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2.
Glob Chang Biol ; 30(1): e17108, 2024 Jan.
Article in English | MEDLINE | ID: mdl-38273551

ABSTRACT

Future phosphorus (P) shortages could seriously affect terrestrial productivity and food security. We investigated the changes in topsoil available P (AP) and total P (TP) in China's forests, grasslands, paddy fields, and upland croplands during the 1980s-2010s based on substantial repeated soil P measurements (63,220 samples in the 1980s, 2000s, and 2010s) and machine learning techniques. Between the 1980s and 2010s, total soil AP stock increased with a small but significant rate of 0.13 kg P ha-1 year-1 , but total soil TP stock declined substantially (4.5 kg P ha-1 year-1 ) in the four ecosystems. We quantified the P budgets of soil-plant systems by harmonizing P fluxes from various sources for this period. Matching trends of soil contents over the decades with P budgets and fluxes, we found that the P-surplus in cultivated soils (especially in upland croplands) might be overestimated due to the great soil TP pool compared to fertilization and the substantial soil P losses through plant uptake and water erosion that offset the P additions. Our findings of P-deficit in China raise the alarm on the sustainability of future biomass production (especially in forests), highlight the urgency of P recycling in croplands, and emphasize the critical role of country-level basic data in guiding sound policies to tackle the global P crises.


Subject(s)
Ecosystem , Soil , Phosphorus/analysis , Forests , Plants , China
3.
Environ Res ; 229: 116005, 2023 07 15.
Article in English | MEDLINE | ID: mdl-37116676

ABSTRACT

Litterfall, typically referring to needles/leaves, may stand for >50% of the total mercury (Hg) deposition in forest ecosystems. By detailed categorisation, we reveal for the first time that the contributions through lichens and fine litter, together 9.98 µg Hg m-2 yr-1, could be as high as that in needle litter (9.96 µg m-2 yr-1) to the annual total Hg deposition (44.6 µg m-2 yr-1) in a subalpine forest in Switzerland. Noticeably, needle litter had the highest contribution (53%) to total Hg in the autumn litterfall but lichens and fine litter together predominated in other seasons (47-59%). Such a seasonal pattern is caused by the high ability of lichens and fine litter to accumulate Hg and the high needle litterfall in autumn, which is related to a good rainfall in summer followed by a dry period in autumn. The constantly higher Hg levels in lichens and fine litter than in needle litter together with similar seasonal patterns of litterfall during 2009-2019 and rainfall during 1980-2019 suggest that our finding can be generally valid. Here, we highlight not only the considerable role of non-needle litterfall in Hg deposition but also the association with weather for seasonal Hg dynamics in different litterfall components.


Subject(s)
Lichens , Mercury , Mercury/analysis , Ecosystem , Trees , Environmental Monitoring , Forests
4.
Sci Total Environ ; 875: 162638, 2023 Jun 01.
Article in English | MEDLINE | ID: mdl-36894091

ABSTRACT

Rapidly changing land use patterns and frequent extreme weather events have resulted in an increased sediment flux to freshwater systems globally, highlighting the need for land-use-based sediment source fingerprinting. Application of variability in hydrogen isotope compositions (δ2H values) of vegetation-specific biomarkers from soils and sediments is relatively underexplored for land-use-based freshwater suspended sediment (SS) source fingerprinting, but has the potential to complement the information from routinely applied carbon isotope analysis and provide new insights. We analysed δ2H values of long-chain fatty acids (LCFAs) as vegetation-specific biomarkers in source soils and SS collected from the mixed land use Tarland catchment (74 km2) in NE Scotland, to identify stream SS sources and quantify their contributions to SS. Plant growth form was the primary control on source soils LCFAs (n-C26:0, n-C28:0, n-C30:0) δ2H variability, while the isotopic composition of source water had no significant control. Forest and heather moorland soils covered with dicotyledonous and gymnosperm species were differentiated from arable land and grasslands soils covered with monocotyledonous species. SS samples collected for fourteen months from the Tarland catchment with a nested sampling approach showed monocot-based land use (cereal crops, grassland) to be the major source of SS with 71 ± 11% contribution on catchment-wide scale averaged throughout the sampling period. Storm events after a dry summer period and sustained high flow conditions in the streams during autumn and early winter suggested enhanced connectivity of more distant forest and heather moorland land uses covering relatively steep topography. This was shown by an increased contribution (44 ± 8%) on catchment-wide scale from dicot and gymnosperm-based land uses during the corresponding period. Our study demonstrated successful application of vegetation-specificity in δ2H values of LCFAs for land-use-based freshwater SS source fingerprinting in a mesoscale catchment where δ2H values of LCFAs were primarily controlled by plant growth forms.


