Energy efficient sludge solubilization by microwave irradiation under carbon nanotube (CNT)-coated condition.

Microwaves (MW) have great potential for sludge solubilization, and carbon materials can act as good microwave absorbers and heat transfer media because of their high dielectric loss tangent and thermal conductivity. In this study, carbon nanotube-coated MW vessels were developed by preparing a silane-CNT mixture and spray coating. In addition, sludge solubilization by microwave irradiation was performed to evaluate the effects of the CNT-coating at different initial total suspended solid (TSS) concentrations, target temperatures, and MW irradiation times in the uncoated and CNT-coated MW vessels. The sludge solubilization efficiency increased with increasing MW irradiation time and temperature and followed a first-order reaction in both vessels. However, the energy requirement to maintain the temperature was reduced in the CNT-coated MW vessel compared to the uncoated vessel. In addition, the Arrhenius equation revealed the catalytic site in the CNT-coated MW vessel to have a temperature of around 130 °C at an average sludge temperature of 100 °C. The maximum chemical oxygen demand (COD) solubilization and soluble COD (sCOD) increase per MW energy used were 1.64 and 1.67 times higher in the CNT-coated MW vessel than in the uncoated vessel, respectively. The increase in soluble total nitrogen and phosphorus in the CNT-coated MW vessel was attributed to cell wall destruction and intracellular protoplast dissolution, because of the acceleration of the MW thermal effect and high conductivity of CNTs, as well as the MW-induced cell wall and membrane disruption by hot spots on the CNT surface. This suggests that CNTs can be applied to increase the energy efficiency in MW-based pretreatment methods.

Field-scale application of spent sulfidic caustic as a source of alternative electron donor for autotrophic denitrification.

Biological reuse of spent sulfidic caustic (SSC) originating from oil refineries is a promising method for the petrochemical industry because of low handling cost. SSC typically contains high concentrations of sulfur, with the most dominant sulfur compounds being sulfide (S(2-)). SSC is also characterized by a high pH and elevated alkalinity up to 5-15% by weight. Because of these characteristics, SSC can be used for denitrification of NO3(-)-N in the biological nitrogen removal process as both the electron donor and buffering agent in sulfur-utilizing autotrophic denitrification. In this study, two kinds of SSC (SSC I, SSC II) produced from two petrochemical companies were used for autotrophic denitrification in a field-scale wastewater treatment plant (WWTP). The effluent total nitrogen (TN) concentration in this process was about 10.5 mg/L without any external carbon sources and the nitrification efficiency was low, about 93.0%, because of alkalinity deficiency in the influent. The injection of SSC I, but not SSC II, promoted nitrification efficiency, which was attributed to the difference in the NaOH/S ratio between SSC I and II. SSC was injected based on sulfide concentration of SSC required to denitrify NO3(-)-N in the WWTP. SSC I had higher NaOH/S than SSC II and thus could supply more alkalinity for nitrification than SSC II. On the other hand, additional TN removal of about 9.0% was achieved with the injection of both SSCs. However, denitrification efficiency was not proportionally increased with increasing SSC injection because of NO3(-)-N deficiency in the anoxic tank due to the limited capacity of the recycling pump. For the same reason, sulfate concentration, which is the end product of sulfur-utilizing autotrophic denitrificaiton in the effluent, was also not increased with increasing SSC injection.

Application of ultrasound and air stripping for the removal of aromatic hydrocarbons from spent sulfidic caustic for use in autotrophic denitrification as an electron donor.

Spent sulfidic caustic (SSC) produced from petroleum industry can be reused to denitrify nitrate-nitrogen via a biological nitrogen removal process as an electron donor for sulfur-based autotrophic denitrification, because it has a large amount of dissolved sulfur. However, SSC has to be refined because it also contains some aromatic hydrocarbons, typically benzene, toluene, ethylbenzene, xylene (BTEX) and phenol that are recalcitrant organic compounds. In this study, laboratory-scale ultrasound irradiation and air stripping treatment were applied in order to remove these aromatic hydrocarbons. In the ultrasound system, both BTEX and phenol were exponentially removed by ultrasound irradiation during 60 min of reaction time to give the greatest removal efficiency of about 80%. Whereas, about 95% removal efficiency of BTEX was achieved, but not any significant phenol removal, within 30 min in the air stripping system, indicating that air stripping was a more efficient method than ultrasound irradiation. However, since air stripping did not remove any significant phenol, an additional process for degrading phenol was required. Accordingly, we applied a combined ultrasound and air stripping process. In these experiments, the removal efficiencies of BTEX and phenol were improved compared to the application of ultrasound and air stripping alone. Thus, the combined ultrasound and air stripping treatment is appropriate for refining SSC.

Microbial community structure and dynamics in a mixotrophic nitrogen removal process using recycled spent caustic under different loading conditions.

A laboratory-scale Bardenpho process was established to investigate the proper nitrogen loading rate (NLR) when modified spent caustic (MSC) is applied as electron donor and alkalinity source for denitrification. MSC injection induced autotrophic nitrogen removal with sulfur as electron donor and heterotrophic denitrification. The nitrogen removal rate (NRR) did not increase proportionally to NLR. Based on the total nitrogen concentration in the effluent observed in the trials with MSC, the NLR in the influent should not exceed 0.15 kg N/m(3)d in order to satisfy water quality regulations. Microbial communities in the anoxic reactors were characterized by pyrosequencing of 16S rRNA gene sequences amplified by the polymerase chain reaction of DNA extracted from sludge samples. Microbial diversity was lower as MSC dosage was increased, and the injection of MSC caused an increase in SOB belonging to the genus Thiobacillus which is responsible for denitrification using sulfur.

Comparison of nitrogen removal and microbial distribution in wastewater treatment process under different electron donor conditions.

The applicability of modified spent caustic (MSC) as an electron donor for denitrification was evaluated in a lab-scale reactor for the Bardenpho process under various electron donor conditions: (A) no electron donor, (B) methanol, (C) thiosulfate and (D) MSC conditions. TN removal efficiency varied in each condition, 23.1%, 87.8%, 83.7% and 71.7%, respectively. The distribution ratio of nitrifying bacteria and DGGE profile including sulfur-reducing or oxidizing bacteria also varied depending on the conditions. These results indicated that the MSC would be used as an efficient electron donor for denitrification by autotrophic denitrifier in wastewater treatment process.