Microplastic contamination in wastewater: Sources, distribution, detection and remediation through physical and chemical-biological methods.

Microplastics are tiny plastic particles smaller than 5 mm. that have been widely detected in the environment, including in wastewater. They originate from various sources including breakdown of larger plastic debris, release of plastic fibres from textiles, and microbeads commonly used in personal care products. In wastewater, microplastics can pass through the treatment process and enter the environment, causing harm to biodiversity by potentially entering the food chain. Additionally, microplastics can act as a vector for harmful pollutants, increasing their transport and distribution in the environment. To address this issue, there is a growing need for effective wastewater treatment methods that can effectively remove microplastics. Currently, several physical and chemical methods are available, including filtration, sedimentation, and chemical degradation. However, these methods are costly, low efficiency and generate secondary pollutants. Furthermore, lack of standardization in the measurement and reporting of microplastics in wastewater, makes it difficult to accurately assess microplastic impact on the environment. In order to effectively manage these issues, further research and development of effective and efficient methods for removing microplastics from wastewater, as well as standardization in measurement and reporting, are necessary to effectively manage these detrimental contaminants.

Microplastics in mangroves with special reference to Asia: Occurrence, distribution, bioaccumulation and remediation options.

Microplastics (MPs) are a new and lesser-known pollutant that has intrigued the interest of scientists all over the world in recent decades. MP (<5mm in size) can enter marine environments such as mangrove forests in a variety of ways, interfering with the health of the environment and organisms. Mangroves are now getting increasingly exposed to microplastic contamination due to their proximity to human activities and their position as critical transitional zones between land and sea. The present study reviews the status of MPs contamination specifically in mangrove ecosystems situated in Asia. Different sources and characteristics of MPs, subsequent deposition of MPs in mangrove water and sediments, bioaccumulation in different organisms are discussed in this context. MP concentrations in sediments and organisms were higher in mangrove forests exposed to fishing, coastal tourism, urban, and industrial wastewater than in pristine areas. The distribution of MPs varies from organism to organism in mangrove ecosystems, and is significantly influenced by their morphometric characteristics, feeding habits, dwelling environment etc. Mangrove plants can accumulate microplastics in their roots, stem and leaves through absorption, adsorption and entrapment helping in reducing abundance of microplastic in the surrounding environment. Several bacterial and fungal species are reported from these mangrove ecosystems, which are capable of degrading MPs. The bioremediation potential of mangrove plants offers an innovative and sustainable approach to mitigate microplastic pollution. Diverse mechanisms of MP biodegradation by mangrove dwelling organisms are discussed in this context. Biotechnological applications can be utilized to explore the genetic potential of the floral and faunal species found in the Asian mangroves. Detailed studies are required to monitor, control, and evaluate MP pollution in sediments and various organisms in mangrove ecosystems in Asia as well as in other parts of the world.

Effects of microplastics and arsenic on plants: Interactions, toxicity and environmental implications.

Microplastics are emerging pollutants that are ubiquitously present in environment. Occurrence and dispersion of microplastics in the soil can pose a considerable risk to soil health and biodiversity, including the plants grown in the soil. Uptake and bioaccumulation of microplastics can have detrimental effects on different plant species. Additionally, the co-presence of microplastics and arsenic can cause synergistic, antagonistic, or potentiating toxic impacts on plants. However, limited studies are available on the combined effects of microplastics and arsenic on plants. This paper elucidates both the individual and synergistic effects of microplastics and arsenic on plants. At the outset, the paper highlighted the presence and degradation of microplastics in soil. Subsequently, the interactions between microplastics and plants, accumulation, and influences of microplastics on plant growth and metabolism were explained with underlying mechanisms. Combined effects of microplastics and arsenic on plant growth, metabolism, and toxicity were discussed thereafter. Combined toxic effects of microplastics and arsenic on plants can have detrimental implications on environment, ecosystems and biodiversity. Further investigations on food chain and human health are needed in the context of microplastic-arsenic interactions.

Microplastic pollution in the Himalayas: Occurrence, distribution, accumulation and environmental impacts.

Microplastics have been reported from various ecosystems including lakes, ponds, wetlands, mountains, and forests globally. Recent research works showed microplastic deposition and accumulation in the Himalayan mountains and adjoining ecosystems, rivers and streams. Fine particles of microplastic originating from different anthropogenic sources can travel long distances, even upwards (altitudinally) through atmospheric transport and can pollute remote and pristine locations situated in the Himalayas. Precipitation also plays a vital role in influencing deposition and fallout of microplastics in the Himalayas. Microplastics can be trapped in the snow in glaciers for a long time and can be released into freshwater rivers by snow melting. Microplastic pollution in Himalayan rivers such as the Ganga, Indus, Brahmaputra, Alaknanda, and Kosi has been researched on both the upper and lower catchments. Additionally, Himalayan region draws many domestic and international tourists throughout the year, resulting in generation of massive and unmanageable volume of plastics wastes and finally ending up in the open landscapes covering forests, river streams and valley. Fragmentation of these plastic wastes can lead to microplastic formation and accumulation in the Himalayas. This paper discusses and explains occurrence and distribution of microplastics in the Himalayan landscapes, possible adverse effects of microplastic on local ecosystems and human population and policy intervention needed to mitigate microplastic pollution in the Himalayas. A knowledge gap was noticed regarding the fate of microplastics in the freshwater ecosystems and their control mechanisms in the Indian Himalayas. Regulatory approaches for microplastics management in the Himalayas sit within the broader plastics/solid waste management and can be implemented effectively by following integrated approaches.

