Your browser doesn't support javascript.
loading
Show: 20 | 50 | 100
Results 1 - 20 de 451
Filter
1.
Sci Total Environ ; : 176631, 2024 Oct 04.
Article in English | MEDLINE | ID: mdl-39370000

ABSTRACT

Air pollution poses a critical global challenge with severe environmental and human health implications. The associated health risks, including premature mortality, underscore the urgency of effective mitigation strategies. Many studies focus on control strategies without considering specific contaminant types, and there is a notable gap in research on cost-effective, eco-friendly methods, especially in countries facing substantial air pollution challenges. This study aims to fill this gap by providing a comprehensive review of various air pollutants and proposing optimal passive design strategies for mitigating them in building facades. Through a structural process and comparative analysis of existing literature, this study evaluates the cost, maintenance, applicability of retrofitting, and removal efficacy of three categories of control strategies: bio-filtration, adsorbents, and water-based approaches. The results confirm that biological air purification systems are more effective than other methods at reducing PM2.5, PM10, and VOCs. Moreover, the cost analysis confirms that the more costly approaches are photocatalytic filters and metal-organic frameworks derived from the adsorbent solutions. Thus, the study suggests applying cost-effective techniques like facade biofiltration, and water-based curtain façade in areas with high air pollution. In terms of the applicability of retrofitting, the results ascertain adsorbent strategies are the most effective for reducing air pollutants in existing buildings followed by water-based methods. Considering limitations associated with certain strategies, such as the high cost and regular maintenance, this study proposes five integrated strategies for the effective control and removal of pollutants from building exteriors. By addressing these gaps in knowledge and offering practical insights, this research contributes valuable guidance for architects, policymakers, and practitioners in developing sustainable, efficient solutions to combat indoor air pollution effectively.

2.
Angew Chem Int Ed Engl ; : e202415051, 2024 Sep 30.
Article in English | MEDLINE | ID: mdl-39345005

ABSTRACT

Microscale zero-valent iron (mZVI) is widely used for water pollutant control and environmental remediation, yet its reactivity is still constrained by the inert oxide shell. Herein, we demonstrate that mechanochemical thioglycolate (TG) modification can dramatically enhance heavy metal (NiII, CrVI, CdII, PbII, HgII, and SbIII) removal rates of mZVI by times of 16.7 to 88.0. Compared with conventional impregnation (wet chemical process), this dry mechanochemical process could construct more robust covalent bonding between TG and the inert oxide shell of mZVI through its electron-withdrawing carboxylate group to accelerate the electron release from the iron core, and more effectively strengthen the surface heavy metal adsorption through metal(d)-sulfur(p) orbital hybridization between its thiol group and heavy metal ions. Impressively, this mechanochemically TG-modified mZVI exhibited an unprecedented NiII removal capacity of 580.4 mg Ni g-1 Fe, 17.1 and 9.5 times those of mZVI and wet chemically TG-modified mZVI, respectively. Its application potential was further validated by more than 10 days of stable groundwater NiII removal in a column flow reactor. This study offers a promising strategy to enhance the reactivity of mZVI, and also emphasizes the importance of the modification strategy in optimizing its performance for environmental applications.

3.
Front Microbiol ; 15: 1424687, 2024.
Article in English | MEDLINE | ID: mdl-39314884

ABSTRACT

Introduction: Thus far, the impact of kaolin mining activities on the surrounding native plants and rhizosphere microecology has not been fully understood. Methods: In this study, we used 16S rRNA high-throughput sequencing to examine the impact of kaolin mining on the rhizosphere bacterial communities and functions of three local plant species: Conyza bonariensis, Artemisia annua, and Dodonaea viscosa. Results: The results showed that kaolin mining significantly reduced the diversity of rhizosphere bacteria in these plants, as indicated by the Shannon, Simpson, Chao1, and observed species indices (p < 0.05). Kaolin mining had an impact on the recruitment of three rhizosphere bacteria native to the area: Actinoplanes, RB41, and Mycobacterium. These bacteria were found to be more abundant in the rhizosphere soil of three local plants than in bulk soil, yet the mining of kaolin caused a decrease in their abundance (p < 0.05). Interestingly, Ralstonia was enriched in the rhizosphere of these plants found in kaolin mining areas, suggesting its resilience to environmental stress. Furthermore, the three plants had different dominant rhizosphere bacterial populations in kaolin mining areas, such as Nocardioides, Pseudarthrobacter, and Sphingomonas, likely due to the unique microecology of the plant rhizosphere. Kaolin mining activities also caused a shift in the functional diversity of rhizosphere bacteria in the three local plants, with each plant displaying different functions to cope with kaolin mining-induced stress, such as increased abundance of the GlpM family and glucan-binding domain. Discussion: This study is the first to investigate the effects of kaolin mining on the rhizosphere microecology of local plants, thus contributing to the establishment of soil microecological health monitoring indicators to better control soil pollution in kaolin mining areas.

