Inventory of biodegradation data of ionic liquids.

Ionic liquids (ILs) are increasingly of interest for environmentally open applications. Therefore, completely mineralising ILs are highly desirable. We reviewed the current state of knowledge on ILs' environmental biodegradability and identified research needs. Literature data were evaluated as for applied standard methods (e.g. OECD, ISO, APHA) for biodegradation of ILs in order to get an overview on the validity of the test results received and ILs' biodegradability. 109 studies were evaluated. The ILs were categorised based on the cation's core structure. The biodegradation data was classified according to a traffic light system (red: 0-19% degradation, amber: 20-59% degradation, green: ≥ 60% degradation). Not all studies could be assessed for compliance with the test guidelines due to missing test parameters. Moreover, no study discussed all validation criteria as defined by the test guidelines. Consequently, the reliability and quality of the existing biodegradation data is restrained. With regard to the different cations classified for ≥ 60% biodegradability, phosphonium ILs are the least biodegradable, followed by imidazolium ones. The most ILs that were biodegradable are cholinium ILs. The results indicate the need for more and qualitatively better testing according to standard methods including application and reporting of all validation criteria in order to get reliable data that enables the comparison of the test data and a comprehensive understanding of ILs' biodegradability. Moreover, reliable data allows the selection of sufficiently environmentally biodegradable ILs if an introduction into the environment during use cannot be excluded.

Abiotic and biotic degradation of five aromatic organosilicon compounds in aqueous media-Structure degradability relationships.

Silicones have many applications and are produced in large quantities. Despite their potential toxicity, information on their environmental mineralisation is scarce. Therefore, we investigated a group of five organosilicon compounds (o-MeOC6H4SiMe3 (1), p-MeOC6H4SiMe3 (2), (p-MeOC6H4)2SiMe2 (3), o-Me2NC6H4SiMe3 (4) and p-Me2NC6H4SiMe3 (5)), recently developed to be 'benign by design' based on their readily degradable core structure. Five different degradability tests were performed, one assessing hydrolytic and two analysing biological and photolytic stability, respectively. All substances, except (p-MeOC6H4)2SiMe2 (3), hydrolysed within 24 h to 50% indicating that this is one of the major pathways of their primary elimination. In agreement with previous research, none of the substances was readily biodegradable. In contrast, 100% of p-Me2NC6H4SiMe3 (5) was primarily eliminated by photolytic and hydrolytic processes. The elimination rates of the other substances ranged from 7% to 64%. Irradiation at shorter wavelengths increased both the extent and speed of photodegradation. Eleven transformation products of p-Me2NC6H4SiMe3 (5) were detected, all of which were completely eliminated within 64 min of irradiation with a Hg lamp (200-400 nm). The insertion of an electron-donating group on the benzene ring like in p-Me2NC6H4SiMe3 (5) clearly enhanced photolytic degradability but further research is necessary to achieve truly biodegradable silicones.