ABSTRACT
Electric vehicles demand high charge and discharge rates creating potentially dangerous temperature rises. Lithium-ion cells are sealed during their manufacture, making internal temperatures challenging to probe1. Tracking current collector expansion using X-ray diffraction (XRD) permits non-destructive internal temperature measurements2; however, cylindrical cells are known to experience complex internal strain3,4. Here, we characterize the state of charge, mechanical strain and temperature within lithium-ion 18650 cells operated at high rates (above 3C) by means of two advanced synchrotron XRD methods: first, as entire cross-sectional temperature maps during open-circuit cooling and second, single-point temperatures during charge-discharge cycling. We observed that a 20-minute discharge on an energy-optimized cell (3.5 Ah) resulted in internal temperatures above 70 °C, whereas a faster 12-minute discharge on a power-optimized cell (1.5 Ah) resulted in substantially lower temperatures (below 50 °C). However, when comparing the two cells under the same electrical current, the peak temperatures were similar, for example, a 6 A discharge resulted in 40 °C peak temperatures for both cell types. We observe that the operando temperature rise is due to heat accumulation, strongly influenced by the charging protocol, for example, constant current and/or constant voltage; mechanisms that worsen with cycling because degradation increases the cell resistance. Design mitigations for temperature-related battery issues should now be explored using this new methodology to provide opportunities for improved thermal management during high-rate electric vehicle applications.
ABSTRACT
A polymer electrolyte fuel cell has been designed to allowoperandox-ray absorption spectroscopy (XAS) measurements of catalysts. The cell has been developed to operate under standard fuel cell conditions, with elevated temperatures and humidification of the gas-phase reactants, both of which greatly impact the catalyst utilisation. X-ray windows in the endplates of the cell facilitate collection of XAS spectra during fuel cell operation while maintaining good compression in the area of measurement. Results of polarisation curves and cyclic voltammograms showed that theoperandocell performs well as a fuel cell, while also providing XAS data of suitable quality for robust XANES analysis. The cell has produced comparable XAS results when performing a cyclic voltammogram to an establishedin situcell when measuring the Pt LIII edge. Similar trends of Pt oxidation, and reduction of the formed Pt oxide, have been presented with a time resolution of 5 s for each spectrum, paving the way for time-resolved spectral measurements of fuel cell catalysts in a fully-operating fuel cell.
ABSTRACT
The data presented here were collected from a commercial LG Chem cylindrical INR18650 MJ1 lithium-ion (Li-ion) battery (approximate nominal specifications: 3.5 Ah, 3.6â¯V, 12.2â¯Wh). Electrochemical and microstructural information is presented, the latter collected across several length scales using X-ray computed tomography (CT): from cell to particle. One cell-level tomogram, four assembly-level and two electrode/particle-level 3D datasets are available; all data was collected in the pristine state. The electrochemical data consists of the full current and voltage charge-discharge curves for 400 operational cycles. All data has been made freely available via a repository [10.5522/04/c.4994651] in order to aid in the development of improved computational models for commercially-relevant Li-ion battery materials.
ABSTRACT
Hollow structured nanomaterials with void space available inside the shells can effectively enhance electrocatalytic activity due to their high specific surface area, volume buffer and shell permeability properties. In this study, low-cost and hollow structured bimetal phosphide nanowires are synthesized directly on Ni foam via the Kirkendall effect by using NaH2PO2 as a phosphorizing agent at 350 °C. Both the crystal and hollow structures of the obtained phosphide can be efficiently tuned by controlling the amount of phosphorizing agent and the phosphorizing time. The morphology and microstructure of the obtained phosphides are characterised using various techniques, which indicate that the formation mechanism of the hollow structure is consistent with the Kirkendall effect. The optimized bimetal phosphide sample demonstrates a low onset potential (59 mV) at a current density of 10 mA cm-2, low charge transfer resistance (0.83 Ω) and superior durability in the hydrogen evolution reaction (HER) for water electrolysis. The electrochemical results clearly demonstrate that the hollow structure can efficiently improve the HER properties and the obtained phosphide is a promising HER catalysts for water splitting in KOH or seawater electrolytes.
ABSTRACT
This article reports the data required for planning attenuation-based X-ray characterisation e.g. X-ray computed tomography (CT), of lithium-ion (Li-ion) battery cathodes. The data reported here is to accompany a co-submitted manuscript (10.1016/j.matdes.2020.108585 [1]) which compares two well-known X-ray attenuation data sources: Henke et al. and Hubbell et al., and applies methodology reported by Reiter et al. to extend this data towards the practical characterisation of prominent cathode materials. This data may be used to extend beyond the analysis reported in the accompanying manuscript, and may aid in the applications for other materials, not limited to Li-ion batteries.
ABSTRACT
The growth of electrodeposited lithium microstructures on metallic lithium electrodes has prevented their use in rechargeable lithium batteries due to early performance degradation and safety implications. Understanding the evolution of lithium microstructures during battery operation is crucial for the development of an effective and safe rechargeable lithium-metal battery. This study employs both synchrotron and laboratory X-ray computed tomography to investigate the morphological evolution of the surface of metallic lithium electrodes during a single cell discharge and over numerous cycles, respectively. The formation of surface pits and the growth of mossy lithium deposits through the separator layer are characterised in three-dimensions. This has provided insight into the microstructural evolution of lithium-metal electrodes during rechargeable battery operation, and further understanding of the importance of separator architecture in mitigating lithium dendrite growth.
ABSTRACT
A robust and versatile sample preparation technique for the fabrication of cylindrical pillars for imaging by X-ray nano-computed tomography (nano-CT) is presented. The procedure employs simple, cost-effective laser micro-machining coupled with focused-ion beam (FIB) milling, when required, to yield mechanically robust samples at the micrometre length-scale to match the field-of-view (FOV) for nano-CT imaging. A variety of energy and geological materials are exhibited as case studies, demonstrating the procedure can be applied to a variety of materials to provide geometrically optimised samples whose size and shape are tailored to the attenuation coefficients of the constituent phases. The procedure can be implemented for the bespoke preparation of pillars for both lab- and synchrotron-based X-ray nano-CT investigations of a wide range of samples.
ABSTRACT
Pt and PtSn catalysts were studied for n-butanol electro-oxidation at various temperatures. PtSn showed a higher activity towards butanol electro-oxidation compared to Pt in acidic media. The onset potential for n-butanol oxidation on PtSn is â¼520 mV lower than that found on Pt, and significantly lower activation energy was found for PtSn compared with that for Pt.
Subject(s)
Butanols/chemistry , Platinum/chemistry , Tin/chemistry , Biofuels , Catalysis , Electrochemical Techniques , Electrodes , Oxidation-ReductionABSTRACT
Raman spectroscopy is a noninvasive and highly sensitive analytical technique capable of identifying chemical compounds in environments that can mimic SOFC operating conditions. Here we demonstrate the use of Raman spectroscopy to perform local thermal and temporal measurements, both of which are essential if phase formation diagrams are to be mapped out and compared to thermodynamic phase stability predictions. We find that the time resolution of the Raman technique is more than sufficient to capture essential dynamic effects associated with a change of chemical composition.