4.
J Environ Manage ; 370: 122499, 2024 Sep 17.
Article in English | MEDLINE | ID: mdl-39293115

ABSTRACT

Atmospheric pollutants PM2.5 and CO2 share similar sources and impact mechanisms. Green innovations and urban greening significantly reduce these pollutants while promoting economic growth. However, the synergies and trade-offs between carbon reduction, pollution control, green expansion, and economic growth remain understudied. This paper examines 110 cities in the Yangtze River Economic Belt (YREB), China's premier green development site, as a unified system. Using fractional-order synthesis analysis, this paper constructs an assessment indicator system and measures synergy with a coupled coordination degree model. The driving factors are explored using a system-generalized method of moments estimation. The findings indicate that most cities in the YREB are at an intermediate coordination stage. The coupling of greening with carbon reduction, pollution control, and growth has a low degree, highlighting an urgent need to strengthen greening efforts. Key drivers include the digital economy, advanced industrial structure, innovative talent aggregation, infrastructure construction, financial investment, and marketization. The digital economy significantly influences all regions of the Yangtze River. Notable heterogeneity exists in the impact of other drivers across different regions. These results offer valuable policy insights for managing carbon emissions and pollutants, contributing to sustainable urban development.

5.
Water Res ; 266: 122433, 2024 Sep 11.
Article in English | MEDLINE | ID: mdl-39276477

ABSTRACT

Anthropogenic enrichment of phosphorus (P) in water environment can cause eutrophication, harmful algal blooms, and water quality deterioration. Adsorbents are often used for the removal and recovery of P from water, however, P is highly susceptible to re-release in anoxic benthic environments. As a response, this study prepared oxygen-carrying iron-rich biochar (O-Fe-BC) as an effective oxygen micro-nanobubble carrier (Q = 8.7024 cm³/g STP at 1.5 MPa) and P adsorbent (qm = 16.7097 mg P/g, q0.1 = 3.1974 mg P/g). Over the 90-day experimental period with O-Fe-BC, dissolved oxygen (DO) levels in the overlying water could maintain at ∼4 mg/L (peaking at ∼9.5 mg/L), and total phosphorus (TP) and soluble reactive phosphorus (SRP) levels decreased by over 96 %. The higher inorganic phosphorus content in the surface sediment-biochar mixture, along with the lower labile P and Fe concentration in the sediment pore water in the O-Fe-BC group compared to other groups, suggested the enhanced P immobilization. Further mechanism exploration revealed the combined roles of adsorption and microbial response, in which O-Fe-BC achieved efficient phosphate adsorption primarily through inner-sphere complexation via ligand exchange and keystone taxa (particularly Candidatus Electronema) played a crucial role in driving water chemistry divergence. Specially, these cable bacteria could provide large pools of Fe oxides in the surface sediment, binding with P to prevent its release, as supported by significant correlations between Ca. Electronema abundance and oxidation-reduction potential (ORP), TP, SRP, and sediment Fe-P variations. Additionally, a pot experiment with mung bean seedlings showed that the recovered O-Fe-BC significantly promoted the seed germination and growth, indicating its potential as a novel material for removing and recovering P from eutrophic waters. Taken together, our work provided a promising strategy for sustainable anoxia and P pollution mitigation, and also highlighted the indispensable roles of inner-sphere adsorption in P recovery and microbial keystone taxa in P cycling regulation.

