Removal of arsenic from jarosite waste using hydrometallurgical treatment.

The jarosite waste used during this study consists of minute amount of arsenic that has a potential to be leached into environment when kept in open area. This study tried to recover arsenic from jarosite waste using hydrometallurgical treatment. The comprehensive characterization of jarosite samples was performed using various analytical techniques, including X-ray diffraction (XRD), Fourier transform Infrared (FTIR), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX), and it was characterized as natrojarosite. For optimal removal of arsenic, the response surface methodology (RSM) was applied with the key factors, including dosage (A), time (B), temperature (C), and acid concentration (D) on the recovery of arsenic. The results indicated that the dosage (A) and acid concentration (D) demonstrated significant positive effects on arsenic recovery. As expected, the higher dosage and acid concentration was associated with increased recovery percentages for the arsenic from jarosite. Whereas time (B) and temperature (C) did not exhibit statistically significant recovery of arsenic within the specified experimental range. The contour plots showed the optimal operating conditions for the highest recovery percentage was approximately 52.61% when 2.5 g of jarosite was treated with 10 mol/L acid for 150 min at operating temperature of 80°. Although our study showed very moderate recovery of arsenic, it is first report where arsenic has been removed from jarosite waste. Readjustment of range of operating parameters would provide more insight into the further optimization of the yield.

Adsorptive removal of oxytetracycline using MnO2-engineered pine-cone biochar: thermodynamic and kinetic investigation and process optimization.

Indiscriminate use of oxytetracycline is linked to the development of antibiotic-resistant genes, posing a serious threat to human health and ecosystem balance. This article reports the adsorptive elimination of oxytetracycline (OTC) from aqueous solution using a newly developed MnO2-modified pine-cone biochar (MnO2/PCBC). The MnO2/PCBC was characterized using X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, CHNS analyzer, inductively coupled plasma-optical emission spectroscopy, and Brunauer-Emmett-Teller N2 adsorption analyzer. Batch adsorption experiments, designed using the central composite design framework of response surface methodology, were conducted to investigate the influence of process variables on the adsorption of OTC onto MnO2/PCBC. The optimized conditions for achieving maximum removal (88.1%) were found to be at pH 8, MnO2/PCBC dose 0.44 g/L, initial OTC concentration 200 mg/L, and temperature 303 K. The adsorption process follows Langmuir (R2=0.95) and Freundlich (R2=0.95) isotherms and pseudo-second-order (R2=0.99) adsorption kinetics. The adsorption process was found to be endothermic (ΔH0 = 33.04 kJ/mol) and spontaneous in nature (ΔG0 from -1.33 kJ/mol at 283 K to -5.65 kJ/mol at 313 K). The synthesized MnO2/PCBC could be recycled and reused for OTC removal with a percentage removal of around 80% after fifth cycle. The results indicate an effective removal of oxytetracycline with only 0.44 g/L MnO2/PCBC with maximum adsorption capacity of 357.14 mg/g which demonstrates improved performance in comparison to many adsorbents reported in literature. This implies that MnO2/PCBC offers potential to be developed into a cost-effective technique for antibiotic removal from water.

A critical review on biochar production from pine wastes, upgradation techniques, environmental sustainability, and challenges.

Pine wastes, including pine needles, cones, and wood, are abundantly produced as an agroforestry by-product globally and have shown tremendous potential for biochar production. Various thermochemical conversion technologies have exhibited promising results in converting pine wastes to biochar, displaying impressive performance. Hence, this review paper aims to investigate the possibilities and recent technological advancements for synthesizing biochar from pine waste. Furthermore, it explores techniques for enhancing the properties of biochar and its integrated applications in various fields, such as soil and water remediation, carbon sequestration, battery capacitor synthesis, and bio-coal production. Finally, the paper sheds light on the limitations of current strategies, emphasizing the need for further research and study to address the challenges in pine waste-based biochar synthesis. By promoting sustainable and effective utilization of pine wastes, this review contributes to environmental conservation and resource management.

Utilization of layered double hydroxides (LDHs) and their derivatives as photocatalysts for degradation of organic pollutants.

Direct or indirect discharge of wastes containing organic pollutants have contributed to the environmental pollution globally. Decontamination of highly polluted natural resources such as water using an effective treatment is a great challenge for public health and environmental protection. Photodegradation of organic pollutants using efficient photocatalyst has attracted extensive interest due to their stability, effectiveness towards degradation efficiency, energy, and cost efficiency. Among various photocatalysts, layered double hydroxides (LDHs) and their derivatives have shown great potential towards photodegradation of organic pollutants. Herein, we review the mechanism, key factors, and performance of LDHs and their derivatives for the photodegradation of organic pollutants. LDH-based photocatalysts are classified into three different categories namely unmodified LDHs, modified LDHs, and calcined LDHs. Each LDH category is reviewed separately in terms of their photodegradation efficiency and kinetics of degradation. In addition, the effect of photocatalyst dose, pH, and initial concentration of pollutant as well as photocatalytic mechanisms are also summarized. Lastly, the stability and reusability of different photocatalysts are discussed. Challenges related to modeling the LDHs and its derivatives are addressed in order to improve their functional capacity.

SARS-CoV-2: sewage surveillance as an early warning system and challenges in developing countries.

Transmission of novel coronavirus (SARS-CoV-2) in humans happens either through airway exposure to respiratory droplets from an infected patient or by touching the virus contaminated surface or objects (fomites). Presence of SARS-CoV-2 in human feces and its passage to sewage system is an emerging concern for public health. Pieces of evidence of the occurrence of viral RNA in feces and municipal wastewater (sewage) systems have not only warned reinforcing the treatment facilities but also suggest that these systems can be monitored to get epidemiological data for checking trend of COVID-19 infection in the community. This review summarizes the occurrence and persistence of novel coronavirus in sewage with an emphasis on the possible water environment contamination. Monitoring of novel coronavirus (SARS-CoV-2) via sewage-based epidemiology could deliver promising information regarding rate of infection providing a valid and complementary tool for tracking and diagnosing COVID-19 across communities. Tracking the sewage systems could act as an early warning tool for alerting the public health authorities for necessary actions. Given the impracticality of testing every citizen with limited diagnostic resources, it is imperative that sewage-based epidemiology can be tested as an early warning system. The need for the development of robust sampling strategies and subsequent detection methodologies and challenges for developing countries are also discussed.