Postmelting hydrogen enrichment in the oceanic lithosphere.

The large range of H2O contents recorded in minerals from exhumed mantle rocks has been challenging to interpret, as it often records a combination of melting, metasomatism, and diffusional processes in spatially isolated samples. Here, we determine the temporal variations of H2O contents in pyroxenes from a 24-Ma time series of abyssal peridotites exposed along the Vema fracture zone (Atlantic Ocean). The H2O contents of pyroxenes correlate with both crustal ages and pyroxene chemistry and increase toward younger and more refractory peridotites. These variations are inconsistent with residual values after melting and opposite to trends often observed in mantle xenoliths. Postmelting hydrogen enrichment occurred by ionic diffusion during cryptic metasomatism of peridotite residues by low-degree, volatile-rich melts and was particularly effective in the most depleted peridotites. The presence of hydrous melts under ridges leads to widespread hydrogen incorporation in the oceanic lithosphere, likely lowering mantle viscosity compared to dry models.

High H2O Content in Pyroxenes of Residual Mantle Peridotites at a Mid Atlantic Ridge Segment.

Global correlations of mid-ocean-ridges basalt chemistry, axial depth and crustal thickness have been ascribed to mantle temperature variations affecting degree of melting. However, mantle H2O content and elemental composition may also play a role. How H2O is distributed in the oceanic upper mantle remains poorly constrained. We tackled this problem by determining the H2O content of orthopyroxenes (opx) and clinopyroxenes (cpx) of peridotites from a continuous lithospheric section created during 26 Ma at a 11°N Mid-Atlantic Ridge segment, and exposed along the Vema Transform. The H2O content of opx ranges from 119 ppm to 383 ppm; that of cpx from 407 ppm to 1072 ppm. We found anomalous H2O-enriched peridotites with their H2O content not correlating inversely with their degree of melting, although H2O is assumed to be incompatible during melting. Inverse correlation of H2O with Ce, another highly incompatible component, suggests post-melting H2O enrichment. We attribute a major role to post-melting temperature-dependent diffusion of hydrogen occurring above the melting region, where water-rich melt flows faster than residual peridotites through dunitic conduits cross-cutting the uprising mantle. Accordingly, estimates of the H2O content of the MORB mantle source based on H2O in abyssal peridotites can be affected by strong uncertainties.

Lake Afrera, a structural depression in the Northern Afar Rift (Red Sea).

The boundary between the African and Arabian plates in the Southern Red Sea region is displaced inland in the northern Afar rift, where it is marked by the Red Sea-parallel Erta Ale, Alaita, and Tat Ali volcanic ridges. The Erta Ale is offset by about 20 and 40 km from the two en echelon ridges to the south. The offset area is highly seismic and marked by a depression filled by lake Afrera, a saline body of water fed by hydrothermal springs. Acoustic bathymetric profiles show ≈80 m deep canyons parallel to the NNW shore of the lake, part of a system of extensional normal faults striking parallel to the Red Sea. This system is intersected by oblique structures, some with strike-slip earthquakes, in what might evolve into a transform boundary. Given that the lake's surface lies today about 112 m below sea level, the depressed (minus ≈190 m below sea level) lake's bottom area may be considered the equivalent of the "nodal deep" in slow-slip oceanic transforms. The chemistry of the lake is compatible with the water having originated from hydrothermal liquids that had reacted with evaporites and basalts, rather than residual from evaporation of sea water. Bottom sediments include calcitic grains, halite and gypsum, as well as ostracod and diatom tests. The lake's level appears to have dropped by over 10 m during the last ≈50 years, continuing a drying up trend of the last few thousand years, after a "wet" stage 9,800 and 7,800 years before present when according to Gasse (1973) Lake Afrera covered an area several times larger than at present. This "wet" stage corresponds to an early Holocene warm-humid climate that prevailed in Saharan and Sub Saharan Africa. Lake Abhé, located roughly 250 km south of Afrera, shows similar climate-driven oscillations of its level.