Subject(s)
Environmental Monitoring , Rivers , Soil , Carbon Isotopes/analysis , Fatty Acids , Geologic Sediments/analysis , Fresh Water/chemistry , Environmental Monitoring/methods
5.
J Environ Radioact ; 257: 107078, 2023 Feb.
Article in English | MEDLINE | ID: mdl-36423536

ABSTRACT

To investigate the effects of converting forests into vineyards typical to Zarivar Lake watershed, Iran, which occurred mainly in the 1970s and 80s, on soil erosion,137Cs and 210Pbex, being mid-and-long-term soil loss tracers, were applied. In Chernobyl-contaminated areas like those found in some parts of Europe and Asia, the proportion of 137Cs Chernobyl fallout needs to be determined to convert 137Cs inventories into soil erosion rates. To do so, Pu radioisotopes were applied for the first time in Iran. The soil samples were gathered from two adjacent, almost similar hillslopes under natural forest (slope length: 250 m; slope gradient: 20%) and rainfed vineyard (slope length: 200 m; slope gradient: 17%). 137Cs/239+240Pu ratios indicated that 49.8 ± 10.0% of 137Cs originated from Chernobyl. The net soil erosion rates derived by 137Cs, and 210Pbex approaches were 5.0 ± 1.1 and 5.9 ± 2.9 Mg ha-1 yr-1 in the forested hillslope, and 25.9 ± 5.7 and 32.5 ± 14.5 Mg ha-1 yr-1 in the vineyard hillslope, respectively. Both 137Cs and 210Pbex highlighted that deforestation increased soil erosion by around five times. Moreover, the impacts of deforestation on soil physicochemical properties were investigated in surface and subsurface soils. Compared to forested hillslope, soil organic carbon stock in the upper 40 cm of the vineyard reduced by 14 Mg C ha-1 (29%), 8 Mg C ha-1 of which was removed by erosion within 35 years, and the remaining have likely been lost via emissions (6 Mg C ha-1). The vineyard topsoil experienced the most dramatic drops in percolation stability (PS), sealing index, and organic matter by about 55, 51, and 49%, respectively. Among all measured physicochemical properties, PS showed the greatest sensitivity to land-use change. Overall, the present study's findings confirmed that deforestation for agricultural purposes triggered soil loss, deteriorated soil quality and possibly contributed to the reduction of the lake's water quality and climate change.


Subject(s)
Radiation Monitoring , Soil Pollutants, Radioactive , Soil/chemistry , Lead , Soil Erosion , Iran , Conservation of Natural Resources , Carbon , Cesium Radioisotopes/analysis , Soil Pollutants, Radioactive/analysis
6.
Environ Sci Technol ; 56(23): 17410-17419, 2022 12 06.
Article in English | MEDLINE | ID: mdl-36399683

