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Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO(2)-expanded liquids.
del Moral, Daniel; Banet Osuna, Anna M; Córdoba, Alba; Moretó, Josep M; Veciana, Jaume; Ricart, Susagna; Ventosa, Nora.
Chem Commun (Camb) ; (31): 4723-5, 2009 Aug 21.
Article in English | MEDLINE | ID: mdl-19641822

ABSTRACT

Selective mono or double carbonylations could be achieved by using CO(2)-expanded liquids in [2 + 2 + 1] carbonylative reactions of alkenes or acetylenes with allyl bromides catalyzed by Ni(i).


Subject(s)
Acetone/chemistry , Carbon Dioxide/chemistry , Nickel/chemistry , Alkynes/chemistry , Allyl Compounds/chemistry , Catalysis , Cyclization , Molecular Structure
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