ABSTRACT
The influence of surface morphology and the oxidation state on the electrocatalytic activity of nanostructured electrodes is well recognized, yet disentangling their individual roles in specific reactions remains challenging. Here, we investigated the electrooxidation of sulfite ions in an alkaline environment using cyclic voltammetry on copper oxide nanostructured electrodes with different oxidation states and morphologies but with similar active areas. To this aim, we synthesized nanostructured Cu films made of nanoparticles or nanorods on top of glassy carbon electrodes. Our findings showed an enhanced sensitivity and a lower detection threshold when utilizing Cu(I) over Cu(II). Density functional theory-based thermochemical analysis revealed the underlying oxidation mechanism, indicating that while the energy gain associated with the process is comparable for both oxide surfaces, the desorption energy barrier for the resulting sulfate molecules is three times higher on Cu(II). This becomes the limiting step of the reaction kinetics and diminishes the overall electrooxidation efficiency. Our proposed mechanism relies on the tautomerization of hydroxyl groups confined on the surface of Cu-based electrodes. This mechanism might be applicable to electrochemical reactions involving other sulfur compounds that hold technological significance.
ABSTRACT
Este libro fue tejido con hebras de distintos colores. Todas ellas lucieron sus mejor perfil en las páginas del suplemento "Puerta Abierta" del matutino Presencia.
Subject(s)
Women , Gender RoleABSTRACT
El documento es tan solo traspasar el umbral de espacios en los que cotidianamente las mujeres hacen historia a traves de sus experiencias,sentires y saberes,y por tanto,este primer volumen recoge las huellas dejadas por algunas de sus protagonistas