1.
Chemistry
; 25(37): 8719-8724, 2019 Jul 02.
Article
in English
| MEDLINE
| ID: mdl-31070822
ABSTRACT
Cyclometalation of a triple helical N-doped phenylene cage prepared by ruthenium(0)-catalyzed diol-diene benzannulation delivers a chiral, conformationally constrained Ir(ppy)3 analogue. Like the parent complex, fac-Ir(ppy)3 , the iridium-containing PAH-cage is phosphorescent, but displays enhanced resistance to oxygen quenching.