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1.
J Mol Graph Model ; 131: 108808, 2024 Sep.
Article in English | MEDLINE | ID: mdl-38852428

ABSTRACT

Hydrogen energy has attracted a lot of interest from researchers as a sustainable and renewable energy source, but there are some technical challenges related to its storage. Hydride materials demonstrate the ability to store hydrogen adequately and safely. In the current study, we have investigated the structural and optoelectronic properties of the XCuH3 (where X = Li, Na and K) perovskite-type hydride using LDA and GGA formalisms for hydrogen storage application. Electronic properties such as band structure, density of states reveal the metallic character of the studied XCuH3 hydrides. Various optical parameters such as the complex dielectric function, refractive index, extinction coefficient, absorption coefficient, reflectivity, optical conductivity, energy loss function, and joint density of states have been computed and compared. The gravimetric hydrogen storage capacity for LiCuH3, NaCuH3 and KCuH3 are found to be 4.11, 3.37 and 2.86 wt%, respectively. The computed values of the gravimetric ratio manifest that XCuH3 hydrides are potential candidates for hydrogen storage applications. These calculations are made for the first time for XCuH3 hydrides and will be inspirational in the future for comparison and for hydrogen storage purposes.


Subject(s)
Calcium Compounds , Hydrogen , Oxides , Titanium , Hydrogen/chemistry , Calcium Compounds/chemistry , Titanium/chemistry , Oxides/chemistry , Sodium/chemistry , Lithium/chemistry , Potassium/chemistry , Models, Molecular
2.
Environ Monit Assess ; 196(5): 458, 2024 Apr 18.
Article in English | MEDLINE | ID: mdl-38635016

ABSTRACT

The poultry industry is a significant source of animal protein, vitamins, and minerals, particularly through the consumption of chicken meat. In order to conduct the study, 100 samples of liver, chicken feed, and drinking water were collected in nearby areas of Lahore. The investigation aims to detect the presence of specific heavy metals in the collected samples. For this purpose, atomic absorption spectroscopy (AAS) was used to detect heavy metals after proper preparation of the samples. The experimentally observed data were analyzed through a novel statistical approach known as neutrosophic statistics. It was observed that copper (Cu), zinc (Zn), and cadmium (Cd) were the most prominent metals detected with contamination above the safe limits (for chicken drinking water (Zn = 23.09±13.67 mg/L, Cu = 3.84±3.04 mg/L, Cd = 0.805±0.645 mg/L, Pb = 0.275±0.095 mg/L, As = 0.982±0.978 mg/L), for chicken feed (Zn = 2.705±0.715 mg/kg, Cu = 1.85±0.53 mg/kg, Cd = 3.065±1.185 mg/kg, Pb = 0.215±0.175 mg/kg, As = 0.68±0.22 mg/kg), and chicken's liver (Zn = 3.93±0.66 mg/kg, Cu = 1.2±0.52 mg/kg, Cd = 0.07±0.05 mg/kg, Pb = 0.805±0.775 mg/kg, As = 1.05±0.8 mg/kg)). Similarly, the statistical analysis leads that the findings emphasize the importance of monitoring and mitigating heavy metal contamination in the poultry industry to ensure the safety and quality of poultry products.


Subject(s)
Drinking Water , Metals, Heavy , Animals , Chickens , Cadmium , Pakistan , Lead , Environmental Monitoring , Zinc
3.
Environ Sci Pollut Res Int ; 30(36): 85903-85909, 2023 Aug.
Article in English | MEDLINE | ID: mdl-37395883

