1.
Phys Chem Chem Phys
; 16(22): 11017-23, 2014 Jun 14.
Article
in English
| MEDLINE
| ID: mdl-24777154
ABSTRACT
Research on homogeneous and heterogeneous catalysis is indeed convergent and finds subnanometric particles to be at the heart of catalytically active species. Here, monodisperse gold clusters are deposited from the gas phase onto porous titania generating well-defined model systems and the resulting composite materials exhibit a sharp size-dependency on the number of gold atoms per cluster and exceptionally high-turnovers toward the bromination of 1,4-dimethoxybenzene are observed. This indicates that the deliberate generation of active centres is of utmost importance for the creation of the most "gold-efficient" catalysts.