6.
J Hazard Mater ; 479: 135716, 2024 Nov 05.
Article in English | MEDLINE | ID: mdl-39236543

ABSTRACT

Condensable particulate matter (CPM) and filterable particulate matter (FPM) emitted from industrial sources have been well studied, but their emissions from vehicles have not yet been covered. This study explores the emission characteristics of CPM and FPM from typical diesel vehicles under various driving conditions. The emission factors (EFs) of CPMs under driving conditions were 5.4-10.4 times higher than those of FPMs, while CPMs EFs under transient driving conditions were about 2.5 times higher than those under steady driving conditions. CPM and FPM are mainly composed of organic matter accounting for 53.3 %-92.9 %, while the intermediate and semi-volatile organic compounds dominate the organic matter accounting for 86.3 %-98.6 %. Similar to industrial sources, alkanes are the predominant organic species emitted by diesel vehicles, comprising 42.0 %-64.0 % of the detected organic components. Inorganic CPM is primarily composed of NH4+ , representing 84.9 %-87.6 % of the total, in contrast to industrial sources where SO42- and Cl- dominate. Interestingly, the air pollution control devices installed on diesel vehicles under steady driving conditions perform better in removing organic CPM and producing higher inorganic CPM emissions than those under transient driving conditions. These findings will enhance the comprehensive understanding of particulate matter emitted from diesel vehicles and provide a scientific foundation for the development of related control technologies.

7.
Sci Total Environ ; 954: 176193, 2024 Sep 14.
Article in English | MEDLINE | ID: mdl-39278488

ABSTRACT

Heavy metal contamination is a huge hazard to the environment and human health, and research into removing heavy metals from their primary sources (industrial and agricultural wastes) has increased significantly. Adsorption has received interest due to its distinct benefits over other treatment approaches. The distinctive qualities of clay minerals, such as their high specific surface area, strong cation exchange capacity, and varied structures, make them particularly ideal for use in the manufacture of adsorbents. The customizable structure and performance of clay minerals allow for unprecedented diversity in adsorbent creation, opening up new possibilities for the development of high-efficiency and functional adsorption technologies. In this review, various approaches for developing optimal adsorbents from raw materials are presented. Then, the correlation between functionalization and performance is investigated, focusing on the effects of structural features and surface properties on adsorption performance. The research progress on the synthesis of adsorbents using clay minerals and other functional materials is systematically reported. Finally, the challenges and opportunities in designing and utilizing innovative clay mineral adsorbents are discussed.

8.
Heliyon ; 10(16): e36289, 2024 Aug 30.
Article in English | MEDLINE | ID: mdl-39247297

ABSTRACT

Presently, China is actively endorsing the pilot initiative for the remunerative use and trading of emission. By examining the operation and efficacy of emission trading in the context of water pollution control, one can contribute to the advancement and refinement of this system, thereby facilitating the attainment of regional pollution reduction, carbon reduction, and high-quality development objectives. In pursuit of this objective, we develop a theoretical framework for the local government and sewage enterprises evolutionary game of water pollution control, which includes two scenarios without considering and considering emission trading for studying the influencing factors and evolution trajectory of the game subject's. Through the stability analysis, the game interactive mechanism, the difference in evolutionary trajectory, and the response logic of the decision-making body in different situations become clearly visible. Further, the system sensitivity factors are analyzed by solving the partial derivation of the area formula of the phase diagram. And the efficacy of the sewage trading system in water pollution control in Zhejiang Province is empirically examined at the micro level by adopting the trading data of the first pilot area of sewage trading in the country and the case of pollution control in Jinhua City. The research reveals the following conclusions: Under specific circumstances, emission trading can incentivize businesses and even industries to enhance pollution control measures as a whole. The performance and degree of sensitivity factors vary across gaming systems, with public reputation evaluation and central government inspection serving as positive constraints. The initial cost of paid use of emission permits, as a fixed cost component for firms to address pollution, has no effect on the enterprises' behavioral actions to satisfy emission regulations. The findings can furnish local governments with a theoretical foundation and decision support in order to optimize regulatory strategies and enhance pollution control policies.

