Progress in the Sustainable Development of Biobased (Nano)materials for Application in Water Treatment Technologies.

Water pollution remains a widespread problem, affecting the health and wellbeing of people around the globe. While current advancements in wastewater treatment and desalination show promise, there are still challenges that need to be overcome to make these technologies commercially viable. Nanotechnology plays a pivotal role in water purification and desalination processes today. However, the release of nanoparticles (NPs) into the environment without proper safeguards can lead to both physical and chemical toxicity. Moreover, many methods of NP synthesis are expensive and not environmentally sustainable. The utilization of biomass as a source for the production of NPs has the potential to mitigate issues pertaining to cost, sustainability, and pollution. The utilization of biobased nanomaterials (bio-NMs) sourced from biomass has garnered attention in the field of water purification due to their cost-effectiveness, biocompatibility, and biodegradability. Several research studies have been conducted to efficiently produce NPs (both inorganic and organic) from biomass for applications in wastewater treatment. Biosynthesized materials such as zinc oxide NPs, phytogenic magnetic NPs, biopolymer-coated metal NPs, cellulose nanocrystals, and silver NPs, among others, have demonstrated efficacy in enhancing the process of water purification. The utilization of environmentally friendly NPs presents a viable option for enhancing the efficiency and sustainability of water pollution eradication. The present review delves into the topic of biomass, its origins, and the methods by which it can be transformed into NPs utilizing an environmentally sustainable approach. The present study will examine the utilization of greener NPs in contemporary wastewater and desalination technologies.

Removal of heavy metals from wastewater by aerogel derived from date palm waste.

Cellulose that has been sourced from date palm leaves as a primary component was utilised. This cellulose served as the foundational material for the development of an aerogel composite. During this process, MXene (Ti3C2Tx) played a pivotal role in enhancing the overall composition of the aerogel. To ensure the stability and durability of the resulting aerogel structure, calcium ions were introduced to the mix. These ions facilitated the cross-linking process of sodium alginate molecules, ultimately leading to the formation of calcium alginate. This cross-linking step is crucial for the enhanced mechanical and chemical stability of the aerogel. Incorporating alginate and Ti3C2Tx into the cellulose aerogel enhanced its structural integrity in aqueous conditions and increased its adsorption capacity. When evaluated with synthetic wastewater, this composite exhibited remarkable adsorption capacities of 72.9, 114.4, 92.9, and 123.9 mg/g for As, Cd, Ni, and Zn ions, respectively. A systematic study was carried out to see the effect of various parameters, including contact time, MXene concentration, pH, and temperature on the adsorption of these elements. Peak adsorption was achieved at 60 min, favoring a pH range between 6 and 8 and exhibited optimal sorption efficiency at lower temperatures. The adsorption kinetics adhered closely to a pseudo-second-order, while the Freundlich model adeptly described the adsorption isotherms. An interesting result of this research was the aerogel's regenerative potential. After undergoing a basic acid treatment, the MXene/cellulose/alginate aerogel composite could be restored and reused for up to three cycles, all while maintaining its core performance capabilities even after the rigorous cross-linking processes. In three consecutive cycles, the removal percentages for As, Cd, Ni, and Zn were 48.15%, 80.38%, 56.51%, and 86.12% in cycle 1; 37.35%, 65.63%, 45.97%, and 78.42% in cycle 2; and 28.60%, 56.22%, 34.70%, and 65.83% in cycle 3, respectively. The composite was tested in conditions resembling seawater salinity. Impressively, the aerogel continued to demonstrate a significant ability to adsorb metals, reinforcing its potential utility in real-world aquatic scenarios. These findings suggest that the composite aerogel, integrating MXene, cellulose, and alginate, is an effective medium for the targeted removal of heavy metals from aquatic environments.

Direct screening of food packaging materials for post-polymerization residues, degradation products and additives by liquid extraction surface analysis nanoelectrospray mass spectrometry (LESA-nESI-MS).

Materials in direct contact with food should be monitored for the presence of species able to migrate into food. A direct method based on liquid extraction surface analysis nanoelectrospray mass spectrometry (LESA-nanoESI-MS) was developed for the analysis of the migrating species from a polymer film. Different types of molecules: post-polymerization residues, degradation products (oligomers resulting from polymer recycling, products of polymer oxidative degradation) and anti-oxidant additives (vitamin E) were demonstrated to be detected and identified, and determined quantitatively if relevant calibration standards are available. The method was validated by a comparison a standard method based on with bulk extraction mass spectrometry. It offers considerable advantages over the latter in terms of drastically reduced analysis time and solvent consumption. Also, LESA-nanoESI-MS produced simpler spectra (limited to compounds able to migrate into food) than Direct Analysis in Real Time (DART).

Modeling of the linear viscoelastic properties of oil-in-water emulsions.

The aim of this work is to use a recently developed statistical model of dispersions with nonhydrodynamic interactions to describe the linear viscoelastic properties of emulsions of Newtonian liquids. None of the existing models can describe the rheological behavior of such systems, particularly the elastic properties, in the linear regime. We first present the results of numerical simulations of our model applied to emulsions. We show that taking nonhydrodynamic interactions into account allows to predict that emulsions of two purely viscous liquids have a complex viscoelastic behavior. We then compare the model to experimental results on oil/water emulsions, stabilized with ionic and nonionic surfactants. We find out that our statistical mechanical approach gives a much better description of the viscoelastic behavior of these samples than purely hydrodynamic models do. However, the elasticity observed is underestimated by our model. We indicate further theoretical developments which could improve the description of the viscoelastic properties of emulsions.