Occurrence and transport of SARS-CoV-2 in wastewater streams and its detection and remediation by chemical-biological methods.

This paper explains the transmission of SARS-CoV and influences of several environmental factors in the transmission process. The article highlighted several methods of collection, sampling and monitoring/estimation as well as surveillance tool for detecting SARS-CoV in wastewater streams. In this context, WBE (Wastewater based epidemiology) is found to be the most effective surveillance tool. Several methods of genomic sequencing are discussed in the paper, which are applied in WBE, like qPCR-based wastewater testing, metagenomics-based analysis, next generation sequencing etc. Additionally, several types of biosensors (colorimetric biosensor, mobile phone-based biosensors, and nanomaterials-based biosensors) showed promising results in sensing SARS-CoV in wastewater. Further, this review paper outlined the gaps in assessing the factors responsible for transmission and challenges in detection and monitoring along with the remediation and disinfection methods of this virus in wastewater. Various methods of disinfection of SARS-CoV-2 in wastewater are discussed (primary, secondary, and tertiary phases) and it is found that a suite of disinfection methods can be used for complete disinfection/removal of the virus. Application of ultraviolet light, ozone and chlorine-based disinfectants are also discussed in the context of treatment methods. This study calls for continuous efforts to gather more information about the virus through continuous monitoring and analyses and to address the existing gaps and identification of the most effective tool/ strategy to prevent SARS-CoV-2 transmission. Wastewater surveillance can be very useful in effective surveillance of future pandemics and epidemics caused by viruses, especially after development of new technologies in detecting and disinfecting viral pathogens more effectively.

Arsenic contamination in groundwater and food chain with mitigation options in Bengal delta with special reference to Bangladesh.

Bangladesh, situated in Bengal delta, is one of the worst affected countries by arsenic contamination in groundwater. Most of the people in the country are dependent on groundwater for domestic and irrigation purposes. Currently, 61 districts out of 64 districts of Bangladesh are affected by arsenic contamination. Drinking arsenic contaminated groundwater is the main pathway of arsenic exposure in the population. Additionally, the use of arsenic-contaminated groundwater for irrigation purpose in crop fields in Bangladesh has elevated arsenic concentration in surface soil and in the plants. In many arsenic-affected countries, including Bangladesh, rice is reported to be one of the significant sources of arsenic contamination. This review discussed scenario of groundwater arsenic contamination and transmission of arsenic through food chain in Bangladesh. The study further highlighted the human health perspectives of arsenic exposure in Bangladesh with possible mitigation and remediation options employed in the country.

Microbial strategies for degradation of microplastics generated from COVID-19 healthcare waste.

COVID-19 pandemic has led to the generation of massive plastic wastes, comprising of onetime useable gloves, masks, tissues, and other personal protective equipment (PPE). Recommendations for the employ of single-use disposable masks made up of various polymeric materials like polyethylene, polyurethane, polyacrylonitrile, and polypropylene, polystyrene, can have significant aftermath on environmental, human as well as animal health. Improper disposal and handling of healthcare wastes and lack of proper management practices are creating serious health hazards and an extra challenge for the local authorities designated for management of solid waste. Most of the COVID-19 medical wastes generated are now being treated by incineration which generates microplastic particles (MPs), dioxin, furans, and various toxic metals, such as cadmium and lead. Moreover, natural degradation and mechanical abrasion of these wastes can lead to the generation of MPs which cause a serious health risk to living beings. It is a major threat to aquatic lives and gets into foods subsequently jeopardizing global food safety. Moreover, the presence of plastic is also considered a threat owing to the increased carbon emission and poses a profound danger to the global food chain. Degradation of MPs by axenic and mixed culture microorganisms, such as bacteria, fungi, microalgae etc. can be considered an eco-sustainable technique for the mitigation of the microplastic menace. This review primarily deals with the increase in microplastic pollution due to increased use of PPE along with different disinfection methods using chemicals, steam, microwave, autoclave, and incineration which are presently being employed for the treatment of COVID-19 pandemic-related wastes. The biological treatment of the MPs by diverse groups of fungi and bacteria can be an alternative option for the mitigation of microplastic wastes generated from COVID-19 healthcare waste.

Learning from hospital deaths.

