A Novel Dry Treatment for Municipal Solid Waste Incineration Bottom Ash for the Reduction of Salts and Potential Toxic Elements.

The main obstacle to bottom ash (BA) being used as a recycling aggregate is the content of salts and potential toxic elements (PTEs), concentrated in a layer that coats BA particles. This work presents a dry treatment for the removal of salts and PTEs from BA particles. Two pilot-scale abrasion units (with/without the removal of the fine particles) were fed with different BA samples. The performance of the abrasion tests was assessed through the analyses of particle size and moisture, and that of the column leaching tests at solid-to-liquid ratios between 0.3 and 4. The results were: the particle-size distribution of the treated materials was homogeneous (25 wt % had dimensions <6.3 mm) and their moisture halved, as well as the electrical conductivity of the leachates. A significant decrease was observed in the leachates of the treated BA for sulphates (44%), chlorides (26%), and PTEs (53% Cr, 60% Cu and 8% Mo). The statistical analysis revealed good correlations between chloride and sulphate concentrations in the leachates with Ba, Cu, Mo, and Sr, illustrating the consistent behavior of the major and minor components of the layer surrounding BA particles. In conclusion, the tested process could be considered as promising for the improvement of BA valorization.

Classification of plastic waste originated from waste electric and electronic equipment based on the concentration of antimony.

The aim of this research is a preliminary assessment of antimony concentration in plastic fractions deriving from different e-waste. We considered microwave ovens, desktop computers, laptops, mobile phones, a TV case, a PC monitor and LED lamps (63 items in total). The plastic fraction ranged from 8%-wt in computers and microwave ovens, up to 40%-wt in cell phones and 59%-wt in LED lamps. Specific polymers were identified through Near Infrared spectroscopy. The samples followed three parallel procedures: acid digestion with aqua regia; conversion into ashes at 600 °C then acid digestion with aqua regia; leaching according to UNI10802 reference procedure. Plastic components with significant amounts of antimony were the ones derived from desktop computers (25-1900 mg/kg) and from microwave ovens (830 mg/kg), yet their relative amount compared to the total weight of the item was limited. Items with larger plastic fractions showed lower concentrations of antimony (1-6 mg/kg in mobile phones cases and 160-640 mg/kg in plastic components of LED lamps). Leaching tests revealed that the analyzed plastic fractions could be mostly admitted in non-hazardous waste landfills. The analysis of ashed samples highlighted the need to further improve the acidic extraction procedure.