ABSTRACT

Peatlands store carbon in the form of dead organic residues. Climate change and human impact impose risks on the sustainability of the peatlands carbon balance due to increased peat decomposition. Here, we investigated molecular changes in the upper peat layers (0-40 cm), inferred from high-resolution vertical depth profiles, from a boreal peatland using two-dimensional 1H-13C nuclear magnetic resonance (NMR) spectroscopy, and comparison to δ13C, δ15N, and carbon and nitrogen content. Effects of hydrological conditions were investigated at respective sites: natural moist, drainage ditch, and natural dry. The molecular characterization revealed preferential degradation of specific side-chain linkages of xylan-type hemicelluloses within 0-14 cm at all sites, indicating organic matter losses up to 25%. In contrast, the xylan backbone, galactomannan-type hemicelluloses, and cellulose were more resistant to degradation and accumulated at the natural moist and drainage site. δ13C, δ15N, and carbon and nitrogen content did not correlate with specific hemicellulose structures but reflected changes in total carbohydrates. Our analysis provides novel insights into peat carbohydrate decomposition and indicates substantial organic matter losses in the acrotelm due to the degradation of specific hemicellulose structures. This suggests that variations in hemicellulose content and structure influence peat stability, which may have important implications with respect to climate change.


Subject(s)
Soil , Xylans , Humans , Soil/chemistry , Carbon/chemistry , Nitrogen/analysis
7.
Sci Total Environ ; 838(Pt 4): 156603, 2022 Sep 10.
Article in English | MEDLINE | ID: mdl-35690201

ABSTRACT

Peatland degradation is tightly connected to hydrological changes and microbial metabolism. To better understand these metabolism processes, more information is needed on how microbial communities and substrate cycling are affected by changing hydrological regimes. These activities should be imprinted in stable isotope bulk values (δ 15N, δ 13C) due to specific isotopic fractionation by different microbial communities, their metabolic pathways and nutrient sources. We hypothesize that stable isotope values and microbial abundance are correlated and act as indicators of different hydrological regimes. We sampled an East-West transect across European fens in 14 areas and conducted a stable isotope (δ 13C, δ 15N) and membrane fatty acid (mFA) analysis. Within each area an undrained, drained and rewetted site was selected. Rewetted sites were separated based on when rewetting occurred. We found differences in the upper layers of all sites in microbial-derived mFAs and stable isotope values corresponding to hydrological regimes. The highest and lowest quantities of microbial-derived mFAs were measured in undrained and drained sites, respectively. Fungal-derived mFAs were especially lower in drained sites. Simultaneously, δ15N stable isotope values were highest in drained sites. In addition, stable isotope values and microbial-derived mFAs showed distinct depth trends. In undrained sites stable isotopes values slightly increased with depth. In drained sites, δ15N values decreased downwards, whereas δ13C values increased. Overall microbial-derived mFAs decreased with depth. These patterns presumably result from anoxic conditions and high peat recalcitrance in the deeper layers. In sites with short time of rewetting, the microbial-derived mFAs and stable isotope values were similar to values of drained sites, while with increasing rewetting time values shifted to those of undrained sites. We conclude that biomarkers indicate that stable isotope values reflect specific microbial metabolic processes, which differ with hydrological regimes, and thus could indicate both drainage and rewetting in fens.


Subject(s)
Hydrology , Microbiota , Biomarkers , Carbon Isotopes , Nitrogen Isotopes/analysis , Soil
8.
Environ Pollut ; 307: 119483, 2022 Aug 15.
Article in English | MEDLINE | ID: mdl-35595001