9.
Environ Sci Technol ; 58(40): 17797-17806, 2024 Oct 08.
Article in English | MEDLINE | ID: mdl-39344077

ABSTRACT

Nitric oxide (NO) is one of the major air pollutants that may cause ecological imbalance and severe human disease. However, the removal of NO faces challenges of low efficiency, high energy consumption, and production of toxic NO2 byproducts. Herein, we report an efficient *OOH intermediate-involved NO oxidation route with high NO3- selectivity via a gas phase photo-Fenton system. Fe single atoms (Fe SAs)-anchored NH2-UiO-66(Zr) (Fe SAs@NU) was synthesized. The five-coordinated Fe SAs undergo a transient structure reconstitution during the photo-Fenton process, which enables a novel heterolytic cleavage pathway of H2O2 to derive specific ·OOH/·O2- radicals as reactive oxygen species. Therefore, a high NO (550 parts per billion) removal rate of 81% (NO3- selectivity up to 99%) is achieved under visible-light irradiation (>420 nm). This study provides new insight for the high-performance photo-Fenton process via a transient structure reconstitution pathway for the removal of gas phase NOx pollutants.


Subject(s)
Hydrogen Peroxide , Nitric Oxide , Oxidation-Reduction , Nitric Oxide/chemistry , Hydrogen Peroxide/chemistry , Iron/chemistry , Air Pollutants/chemistry
10.
Environ Pollut ; 361: 124806, 2024 Aug 23.
Article in English | MEDLINE | ID: mdl-39182815

ABSTRACT

Elemental mercury (Hg0) removal is a crucial target for mercury pollution control in flue gas. This article focuses on Hg0 removal in flue gas using corona discharge (CD) and dielectric barrier discharge (DBD) technologies, and provides a mechanistic perspective on the development and influencing factors of non-thermal plasma (NTP) technology for Hg0 removal. The influence factors include reactor configurations, power supplies, energy density, residence time, oxidation methods, gas composition, and the synergy between NTP and catalysis/adsorption, etc. This study reveals that the use of a pulsating electrical power supply significantly increases electron densities in both CD and DBD systems, thereby ensuring high energy efficiency and economic viability. Cl2 proves to be more effective than HCl as a chlorine source for Hg0 removal. NO significantly reduces Hg0 oxidation efficiency, while the effects of SO2 and H2O remain unclear. Energy density distribution is closely related to plasma devices, power supplies, and overall reactor configurations. Direct oxidation proves to be more effective than indirect oxidation for Hg0 removal. The combination of NTP with adsorption/catalysis technologies shows significantly better Hg0 removal efficiency compared to using NTP alone. This study can provide theoretical support for enhancing Hg0 removal mechanisms and optimizing process control parameters in industrial applications of NTP technology.

11.
Environ Monit Assess ; 196(9): 776, 2024 Aug 02.
Article in English | MEDLINE | ID: mdl-39095670

ABSTRACT

The oil industry in Khuzestan province (Southwest Iran) is one of the main reasons contributing to the pollution of the environment in this area. TPH, including both aromatic and aliphatic compounds, are important parameters in creating pollution. The present study aimed to investigate the source of soil contamination by TPH in the Ahvaz oil field in 2022. The soil samples were collected from four oil centers (an oil exploitation unit, an oil desalination unit, an oil rig, and a pump oil center). An area outside the oil field was determined as a control area. Ten samples with three replicates were taken from each area according to the standard methods. Aromatic and aliphatic compounds were measured by HPLC and GC methods. The positive matrix factorization (PMF) model and isomeric ratios were used to determine the source apportionment of aromatic compounds in soil samples. The effects range low and effects range median indices were also used to assess the level of ecological risk of petroleum compounds in the soil samples. The results showed that Benzo.b.fluoranthene had the highest concentration with an average of 5667.7 ug/kg in soil samples in the Ahvaz oil field. The highest average was found in samples from the pump oil center area at 7329.48 ug/kg, while the lowest was found in control samples at 1919.4 ug/kg-1. The highest level of aliphatic components was also found in the pump oil center, with a total of 3649 (mg. Kg-1). The results of source apportionment of petroleum compounds in soil samples showed that oil activities accounted for 51.5% of the measured PAHs in soil. 38.3% of other measured compounds had anthropogenic origins, and only 10.1% of these compounds were of biotic origin. The results of the isomeric ratios also indicated the local petroleum and pyrogenic origin of PAH compounds, which is consistent with the PMF results. The analysis of ecological risk indices resulting from the release of PAHs in the environment showed that, except for fluoranthene, other PAHs in the oil exploitation unit area were above the effects range median level (ERM) and at high risk. The results of the study showed that soil pollution by total petroleum hydrocarbons (TPH), both aromatic and aliphatic, is at a high level, and is mainly caused by human activities, particularly oil activities.