ABSTRACT

The concentrations of potentially toxic metals like lead (Pb), cadmium (Cd), and mercury (Hg) in healthy lactating mothers of Lahore city were estimated during 2020-2021 with the help of a flame atomic absorption spectrometer (FAAS). Seventy samples of breast milk were collected from two different age groups, namely, G-1 (25-30 years) and G-2 (31-40 years). The results showed that Cd contents were below the detection limit of the measuring instrument; however, the Pb and Hg contents were detected with great ease. The mean concentrations of Pb and Hg in the G-1 corresponding to the age between 25 and 30 years were observed to be 1.914 ± 0.493 µg/L and 10.432 ± 3.249 µg/L, respectively. For the G-2 with an age limit between 31 and 40 years, the concentrations of Pb and Hg were estimated to be 2.045 ± 0.502 µg/L and 11.527 ± 3.231 µg/L, respectively. The T-test analysis of concentrations of these toxic metals indicated a significant correlation between the content levels of Pb and Hg (p < 0.05). The observed values of toxic metals were significantly more frequent than those suggested by WHO (World Health Organization). An increase in the concentrations of Pb and Hg is directly associated with the location of the target population. As a result, it is turned out that the majority of the lactating woman with significantly high levels of Pb and Hg belongs to industrial areas of Lahore. To avoid such conditions, residential areas must be at larger distances, in addition, to strictly abiding by the environmental policies of the government.


Subject(s)
Mercury , Metals, Heavy , Humans , Female , Adult , Milk, Human/chemistry , Cadmium/analysis , Lead/analysis , Lactation , Pakistan , Mercury/analysis , Heavy Metal Poisoning , Metals, Heavy/analysis
4.
Heliyon ; 9(2): e13371, 2023 Feb.
Article in English | MEDLINE | ID: mdl-36814613

ABSTRACT

The following work is based on real-time temperature monitoring during the construction and during the operation of a dam. For this purpose, we have proposed a sensing model named: the "complex wireless sensors model (CWSM)" for measuring the value of different factors like temperature, humidity and pressure on the dam. The installation of the proposed model has been discussed with its wireless networking. The model contains five types of sensors i.e. humidity, temperature, pressure, sun and irradiance sensors for measuring the variation of different factors. The computation modeling of CWSM has been discussed in the paper. 3-D Finite Element method is used for thermal analysis. As the result, it is concluded that the wireless network will be more suitable for measuring and analyzing the effects of temperature, humidity, water pressure and solar radiation on the dam.

5.
Environ Sci Pollut Res Int ; 30(6): 14592-14603, 2023 Feb.
Article in English | MEDLINE | ID: mdl-36152095

ABSTRACT

Dams are studied not only for potential advantages but also for possible environmental repercussions. The objective of this case study is to see the effects caused by Gomal Zam Dam on temperature, humidity and precipitation in their surroundings, both spatially and temporally. The meteorology parameters' characteristics have been detected using two different approaches, Mann-Kendall statistical test and Sen's slope estimator. Data stations chosen were those that have been close to the dam and sufficiently far away from the dam. As a consequence, although temporal changes in mean heat were established, periodic and regional disparities in humidity readings were found.


Subject(s)
Environmental Monitoring , Hot Temperature , Temperature , Humidity , Pakistan
6.
RSC Adv ; 12(52): 33679-33687, 2022 Nov 22.
Article in English | MEDLINE | ID: mdl-36505702

ABSTRACT

Opto-chemical sensors are the most significant type of sensors that are widely used to detect a variety of volatile organic compounds and chemicals. This research work demonstrates the fabrication and characterization of an opto-chemical sensor based on a graphene thin film. A 300 nm graphene thin film was deposited on clean glass with the help of RF magnetron sputtering. The structure, surface and quality of the graphene thin film were characterized using XRD, SEM and Raman spectroscopy. For optical characterization, the thin film was exposed to IPA, acetone and toluene (separately) for five, ten and fifteen minutes. The optical transmission was then observed via UV-NIR spectroscopy in the near-infrared range (900 to 1450 nm). The thin film of graphene has expressed a sharp response time and recovery time with high sensitivity for each chemical. However, by comparing the output of the graphene thin film in response to each chemical, it was observed that graphene thin film has a better transmission and sensing rate for exposure to toluene.