Current guidelines and regulations require trusts to take full responsibility for deaths within their premises. Higher than expected deaths indicate poor standards of care or negligence. NHS Trusts need to put systems in place to ensure that they learn and extrapolate risk factors through in-depth review of care provided to patients prior to their deaths, curb and ultimately diminish relative mortality through improved practices, and improve care and safety for the whole organisation. Mortality reviews can provide insight into the standard of care that dying patients receive; this matters as NHS Hospitals are the main providers of terminal care, nationally.

Coupled effects of microplastics and heavy metals on plants: Uptake, bioaccumulation, and environmental health perspectives.

Microplastic pollution has severe ecological and environmental concerns because of its enormous production and discharge in natural ecosystems worldwide. Microplastics interact with heavy metals and metalloids like arsenic, chromium, copper, cadmium, and lead in soil and can cause detrimental effects on soil structure and microbial activities and subsequently impact the plants and human health. This article focuses on microplastic translocation from soil to plants together with heavy metals. Microplastic exposure impacts biomass, photosynthetic activity, chlorophyll content, root and shoot length in the plants through apoplastic and symplastic pathways. Microplastics can also indirectly affect the plant growth by changing soil nutrient content and microbial community structure. At the same time, microplastics can absorb heavy metals and increase phytotoxicity in plants. However, the current knowledge about the coupled effect of heavy metals and microplastics bioaccumulation in plants is limited. It is postulated that heavy metals and microplastics collectively impact the chlorophyll content, photosynthetic activity, and induction of reactive oxygen species in plants. This work also outlines the environmental health perspectives based on microplastic and heavy metals toxicity and provides a guideline for future research on the coupled effects of heavy metals and microplastics on plants and humans.

Inhabiting the state subjunctively: Transgender life-making alongside death and a pandemic.

The Indian Prime Minister, Narendra Modi, while addressing the United Nations General Assembly on 26 September 2020, stated that India had introduced legal reforms to accord rights to transgender citizens. Even though there is not much material basis to these rights, transgender communities have been protesting against the state and at times negotiating with it to get laws that are more in alignment with their rights. In the wake of serialised deaths and precarity intensified by the Covid-19 pandemic, transgender communities also stage other negotiations in the everyday with activists, transnationally funded NGOs and academics researching their communities, encounters that are not as spectacular as the protests against the state, but that which ensures their daily sustenance. This paper investigates how they inhabit these systemically violent institutions. Deploying ethnographic field notes from eastern India, this paper argues that they inhabit them subjunctively, which is not about refusing engagement with what is oppressive but about the ceaseless conjuring of improvisatory and contingent gestures that are marked by hope as well as uncertainty. The simultaneity of protests, rage, hopelessness, hope, negotiations, supplications and scepticism allow them to not only endure the violence of institutions but also to rupture them and imagine them otherwise.

Conflict of interest in regulatory investigations on medical professionals.

Medical professionals' practices may be investigated by their employers. Biased and flawed investigations impact badly on clinicians' lives and careers but also reduce the quality of patient care provided, which in turn result in serious financial costs for the National Health Service. This article considers the importance of excluding conflict of interest while organising regulatory investigations. It explores the harmful effects that a biased and badly conducted investigation may have on staff and the possible ways of ensuring that investigations are fair and unbiased, with reference to Fit and Proper Persons Test and overarching responsibility of the Trust Board of Directors.

Calcium ion incorporated hydrous iron(III) oxide: synthesis, characterization, and property exploitation towards water remediation from arsenite and fluoride.

Calcium ion-incorporated hydrous iron(III) oxide (CIHIO) samples have been prepared aiming investigation of efficiency enhancement on arsenic and fluoride adsorption of hydrous iron(III) oxide (HIO). Characterization of the optimized product with various analytical tools confirms that CIHIO is microcrystalline and mesoporous (pore width, 26.97 Å; pore diameter, 27.742 Å with pore volume 0.18 cm3 g-1) material. Increase of the BET surface area (> 60%) of CIHIO (269.61 m2 g-1) relative to HIO (165.6 m2 g-1) is noticeable. CIHIO particles are estimated to be ~ 50 nm from AFM and TEM analyses. Although the pH optimized for arsenite and fluoride adsorptions are different, the efficiencies of CIHIO towards their adsorption are very good at pH 6.5 (pHzpc). The adsorption kinetics and equilibrium data of either tested species agree well, respectively, with pseudo-second order model and Langmuir monolayer adsorption phenomenon. Langmuir capacities (mg g-1at 303 K) estimated are 29.07 and 25.57, respectively, for arsenite and fluoride. The spontaneity of adsorption reactions (ΔG0 = - 18.02 to - 20.12 kJ mol-1 for arsenite; - 0.2523 to - 3.352 kJ mol-1 for fluoride) are the consequence of entropy parameter. The phosphate ion (1 mM) compared to others influenced adversely the arsenite and/or fluoride adsorption reactions. CIHIO (2.0 g L-1) is capable to abstract arsenite or fluoride above 90% from their solution (0 to 5.0 mg L-1). Mechanism assessment revealed that the adsorption of arsenite occurs via chelation, while of fluoride occurs with ion-exchange.