ABSTRACT

Taking advantage of the different histories of Hg deposition in Davos Seehornwald in E-Switzerland and Changbai Mountain in NE-China, the influence of atmospheric deposition on Hg soil dynamics in forest soil profiles was investigated. Today, Hg fluxes in bulk precipitation were similar, and soil profiles were generally sinks for atmospherically deposited Hg at both sites. Noticeably, a net release of 2.07 µg Hg m-2 yr-1 from the Bs horizon (Podzol) in Seehornwald was highlighted, where Hg concentration (up to 73.9 µg kg-1) and soil storage (100 mg m-3) peaked. Sequential extraction revealed that organic matter and crystalline Fe and Al hydr (oxide)-associated Hg decreased in the E horizon but increased in the Bs horizon as compared to the Ah horizon, demonstrating the coupling of Hg dynamics with the podzolisation process and accumulation of legacy Hg deposited last century in the Bs horizon. The mor humus in Seehornwald allowed Hg enrichment in the forest floor (182-269 µg kg-1). In Changbai Mountain, the Hg concentrations in the Cambisol surface layer with mull humus were markedly lower (<148 µg kg-1), but with much higher Hg soil storage (54-120 mg m-3) than in the Seehornwald forest floor (18-27 mg m-3). Thus, the vertical distribution pattern of Hg was influenced by humus form and soil type. The concentrations of Hg in soil porewater in Seehornwald (3.4-101 ng L-1) and in runoff of Changbai Mountain (1.26-5.62 ng L-1) were all low. Moreover, the pools of readily extractable Hg in the soils at both sites were all <2% of total Hg. Therefore, the potential of Hg release from the forest soil profile to the adjacent aquatic environment is currently low at both sites.


Subject(s)
Mercury , Soil Pollutants , China , Environmental Monitoring , Forests , Mercury/analysis , Soil/chemistry , Soil Pollutants/analysis , Switzerland , Taiga , Trees
9.
Sci Total Environ ; 800: 149498, 2021 Dec 15.
Article in English | MEDLINE | ID: mdl-34426363

ABSTRACT

Drainage for agriculture has turned peatlands from a net sink to a net source of carbon (C). In order to reduce the environmental footprint of agricultural peatland drainage, and to counteract soil subsidence, mineral soil coverage is becoming an increasingly used practice in Switzerland. To explore the effect of mineral soil coverage on soil C loss and the source of CO2 from peatland drained for agriculture, we utilized the radiocarbon signature (F14C) of soil C and emitted CO2 in the field. The experiment, located in the Swiss Rhine Valley, was carried out on two adjacent drained organic soils, either without mineral soil cover (reference 'Ref'), or covered with mineral soil (thickness ~ 40 cm) (coverage 'Cov') 13 years ago. Drainage already commenced 130 years ago and the site was managed as meadow since the 1970ies. Drainage induced 41-75 kg C m-2 loss, which is equivalent to annual C loss rates of 0.49-0.58 kg C m-2 yr-1 and 0.31-0.63 kg C m-2 yr-1 for Cov and Ref, respectively. Mineral soil coverage had no significant effect on the amount of heterotrophic respiration, however, at Cov, the radiocarbon signature of heterotrophic CO2 was significantly (p<0.01) younger than at Ref, indicating that mineral soil coverage moved the source of decomposition of soil organic carbon (SOC) from a higher share of old peat towards a higher share of relatively younger material. In summary, our study lends support to the hypothesis that mineral soil coverage might reduce the decomposition of old peat underneath, and may therefore be a promising peatland management technique for the future use of drained peatland for agriculture.


Subject(s)
Carbon , Soil , Agriculture , Carbon Dioxide/analysis , Minerals
10.
Environ Res ; 197: 111087, 2021 06.
Article in English | MEDLINE | ID: mdl-33798514