Subject(s)
Environmental Monitoring , Petroleum Pollution , Petroleum , Soil Pollutants , Soil , Soil Pollutants/analysis , Petroleum/analysis , Petroleum Pollution/analysis , Soil/chemistry , Iran , Oil and Gas Fields , Hydrocarbons/analysis
12.
J Hazard Mater ; 478: 135428, 2024 Oct 05.
Article in English | MEDLINE | ID: mdl-39137544

ABSTRACT

Human health risks from particles with a diameter of less than 2.5 µm (PM2.5) highlight the role of urban trees as bio-filters in air pollution control. However, whether the size and composition of particles captured by various tree species differ or not remain unclear. This study investigates how leaf attributes affect the capture of PM2.5, which can penetrate deep into the lungs and pose significant health risks. Using a self-developed particulate matter (PM) resuspension chamber and single-particle aerosol mass spectrometer, we measured the size distribution and mass spectra of particles captured by ten tree species. Notably, Cinnamomum camphora (L.) J.Presl and Osmanthus fragrans Lour. are more effective at capturing particles under 1 µm, which are most harmful because they can reach the alveoli, whereas Ginkgo biloba L. and Platanus × acerifolia (Aiton) Willd. tend to capture larger particles, up to 1.6 µm, which are prone to being trapped in the upper respiratory tract. Leaf physiological traits such as stomatal conductance and water potential significantly enhance the capture of larger particles. The Adaptive Resonance Theory neural network (ART-2a) algorithm classified a large number of single particles to determine their composition. Results indicate distinct inter-species variations in chemical composition of particles captured by leaves. Moreover, we identified how specific leaf wax compositions-beyond the known sticky nature of hydrophobic waxes-contribute to particle adhesion, particularly highlighting the roles of fatty acids and alkanes in adhering particles rich in organic carbon and heavy metals, respectively. This research advances our understanding by linking leaf physiological and wax characteristics to the selective capture of PM2.5, providing actionable insights for urban forestry management. The detailed exploration of particle size and composition, tied to specific tree species, enriches the current literature by quantifying how and why different species contribute variably to air quality improvement. This adds a crucial layer of specificity to the general knowledge that trees serve as bio-filters, offering a refined strategy for planting urban trees based on their particulate capture profiles.


Subject(s)
Air Pollutants , Particle Size , Particulate Matter , Plant Leaves , Trees , Waxes , Particulate Matter/analysis , Particulate Matter/chemistry , Plant Leaves/chemistry , Waxes/chemistry , Air Pollutants/analysis , Air Pollutants/chemistry , Cities , Air Pollution/analysis , Neural Networks, Computer
13.
J Hazard Mater ; 478: 135390, 2024 Oct 05.
Article in English | MEDLINE | ID: mdl-39163730

ABSTRACT

The efficient removal of fine particles from coal-fired flue gas poses challenges for conventional electrostatic precipitators and bag filters. Recently, a novel approach incorporating deep cooling of the flue gas has been proposed to enhance the removal of gaseous pollutants and particles. However, the achievable efficiency and underlying mechanisms of particle capture within the gas cooling system remain poorly understood. This study aims to elucidate the effectiveness of gas cooling in enhancing the removal of particles through a laboratory-scale spray tower equipped with packing materials. The results demonstrate a significant increase in particle removal efficiency, from 63.4 % to over 98 %, as the temperature of the spray liquid decreases from 20℃ to -20℃. Notably, this enhancement is particularly pronounced for particles sized 0.1-1 µm, with efficiency rising from approximately 40 % to 95 %, effectively eliminating the penetration window. Moreover, we find that the spray flow rate positively influences particle removal capability, while the height of the packing section exhibits an optimal value. Beyond this optimal height, particle removal performance may decline due to an inadequate liquid-to-packing ratio. To provide insight into the capture process, we introduce a single-droplet model demonstrating that particle capture is primarily enhanced through the augmented thermophoretic force.