7.
ACS Omega ; 7(36): 32569-32576, 2022 Sep 13.
Article in English | MEDLINE | ID: mdl-36120017

ABSTRACT

Tactile sensors are widely used in the electronic industry. In the following research work, we proposed a tactile sensor based on indium zinc oxide (IZO) electrodes and used neutrosophic statistics to analyze the capacitance and resistance of the tactile sensor. The tactile sensor was fabricated by depositing the IZO electrodes on a polycarbonate substrate (a thin layer). The IZO was characterized through X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and ultraviolet-visible (UV-vis) spectroscopy techniques. The sensor's electrical properties were characterized using an LCR meter, i.e., capacitance and resistance were measured in intervals with respect to changes in the applied force on the sensor at 1 kHz operational frequency. The sensor expressed high sensitivity with quick response and recovery times. The sensor also expressed long-term stability. For the analysis of capacitance and resistance, two statistical approaches, i.e., classical and neutrosophic approaches, were applied, and the better analysis approach for the sensor was found.

8.
RSC Adv ; 12(33): 21297-21308, 2022 Jul 21.
Article in English | MEDLINE | ID: mdl-35975052

ABSTRACT

Graphene is a 2D material with remarkable properties. The present study demonstrates the fabrication of a graphene-based sensor for measuring the temperature and humidity of a metal body. The graphene sensor was fabricated by depositing a thin film of graphene nanoparticles between silver electrodes (separated by ∼50 µm) on a glass substrate. The graphene thin film was characterized by XRD, Raman spectroscopy and UV-vis techniques. The capacitance and resistance for both the relative humidity (in the range of 0-100% RH) and temperature (in the range of 230-310 K) were measured using an LCR meter at 1 kHz in a controlled chamber. The graphene-based sensor expressed high sensitivity with fast response and recovery times for both humidity and temperature with long stability and low hysteresis curves. The sensor was also tested on a metal body, which expressed a good response time. Moreover, the measured data of capacitance and resistance was analyzed with classical and neutrosophic analysis as an application of modern material statistics. It was observed that neutrosophic analysis is more flexible for analyzing the capacitance and resistance of the fabricated sensor.

9.
RSC Adv ; 12(27): 17138-17145, 2022 Jun 07.
Article in English | MEDLINE | ID: mdl-35755584

ABSTRACT

The use of flexible electronic devices in different applications of Internet of Things, especially in robot technology, has gained importance to measure different physical factors such as temperature. Moreover, there is a need for a flexible and more informative approach to analyse the data. In this study, we report two flexible temperature sensors based on reduced graphene and multi-walled carbon nanotubes with high sensitivity and quick response and recovery times. The electrical properties of the sensors were studied using an LCR meter associated with a controlled chamber at 1 kHz. We used both classical and neutrosophic methods for analyzing the measured data of temperature sensors and found the more effective method by comparing their methods of analysis.

10.
Sci Rep ; 11(1): 23939, 2021 Dec 14.
Article in English | MEDLINE | ID: mdl-34907243

ABSTRACT

In this work, we have proposed a neutrosophic statistical approach for the analysis of resistance of conducting material depending on the temperature variance. We have developed a neutrosophic formula and applied it to the resistance data. We also use the classical statistical approach for making a comparison between both approaches. As a result, it is observed that the neutrosophic statistical approach is more flexible and informative. Also, this work suggests that the neutrosophic statistical approach analyzes the resistance of conducting material for big data.

11.
RSC Adv ; 11(61): 38674-38682, 2021 Nov 29.
Article in English | MEDLINE | ID: mdl-35493226

ABSTRACT

In this work, we propose a humidity sensor based on methyl green thin film. A surface-type humidity sensor Al/MG/Al was fabricated by depositing methyl green thin film between aluminum electrodes. The structural, optical and surface morphological properties of the thin film were characterized by XRD, UV Vis and FESEM. The sensing properties with high sensitivity as well as response time 200 s and recovery 60 s of the humidity sensor were investigated by measuring the capacitance and resistance at 1, 10 and 100 kHz with the humidity varying range from 32 to 85% RH. These measured values were analyzed by classical statistics and neutrosophic statistics. As a result, it was observed that neutrosophic statistics were more informative, flexible and adequate than classical statistics for analyzing the measured values of capacitance and resistance.

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