ABSTRACT

Soil erosion can present a major threat to agriculture due to loss of soil, nutrients, and organic carbon. Therefore, soil erosion modelling is one of the steps used to plan suitable soil protection measures and detect erosion hotspots. A bibliometric analysis of this topic can reveal research patterns and soil erosion modelling characteristics that can help identify steps needed to enhance the research conducted in this field. Therefore, a detailed bibliometric analysis, including investigation of collaboration networks and citation patterns, should be conducted. The updated version of the Global Applications of Soil Erosion Modelling Tracker (GASEMT) database contains information about citation characteristics and publication type. Here, we investigated the impact of the number of authors, the publication type and the selected journal on the number of citations. Generalized boosted regression tree (BRT) modelling was used to evaluate the most relevant variables related to soil erosion modelling. Additionally, bibliometric networks were analysed and visualized. This study revealed that the selection of the soil erosion model has the largest impact on the number of publication citations, followed by the modelling scale and the publication's CiteScore. Some of the other GASEMT database attributes such as model calibration and validation have negligible influence on the number of citations according to the BRT model. Although it is true that studies that conduct calibration, on average, received around 30% more citations, than studies where calibration was not performed. Moreover, the bibliographic coupling and citation networks show a clear continental pattern, although the co-authorship network does not show the same characteristics. Therefore, soil erosion modellers should conduct even more comprehensive review of past studies and focus not just on the research conducted in the same country or continent. Moreover, when evaluating soil erosion models, an additional focus should be given to field measurements, model calibration, performance assessment and uncertainty of modelling results. The results of this study indicate that these GASEMT database attributes had smaller impact on the number of citations, according to the BRT model, than anticipated, which could suggest that these attributes should be given additional attention by the soil erosion modelling community. This study provides a kind of bibliographic benchmark for soil erosion modelling research papers as modellers can estimate the influence of their paper.


Subject(s)
Bibliometrics , Soil Erosion , Agriculture , Publications , Soil
11.
Sci Total Environ ; 780: 146494, 2021 Aug 01.
Article in English | MEDLINE | ID: mdl-33773346

ABSTRACT

To gain a better understanding of the global application of soil erosion prediction models, we comprehensively reviewed relevant peer-reviewed research literature on soil-erosion modelling published between 1994 and 2017. We aimed to identify (i) the processes and models most frequently addressed in the literature, (ii) the regions within which models are primarily applied, (iii) the regions which remain unaddressed and why, and (iv) how frequently studies are conducted to validate/evaluate model outcomes relative to measured data. To perform this task, we combined the collective knowledge of 67 soil-erosion scientists from 25 countries. The resulting database, named 'Global Applications of Soil Erosion Modelling Tracker (GASEMT)', includes 3030 individual modelling records from 126 countries, encompassing all continents (except Antarctica). Out of the 8471 articles identified as potentially relevant, we reviewed 1697 appropriate articles and systematically evaluated and transferred 42 relevant attributes into the database. This GASEMT database provides comprehensive insights into the state-of-the-art of soil- erosion models and model applications worldwide. This database intends to support the upcoming country-based United Nations global soil-erosion assessment in addition to helping to inform soil erosion research priorities by building a foundation for future targeted, in-depth analyses. GASEMT is an open-source database available to the entire user-community to develop research, rectify errors, and make future expansions.

12.
Sci Total Environ ; 755(Pt 1): 142916, 2021 Feb 10.
Article in English | MEDLINE | ID: mdl-33172631

ABSTRACT

Intensification of land use is a primary cause of increased suspended sediment load in freshwater systems, hence land-use-specific sediment source tracing is necessary to inform sustainable land and water management. Here we tested the application of compound-specific isotope analysis (CSIA) of vegetation biomarkers to fingerprint suspended sediment sources from the mesoscale agricultural Tarland catchment (74 km2) in NE Scotland. Our aim was to test a parsimonious nested sampling approach from a headwater sub-catchment to apportion suspended sediment sources across headwater to catchment-wide scales. Compound-specific carbon isotopic signatures (δ13C) of long-chain fatty acids (LCFAs) from source soils were able to successfully distinguish between forest, heather moorland, permanent grassland, and arable land cover. Permanent grassland was a prominent source of sediment at both headwater and catchment scales, with an annual average contribution of 79% and 56%, respectively, indicating grazing pressure and runoff via preferential pathways. Increased sediment input from arable land at the catchment scale (40%) compared to the headwater sub-catchment (18%) indicated land use intensification in lowland areas. Forest and heather moorland contributed marginally to suspended sediments (~2%), despite covering 43% area of the catchment area. Temporal variability of sediment sources observed over fourteen months (May 2017 - June 2018) showed a higher relative contribution from arable land during summer and autumn and a higher contribution from permanent grassland during winter and spring, likely linked to seasonality of rainfall and agronomic activities. These results demonstrate a successful use of δ13C values of LCFAs to quantify land-use-specific suspended sediment sources. Comparison of two suspended sediment techniques showed usefulness of time-integrated mass samplers for representative and cost-effective sampling. We recommend that future nested sampling designs should include spatially distributed source soil tracer characterization covering the whole catchment area to reduce the uncertainty in sediment source attribution from headwaters to the catchment outlet.