14.
Environ Sci Technol ; 58(35): 15381-15394, 2024 Sep 03.
Article in English | MEDLINE | ID: mdl-39136294

ABSTRACT

China is confronting the dual challenges of air pollution and climate change, mandating the co-control of air pollutants and CO2 emissions from their shared sources. Here we identify key sources for co-control that prioritize the mitigation of PM2.5-related health burdens, given the homogeneous impacts of CO2 emissions from various sources. By applying an integrated analysis framework that consists of a detailed emission inventory, a chemical transport model, a multisource fused dataset, and epidemiological concentration-response functions, we systematically evaluate the contribution of emissions from 390 sources (30 provinces and 13 socioeconomic sectors) to PM2.5-related health impacts and CO2 emissions, as well as the marginal health benefits of CO2 abatement across China. The estimated source-specific contributions exhibit substantial disparities, with the marginal benefits varying by 3 orders of magnitude. The rural residential, transportation, metal, and power and heating sectors emerge as pivotal sources for co-control, with regard to their relatively large marginal benefits or the sectoral total benefits. In addition, populous and heavily industrialized provinces such as Shandong and Henan are identified as the key regions for co-control. Our study highlights the significance of incorporating health benefits into formulating air pollution and carbon co-control strategies for improving the overall social welfare.


Subject(s)
Air Pollutants , Air Pollution , Carbon Dioxide , China , Carbon Dioxide/analysis , Air Pollutants/analysis , Particulate Matter/analysis , Climate Change , Environmental Monitoring
15.
Chemosphere ; 364: 143026, 2024 Sep.
Article in English | MEDLINE | ID: mdl-39121964

ABSTRACT

The presence of polybrominated diphenyl ethers (PBDEs) in consumer products, waste treatment processes, and treated ashes poses a significant environmental threat. Due to the lack of research on the removal of PBDEs during waste incineration, this study investigated the effectiveness of a Hazardous Waste Thermal Treatment System (HAWTTS) utilizing reburning of sludge and fly ash (SFA) with gasification-moderate or intense low-oxygen dilution (GASMILD) combustion for PBDE removal. The closed-loop treatment of sludge and ash within the HAWTTS provides a potential pathway for near-zero PBDE emissions. The GASMILD combustion addresses potential combustion issues associated with fly ash recirculation. The system achieved an impressive overall removal efficiency of 98.4% for PBDEs, with minimal stack emissions (2.45 ng/Nm³) and a negative net discharge rate (-1.02 µg/h). GASMILD combustion played a crucial role (92.7%-97.6% destruction) in addressing challenges associated with high-moisture feedstocks and SFA residues. Debromination of highly brominated PBDEs occurred within the incinerator, resulting in an increased proportion of lower brominated PBDEs in the bottom slag compared to the feedstock. Air Pollution Control Devices (APCDs) achieved a total PBDE removal efficiency of 74.4%. However, the hydrophobic nature of PBDEs limited removal efficiency in scrubbers (36.0%) and cyclonic demisters (37.86%). This study demonstrates that reintroducing SFA into the GASMILD combustion process offers an effective and environmentally sustainable strategy for reducing net PBDE levels in hazardous waste. This approach also provides additional benefits such as energy conservation, reduced carbon emissions, and lower operating costs associated with secondary treatment of thermally treated byproducts.


Subject(s)
Coal Ash , Halogenated Diphenyl Ethers , Hazardous Waste , Incineration , Sewage , Coal Ash/chemistry , Halogenated Diphenyl Ethers/analysis , Sewage/chemistry , Hazardous Waste/analysis , Air Pollutants/analysis
16.
Water Sci Technol ; 89(12): 3309-3324, 2024 Jun.
Article in English | MEDLINE | ID: mdl-39150426

