDCs) as priority contaminants. Indeed, this may trigger the enactment of regulatory guidelines and public policies that help to reduce the exposure of these EDCs in humans by drinking water consumption.

Influence of sediment parameters on the distribution and fate of PAHs in an estuarine tropical region located in the Brazilian semi-arid (Jaguaribe River, Ceará coast).

18 polycyclic aromatic hydrocarbons (PAHs) were evaluated in the Jaguaribe River to explore the influence of grain size, organic carbon, humic and fulvic acids and black carbon on their adsorption onto sediment. The ∑PAHs concentrations variated from 0.6 to 3752.0 ng g-1 with highest concentrations in the estuarine zone. The PAHs predominant source along the river was from mixed sources, mainly related to biomass combustion, small oil spills related to recreational nautical activities and runoff from cities. Organic and inorganic parameters presented influence on PAHs distribution along the river, with humic acid as a determinant factor. These research findings are of importance to an assessment of the fate and transport of PAHs in estuarine systems.