13.
Nat Commun ; 11(1): 4546, 2020 09 11.
Article in English | MEDLINE | ID: mdl-32917863

ABSTRACT

Soil phosphorus (P) loss from agricultural systems will limit food and feed production in the future. Here, we combine spatially distributed global soil erosion estimates (only considering sheet and rill erosion by water) with spatially distributed global P content for cropland soils to assess global soil P loss. The world's soils are currently being depleted in P in spite of high chemical fertilizer input. Africa (not being able to afford the high costs of chemical fertilizer) as well as South America (due to non-efficient organic P management) and Eastern Europe (for a combination of the two previous reasons) have the highest P depletion rates. In a future world, with an assumed absolute shortage of mineral P fertilizer, agricultural soils worldwide will be depleted by between 4-19 kg ha-1 yr-1, with average losses of P due to erosion by water contributing over 50% of total P losses.

14.
Proc Natl Acad Sci U S A ; 117(36): 21994-22001, 2020 09 08.
Article in English | MEDLINE | ID: mdl-32839306

ABSTRACT

Soil erosion is a major global soil degradation threat to land, freshwater, and oceans. Wind and water are the major drivers, with water erosion over land being the focus of this work; excluding gullying and river bank erosion. Improving knowledge of the probable future rates of soil erosion, accelerated by human activity, is important both for policy makers engaged in land use decision-making and for earth-system modelers seeking to reduce uncertainty on global predictions. Here we predict future rates of erosion by modeling change in potential global soil erosion by water using three alternative (2.6, 4.5, and 8.5) Shared Socioeconomic Pathway and Representative Concentration Pathway (SSP-RCP) scenarios. Global predictions rely on a high spatial resolution Revised Universal Soil Loss Equation (RUSLE)-based semiempirical modeling approach (GloSEM). The baseline model (2015) predicts global potential soil erosion rates of [Formula: see text] Pg yr-1, with current conservation agriculture (CA) practices estimated to reduce this by ∼5%. Our future scenarios suggest that socioeconomic developments impacting land use will either decrease (SSP1-RCP2.6-10%) or increase (SSP2-RCP4.5 +2%, SSP5-RCP8.5 +10%) water erosion by 2070. Climate projections, for all global dynamics scenarios, indicate a trend, moving toward a more vigorous hydrological cycle, which could increase global water erosion (+30 to +66%). Accepting some degrees of uncertainty, our findings provide insights into how possible future socioeconomic development will affect soil erosion by water using a globally consistent approach. This preliminary evidence seeks to inform efforts such as those of the United Nations to assess global soil erosion and inform decision makers developing national strategies for soil conservation.