ABSTRACT

Polyacrylamide (PAM) in environmental water has become a major problem in water pollution management due to its high molecular mass, high viscosity and non-absorption by soil. CoFe2O4 with strong magnetic properties was prepared by solvent-thermal synthesis method and used as the catalyst for the removal on PAM in heterogeneous Electro-Fenton (EF) system. It showed that the removal efficiency of PAM by the heterogeneous EF system using CoFe2O4 catalyst was 92.01% at pH 3 after 120 min. Further studies indicated that ·OH was the most significant active species for the removal of PAM, and the contribution of ·O2- and SO4·- for the removal of PAM was less than 15%. The reusability test and XRD, XPS, FTIR analyses proved that the catalyst had good stability. After a repeated use for five times, the catalyst still had a high PAM removal rate and stable structure. The valence distribution and functional groups of the phase components of the catalyst did not change significantly before and after the reaction. The possible mechanism of catalyst activation of H2O2 was deduced by mechanism investigation. The CoFe2O4 is an efficient and promising catalyst for the removal of PAM wastewater.


Subject(s)
Acrylic Resins , Cobalt , Ferric Compounds , Hydrogen Peroxide , Iron , Acrylic Resins/chemistry , Cobalt/chemistry , Catalysis , Hydrogen Peroxide/chemistry , Iron/chemistry , Ferric Compounds/chemistry , Water Pollutants, Chemical/chemistry , Water Purification/methods , Waste Disposal, Fluid/methods
17.
J Environ Manage ; 367: 122033, 2024 Sep.
Article in English | MEDLINE | ID: mdl-39096724

ABSTRACT

Landfill is an important means of municipal solid waste treatment. Previous studies have shown that the combination of "cut-off wall and pumping well" technology is an effective measure to deal with the leachate emission reduction and pollution control of landfill, and has been widely used in plain areas. However, for landfills in hilly areas with complex terrain and geological conditions, there is still a lack of clear and referable ideas and operational strategies for leachate emission reduction and pollution control. In this study, we proposed strategies for determining the position and depth of cut-off walls and pumping wells and reasonable combinations of the cut-off wall depth and pumping quantity for leachate reduction and pollution prevention of landfills in hilly areas. The determination of leachate reduction and pollution control strategy need to be achieved in two stages, qualitative and quantitative: (1) In the qualitative stage, the natural conditions (Weathering degree, groundwater flow characteristics, topography condition, hydrometeor condition, and aquifer thickness) and engineering conditions (Operation status, landfill location, and excavation status) of the study area are analysed in detail, and then the depth range and location of the cut-off wall and pumping well are determined. (2) In the quantitative stage, we need to quantify the combination of the cut-off wall depth and pumping quantity by using profile particle tracing and pollutant transport modelling. A reasonable cut-off wall depth needs to control the leakage of pollutants inside the wall, and a reasonable pumping quantity needs to ensure that the depth of the pollutant distribution is equivalent to the depth of the separation line, which separates the water flow towards the pumping well and the water flow downstream. (3) The effectiveness of the leachate reduction and prevention strategies proposed in this study was verified through an example of a landfill in Northeast China. This study provides a reference and operation method for leachate emission reduction and pollution control of landfills in hilly areas.


Subject(s)
Groundwater , Refuse Disposal , Waste Disposal Facilities , Water Pollutants, Chemical , Water Pollutants, Chemical/analysis , Refuse Disposal/methods , Environmental Monitoring
18.
J Environ Manage ; 367: 122017, 2024 Sep.
Article in English | MEDLINE | ID: mdl-39106803

ABSTRACT

In response to the dual challenges of air pollution control and carbon mitigation, China has strategically shifted its focus towards the synergistic reduction of air pollutants and CO2 emissions. This study identifies the potential areas and specific air pollutant species (including CO, NOx, and SO2) for co-reduction with carbon mitigation. We also reveal the driving forces behind the emissions of each air pollutant at both the national and regional scales. Our findings are as follows: (1) The potential for synergistic reduction of CO and SO2 with CO2 emissions has diminished in economically developed areas. There is a significant opportunity for co-reduction of SO2 and CO2 in the western and northern regions of China, particularly within Heilongjiang Province. (2) NOx is the key species for synergistic reduction with CO2 emissions across China, especially in the Chengyu Plain. (3) Cleaner production and the synergistic reduction effect are the primary contributors to national air pollutant reduction in China from 2008 to 2017. Conversely, efforts in economic development and energy efficiency have led to emission increases. Energy and industrial structures have only made limited contributions to emission reductions, and carbon mitigation shows an inhibition effect on emission reductions. These results offer valuable insights for developing targeted regional strategies for deeper air pollution control, considering the specific characteristics and needs of each region. Additionally, our findings highlight the importance of addressing policy misalignments and strengthening mutual-influence mechanisms between air pollution control and carbon mitigation, ensuring that policies for carbon reduction also effectively contribute to air quality improvements.