Post-mesozoic rapid increase of seawater Mg/Ca due to enhanced mantle-seawater interaction.

The seawater Mg/Ca ratio increased significantly from ~ 80 Ma to present, as suggested by studies of carbonate veins in oceanic basalts and of fluid inclusions in halite. We show here that reactions of mantle-derived peridotites with seawater along slow spreading mid-ocean ridges contributed to the post-Cretaceous Mg/Ca increase. These reactions can release to modern seawater up to 20% of the yearly Mg river input. However, no significant peridotite-seawater interaction and Mg-release to the ocean occur in fast spreading, East Pacific Rise-type ridges. The Mesozoic Pangean superocean implies a hot fast spreading ridge system. This prevented peridotite-seawater interaction and Mg release to the Mesozoic ocean, but favored hydrothermal Mg capture and Ca release by the basaltic crust, resulting in a low seawater Mg/Ca ratio. Continent dispersal and development of slow spreading ridges allowed Mg release to the ocean by peridotite-seawater reactions, contributing to the increase of the Mg/Ca ratio of post-Mesozoic seawater.

Mediterranean megaturbidite triggered by the AD 365 Crete earthquake and tsunami.

Historian Ammianus Marcellinus documented the devastating effects of a tsunami hitting Alexandria, Egypt, on July 21, AD 365. "The solidity of the earth was made to shake … and the sea was driven away. The waters returning when least expected killed many thousands by drowning. Huge ships… perched on the roofs of houses… hurled miles from the shore….". Other settlements around the Mediterranean were hit at roughly the same time. This scenario is similar to that of the recent Sumatra and Tohoku tsunamis. Based on geophysical surveys and sediment cores from the Ionian Sea we show that the 20-25 m thick megaturbidite known in the literature as Homogenite/Augias was triggered not by the Santorini caldera collapse but by the 365 AD Cretan earthquake/tsunami. An older similar megaturbidite was deposited after 14.590 ± 80 yr BP, implying a large recurrence time of such extreme sedimentary events in the Mediterranean Sea.

Water-rich basalts at mid-ocean-ridge cold spots.

Although water is only present in trace amounts in the suboceanic upper mantle, it is thought to play a significant role in affecting mantle viscosity, melting and the generation of crust at mid-ocean ridges. The concentration of water in oceanic basalts has been observed to stay below 0.2 wt%, except for water-rich basalts sampled near hotspots and generated by 'wet' mantle plumes. Here, however, we report unusually high water content in basaltic glasses from a cold region of the mid-ocean-ridge system in the equatorial Atlantic Ocean. These basalts are sodium-rich, having been generated by low degrees of melting of the mantle, and contain unusually high ratios of light versus heavy rare-earth elements, implying the presence of garnet in the melting region. We infer that water-rich basalts from such regions of thermal minima derive from low degrees of 'wet' melting greater than 60 km deep in the mantle, with minor dilution by melts produced by shallower 'dry' melting--a view supported by numerical modelling. We therefore conclude that oceanic basalts are water-rich not only near hotspots, but also at 'cold spots'.

Mantle thermal pulses below the Mid-Atlantic Ridge and temporal variations in the formation of oceanic lithosphere.

A 20-Myr record of creation of oceanic lithosphere is exposed along a segment of the central Mid-Atlantic Ridge on an uplifted sliver of lithosphere. The degree of melting of the mantle that is upwelling below the ridge, estimated from the chemistry of the exposed mantle rocks, as well as crustal thickness inferred from gravity measurements, show oscillations of approximately 3-4 Myr superimposed on a longer-term steady increase with time. The time lag between oscillations of mantle melting and crustal thickness indicates that the mantle is upwelling at an average rate of approximately 25 mm x yr(-1), but this appears to vary through time. Slow-spreading lithosphere seems to form through dynamic pulses of mantle upwelling and melting, leading not only to along-axis segmentation but also to across-axis structural variability. Also, the central Mid-Atlantic Ridge appears to have become steadily hotter over the past 20 Myr, possibly owing to north-south mantle flow.