Subject(s)
Climate Change , Conservation of Natural Resources , Landslides/statistics & numerical data , Water/chemistry , Climate Change/economics , Conservation of Natural Resources/economics , Conservation of Natural Resources/trends , Environmental Monitoring , Human Activities , Humans , Landslides/economics , Socioeconomic Factors , Soil/chemistry
15.
Sci Rep ; 10(1): 11858, 2020 07 16.
Article in English | MEDLINE | ID: mdl-32678221

ABSTRACT

Global nuclear weapon testing and the Chernobyl accident have released large amounts of radionuclides into the environment. However, to date, the spatial patterns of these fallout sources remain poorly constrained. Fallout radionuclides (137Cs, 239Pu, 240Pu) were measured in soil samples (n = 160) collected at flat, undisturbed grasslands in Western Europe in the framework of a harmonised European soil survey. We show that both fallout sources left a specific radionuclide imprint in European soils. Accordingly, we used plutonium to quantify contributions of global versus Chernobyl fallout to 137Cs found in European soils. Spatial prediction models allowed for a first assessment of the global versus Chernobyl fallout pattern across national boundaries. Understanding the magnitude of these fallout sources is crucial not only to establish a baseline in case of future radionuclide fallout but also to define a baseline for geomorphological reconstructions of soil redistribution due to soil erosion processes.

16.
Environ Pollut ; 250: 944-952, 2019 Jul.
Article in English | MEDLINE | ID: mdl-31085481

ABSTRACT

The Minamata Convention entered into force in 2017 with the aim to phase-out the use of mercury (Hg) in manufacturing processes such as the chlor-alkali or vinyl chloride monomer production. However, past industrial use of Hg had already resulted in extensive soil pollution, which poses a potential environmental threat. We investigated the emission of gaseous elemental mercury (Hg0) from Hg polluted soils in settlement areas in the canton of Valais, Switzerland, and its impact on local air Hg concentrations. Most soil Hg was found as soil matrix-bound divalent Hg (HgII). Elemental mercury (Hg0) was undetectable in soils, yet we observed substantial Hg0 emission (20-1392 ng m-2 h-1) from 27 soil plots contaminated with Hg (0.2-390 mg Hg kg-1). The emissions of Hg0 were calculated for 1274 parcels covering an area of 8.6 km2 of which 12% exceeded the Swiss soil remediation threshold of 2 mg Hg kg-1. The annual Hg0 emission from this area was approximately 6 kg a-1, which is almost 1% of the total atmospheric Hg emissions in Switzerland based on emission inventory estimates. Our results show a higher abundance of Hg resistance genes (merA) in soil microbial communities with increasing soil Hg concentrations, indicating that biotic reduction of HgII is likely an important pathway to form volatile Hg0 in these soils. The total soil Hg pool in the top 20 cm of the investigated area was 4288 kg; hence, if not remediated, these contaminated soils remain a long-term source of atmospheric Hg, which is prone to long-range atmospheric transport.


Subject(s)
Bacteria/drug effects , Bacteria/genetics , Environmental Monitoring/methods , Mercury/analysis , Mercury/toxicity , Oxidoreductases/genetics , Soil Pollutants/analysis , Soil/chemistry , Drug Resistance, Bacterial/genetics , Environmental Pollution/analysis , Industry , Meteorological Concepts , Switzerland
17.
Chemosphere ; 221: 193-202, 2019 Apr.
Article in English | MEDLINE | ID: mdl-30639815

ABSTRACT

Understanding the sorption kinetics of Hg2+ is the key to predicting its reactivity in soils which is indispensable for environmental risk assessment. The temporal change in the solubility of 196Hg2+ spikes (6 mg kg-1) added to a range of soils with different properties was investigated and modelled. The sorption of 196Hg2+ displayed a biphasic pattern with a rapid initial (short-term) phase followed by a slower (time-dependent) one. The overall reaction rate constants ranged from 0.003 to 4.9 h-1 and were significantly correlated (r = 0.94) to soil organic carbon (SOC). Elovich and Spherical Diffusion expressions compellingly fitted the observed 196Hg2+ sorption kinetics highlighting their flexibility to describe reactions occurring over multiple phases and wide timeframes. A parameterized Elovich model from soil variables indicated that the short-term sorption is solely controlled by SOC while the time-dependent sorption appeared independent of SOC and decreased at higher pH values and Al(OH)3 and MnO2 concentrations. This is consistent with a rapid chemical reaction of Hg2+ with soil organic matter (SOM) which is followed by a noticeably slower phase likely occurring through physical pathways e.g. pore diffusion of Hg2+ into spherical soil aggregates and progressive incorporation of soluble organic-Hg into solid phase. The model lines predicted that in soils with >4% SOC, Hg2+ is removed from soil solution over seconds to minutes; however, in soils with <2% SOC and higher pH values, Hg2+ may remain soluble for months and beyond with a considerable associated risk of re-emission or migration to the surrounding environments.