Subject(s)
Air Pollutants , Air Pollution , China , Air Pollution/prevention & control , Air Pollutants/analysis , Carbon/analysis , Carbon Dioxide/analysis , Environmental Monitoring
19.
Environ Sci Technol ; 2024 Aug 12.
Article in English | MEDLINE | ID: mdl-39133145

ABSTRACT

In the pursuit of carbon neutrality, China's 2060 targets have been largely anchored in reducing greenhouse gas emissions, with less emphasis on the consequential benefits for air quality and public health. This study pivots to this critical nexus, exploring how China's carbon neutrality aligns with the World Health Organization's air quality guidelines (WHO AQG) regarding fine particulate matter (PM2.5) exposure. Coupling a technology-rich integrated assessment model, an emission-concentration response surface model, and exposure and health assessment, we find that decarbonization reduces sulfur dioxide (SO2), nitrogen oxides (NOx), and PM2.5 emissions by more than 90%; reduces nonmethane volatile organic compounds (NMVOCs) by more than 50%; and simultaneously reduces the disparities across regions. Critically, our analysis reveals that further targeted reductions in air pollutants, notably NH3 and non-energy-related NMVOCs, could bring most Chinese cities into attainment of WHO AQG for PM2.5 5 to 10 years earlier than the pathway focused solely on carbon neutrality. Thus, the integration of air pollution control measures into carbon neutrality strategies will present a significant opportunity for China to attain health and environmental equality.

20.
Glob Health Res Policy ; 9(1): 30, 2024 Aug 21.
Article in English | MEDLINE | ID: mdl-39164785

ABSTRACT

BACKGROUND: Air pollution poses a significant threat to global public health. While broad mitigation policies exist, an understanding of the economic consequences, both in terms of health benefits and mitigation costs, remains lacking. This study systematically reviewed the existing economic implications of air pollution control strategies worldwide. METHODS: A predefined search strategy, without limitations on region or study design, was employed to search the PubMed, Scopus, Cochrane Library, Embase, Web of Science, and CEA registry databases for studies from their inception to November 2023 using keywords such as "cost-benefit analyses", "air pollution", and "particulate matter". Focus was placed on studies that specifically considered the health benefits of air pollution control strategies. The evidence was summarized by pollution control strategy and reported using principle economic evaluation measurements such as net benefits and benefit-cost ratios. RESULTS: The search yielded 104 studies that met the inclusion criteria. A total of 75, 21, and 8 studies assessed the costs and benefits of outdoor, indoor, and mixed control strategies, respectively, of which 54, 15, and 3 reported that the benefits of the control strategy exceeded the mitigation costs. Source reduction (n = 42) and end-of-pipe treatments (n = 15) were the most commonly employed pollution control methodologies. The association between particulate matter (PM) and mortality was the most widely assessed exposure-effect relationship and had the largest health gains (n = 42). A total of 32 studies employed a broader benefits framework, examining the impacts of air pollution control strategies on the environment, ecology, and society. Of these, 31 studies reported partially or entirely positive economic evidence. However, despite overwhelming evidence in support of these strategies, the studies also highlighted some policy flaws concerning equity, optimization, and uncertainty characterization. CONCLUSIONS: Nearly 70% of the reviewed studies reported that the economic benefits of implementing air pollution control strategies outweighed the relative costs. This was primarily due to the improved mortality and morbidity rates associated with lowering PM levels. In addition to health benefits, air pollution control strategies were also associated with other environmental and social benefits, strengthening the economic case for implementation. However, future air pollution control strategy designs will need to address some of the existing policy limitations.


Subject(s)
Air Pollution , Cost-Benefit Analysis , Air Pollution/prevention & control , Air Pollution/economics , Humans , Particulate Matter/analysis , Particulate Matter/adverse effects
SELECTION OF CITATIONS
SEARCH DETAIL