Dew benefits on alpine grasslands are cancelled out by combined heatwave and drought stress.

Increasing frequencies of heatwaves combined with simultaneous drought stress in Europe threaten the ecosystem water and carbon budgets of alpine grasslands. Dew as an additional water source can promote ecosystem carbon assimilation. It is known that grassland ecosystems keep high evapotranspiration as long as soil water is available. However, it is rarely being investigated whether dew can mitigate the impact of such extreme climatic events on grassland ecosystem carbon and water exchange. Here we use stable isotopes in meteoric waters and leaf sugars, eddy covariance fluxes for H2O vapor and CO2, in combination with meteorological and plant physiological measurements, to investigate the combined effect of dew and heat-drought stress on plant water status and net ecosystem production (NEP) in an alpine grassland (2000 m elevation) during the June 2019 European heatwave. Before the heatwave, enhanced NEP in the early morning hours can be attributed to leaf wetting by dew. However, dew benefits on NEP were cancelled out by the heatwave, due to the minor contribution of dew in leaf water. Heat-induced reduction in NEP was intensified by the combined effect of drought stress. The recovery of NEP after the peak of the heatwave could be linked to the refilling of plant tissues during nighttime. Among-genera differences of plant water status affected by dew and heat-drought stress can be attributed to differences in their foliar dew water uptake, and their reliance on soil moisture or the impact of the atmospheric evaporative demand. Our results indicate that dew influence on alpine grassland ecosystems varies according to the environmental stress and plant physiology.

Origin and percolation times of Milandre Cave drip water determined by tritium time series and beryllium-7 data from Switzerland.

Early observations of the tritium (3H) activity in precipitation from Switzerland started in 1967 in Bern and a monitoring program with improved analytical techniques was carried out between 1971 and 2009. Between 2012 and 2015, we performed tritium analyses on daily precipitation samples from north-western Switzerland to better constrain the tritium variability. We also collected waters dripping inside Milandre Cave (Jura Mountains) with a 4-6 months' resolution in order to estimate the age of the drip water, which is mandatory to interpret the high-resolution speleothem (cave carbonate deposits) records. Over the monitoring period, the mean tritium concentration in the daily precipitation samples was approximately 8.7 ± 4.7 TU with distinct seasonality showing higher values in spring and summer (from April-May to August-September). The similarity in trends with the other cosmogenic radionuclide beryllium-7 (7Be) suggests that, for the study site, tritium in precipitation essentially originates from stratospheric input in spring. In winter, precipitation dynamics with increasing moisture originating from the Atlantic and diluted during transport contribute to low values close to the Atlantic background. In cave drip water, the depleted activity level of tritium indicates a relatively long percolation time from the surface to the cave of several years. A residual superimposed short tritium variability provides evidence for the occurrence of fast flowing water paths. The contribution from both components were quantified based on a two-component lumped parameter-mixing model. Finally, we show that tritium concentrations in cave drip water are linked to the moisture origin and atmospheric transport pathways.

A global database of water vapor isotopes measured with high temporal resolution infrared laser spectroscopy.

The isotopic composition of water vapour provides integrated perspectives on the hydrological histories of air masses and has been widely used for tracing physical processes in hydrological and climatic studies. Over the last two decades, the infrared laser spectroscopy technique has been used to measure the isotopic composition of water vapour near the Earth's surface. Here, we have assembled a global database of high temporal resolution stable water vapour isotope ratios (δ18O and δD) observed using this measurement technique. As of March 2018, the database includes data collected at 35 sites in 15 Köppen climate zones from the years 2004 to 2017. The key variables in each dataset are hourly values of δ18O and δD in atmospheric water vapour. To support interpretation of the isotopologue data, synchronized time series of standard meteorological variables from in situ observations and ERA5 reanalyses are also provided. This database is intended to serve as a centralized platform allowing researchers to share their vapour isotope datasets, thus facilitating investigations that transcend disciplinary and geographic boundaries.

Marine versus Continental Sources of Iodine and Selenium in Rainfall at Two European High-Altitude Locations.

The essential elements selenium (Se) and iodine (I) are often present in low levels in terrestrial diets, leading to potential deficiencies. Marine I and Se emissions and subsequent atmospheric wet deposition has been suggested to be an important source of I and Se to soils and terrestrial food chains. However, the contribution of recycled moisture of continental origin to I and Se to precipitation has never been analyzed. Here we report concentrations and speciation of I and Se, as well as of bromine (Br), sulfur (S), and DOC-δ13C signatures for weekly collected precipitation samples (in the period of April 2015 to September 2016) at two high altitude sites, i.e., Jungfraujoch (JFJ; Switzerland) and Pic du Midi (PDM; France). Analysis of precipitation chemistry and moisture sources indicate combined marine and continental sources of precipitation and Se, I, Br, and S at both sites. At JFJ, concentrations of I and Se were highest when continental moisture sources were dominant, indicating important terrestrial sources for these elements. Furthermore, correlations between investigated elements and DOC-δ13C, particularly when continental moisture source contributions were high, indicate a link between these elements and the source of dissolved organic matter, especially for I (JFJ and PDM) and Se (JFJ).