Subject(s)
Mercury/analysis , Soil Pollutants/analysis , Soil/chemistry , Adsorption , Carbon , Diffusion , Hydrogen-Ion Concentration , Isotopes , Kinetics , Solubility
18.
Data Brief ; 20: 1992-1998, 2018 Oct.
Article in English | MEDLINE | ID: mdl-30306103

ABSTRACT

So far, neither a grassland map, temporal analysis of the conversion of permanent grassland (PG) to other land uses nor the differentiation of permanent and temporal grassland exists for Switzerland. For the first time in Switzerland, we present a Swiss national grassland map for the year 2015 capturing the extent of both, permanent and temporal grasslands (here called grasslands) by intersecting the information of three datasets. We blended the high temporal resolution Climate Change Initiate (CCI) Land Cover of 2015 (processed by the European Space Agency (ESA)), with the high spatial resolution Swiss topographical landscape model "SwissTLM3D" and the landscape model "vector25" both provided by Swisstopo. The final data presents the spatial patterns and the national extent of Swiss grasslands. Furthermore, the recently published (April 2017) CCI Land Cover dataset allow extracting the extent of grasslands for 24 years (1992-2015) with a coarse spatial resolution of 300 m. We used the time series data of the grassland extent to produce annual PG maps from 1996 to 2015. That data enables the identification of the development of grassland extent over two decades. The Swiss national grassland map is used for investigating the spatio-temporal patterns of the soil erosion risk of Swiss grasslands (see Mapping spatio-temporal dynamics of the cover and management factor (C-factor) for grasslands in Switzerland, doi:10.1016/j.rse.2018.04.008 (Schmidt el al., 2018)).

19.
Glob Chang Biol ; 24(8): 3283-3284, 2018 08.
Article in English | MEDLINE | ID: mdl-29971951

ABSTRACT

This study combines two unprecedentedly high resolution (250 × 250 m) maps of soil erosion (inter-rill and rill processes) and soil organic carbon to calculate a global estimate of erosion-induced organic carbon (C) displacement. The results indicate a gross C displacement by soil erosion of 2.5-0.3+0.5 Pg C/year. The greatest share of displaced C (64%) comes from seminatural lands and forests. This suggests that lateral C transfer from erosion in noncroplands may play a more important role than previously assumed.


Subject(s)
Agriculture/methods , Carbon/analysis , Forests , Soil/chemistry
20.
Nat Commun ; 8(1): 2013, 2017 12 08.
Article in English | MEDLINE | ID: mdl-29222506

ABSTRACT

Human activity and related land use change are the primary cause of accelerated soil erosion, which has substantial implications for nutrient and carbon cycling, land productivity and in turn, worldwide socio-economic conditions. Here we present an unprecedentedly high resolution (250 × 250 m) global potential soil erosion model, using a combination of remote sensing, GIS modelling and census data. We challenge the previous annual soil erosion reference values as our estimate, of 35.9 Pg yr-1 of soil eroded in 2012, is at least two times lower. Moreover, we estimate the spatial and temporal effects of land use change between 2001 and 2012 and the potential offset of the global application of conservation practices. Our findings indicate a potential overall increase in global soil erosion driven by cropland expansion. The greatest increases are predicted to occur in Sub-Saharan Africa, South America and Southeast Asia. The least developed economies have been found to experience the highest estimates of soil erosion rates.

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