Broadband Enhancement of Magneto-Optical Effects in Hybrid Waveguide-Plasmonic Surfaces for Sensing.

Conventional magnetophotonic nanostructures typically function within narrow wavelength and incident angle ranges, where resonance is observed and magneto-optical (MO) effects are amplified. Expanding these operational ranges may allow for improved applications, including in (bio)sensing devices. In this study, we describe a hybrid magnetoplasmonic waveguide grating (HMPWG) in which the coupling of plasmonic resonances and waveguide modes leads to enhanced MO effects and sensitivity, according to full-wave electromagnetic simulations. High transverse magneto-optical Kerr effect (TMOKE) signals were observed for the full range of wavelengths and angles investigated, i.e., for θinc ≥ 1° and 500 nm ≤ λ ≤ 850 nm. As a proof-of-concept we verified that using the HMPWG nanostructure with an aqueous solution as superstrate one may obtain a sensitivity in variation of the refractive index unit (RIU) of S = 166°/RIU and S = 230 nm/RIU in angle and wavelength interrogation modes, respectively. Upon comparing with conventional magnetoplasmonic gratings, which only enable excitation of plasmonic resonances, we demonstrate that HMPWG nanostructures can be further optimized to reach not only high sensitivity but also high resolution in sensing and biosensing.

Green Ultrasound-Assisted Synthesis of Surface-Decorated Nanoparticles of Fe3O4 with Au and Ag: Study of the Antifungal and Antibacterial Activity.

This work proposes a sonochemical biosynthesis of magnetoplasmonic nanostructures of Fe3O4 decorated with Au and Ag. The magnetoplasmonic systems, such as Fe3O4 and Fe3O4-Ag, were characterized structurally and magnetically. The structural characterizations reveal the magnetite structures as the primary phase. Noble metals, such as Au and Ag, are present in the sample, resulting in a structure-decorated type. The magnetic measurements indicate the superparamagnetic behavior of the Fe3O4-Ag and Fe3O4-Au nanostructures. The characterizations were carried out by X-ray diffraction and scanning electron microscopy. Complementarily, antibacterial and antifungal assays were carried out to evaluate the potential properties and future applications in biomedicine.

Design of Nanoarchitectures for Magnetoplasmonic Biosensing with Near-Zero-Transmittance Conditions.

Nanostructures exhibiting large transverse magneto-optical Kerr effect (TMOKE) are required for magnetoplasmonic biosensing if the aim is the minituarization and integration into microfluidic devices. In this work, we present a general strategy to design nanoarchitectures with enhanced TMOKE, which consist of an arrangement of gold ribs deposited on an magneto-optical (MO) dielectric slab of Bi:YIG (bismuth-substituted yttrium iron garnet) with a SiO2 substrate surrounded by water. Using the finite element method (FEM), we demonstrate numerically that the near-zero-transmittance condition is the most important requirement for high TMOKE values. This can be reached through geometric optimization of the nanoarchitecture by tuning the period, height, and width of the grating, thus leading to resonances at wavelengths where the MO dielectric slab has high MO activity. We also show that the TMOKE amplitude can be further increased if losses in metal ribs are reduced. For a magnetoplasmonic grating with optimized geometry, we demonstrated the potential detection of biologically relevant analytes with sensitivity in the order of 102 nm/RIU (refractive index unit). Since the nanoarchitecture proposed is experimentally feasible with, e.g., nanolithography techniques, one may expect that the design strategy may inspire the development of efficient magnetoplasmonic sensing platforms.