"Flexible-strong" polylactic acid porous membrane via tailored polymerization degree of lactic acid side-chains grafting for passive daytime radiative cooler.

Aerogel possesses the advantages of high specific surface area, low density, and high porosity, which have shown great application in thermal regulation due to its efficient light scattering capability. However, traditional polymer-based aerogels have poor mechanical properties and lack ductility in outdoor applications, the cooling efficiency of the material is easily affected by damage during transportation, installation, and environmental factors. In this work, combining the porous nature of aerogels and the high ductility of membranes, a polylactic acid-based porous membrane cooler was developed by combining a regular honeycomb surface porous structure design and physical/chemical modification to enhance flexibility, using a simple non-solvent induced phase separation method. This porous membrane exhibits both super-flexibility (116 % elongation at break) and porous characteristics. It achieves a sub-ambient temperature decrease of 4-6 °C under direct sunlight. The optimized porous membrane demonstrates high solar reflectance (94 % of peak reflectivity, 90 % of average reflectivity) and strong infrared emissivity (96 % of peak emissivity, 91 % of average emissivity), it also maintains a solar peak reflectivity of 91 % under 100 % tensile strain and 1000 bending cycles, the cooler still maintains a cooling effect of 2-5 °C below ambient temperature. This work paves the way for developing mechanical flexible and strong radiative coolers for thermal regulation.

Tree transpiration-inspired cellulose aerogel with engineered cold-evaporated surface for promoting structural stability and minimizing energy loss.

Solar-driven evaporation technology could significantly relieve the fresh-water crisis in the world. However, several problems, such as poor structural stability, low photothermal conversion capacity, and single heat source of traditional evaporators limited the promotion of fresh-water production efficiency. Herein, inspired by tree transpiration, we report a hydrophilic three-dimensional (3D) cellulose-based evaporator similar to the root of a tree, which can pump the bottom water to the evaporation surface for vapor generation. The aldehyde-based cellulose nanocrystals/ethylene imine polymer (ACP) aerogel was developed through Schiff base reaction to enhance the chain entangle capacity of the cellulose nanocrystals (CNCs) aerogel in water. Coating the ACP aerogel with lignin-derived photothermal material created the double-layered solar-driven evaporator (ACP-7LM), achieving a remarkable surface temperature of 35.9 °C in water under 1 sun irradiation for 1 h. The ACP-7LM exhibited an impressive evaporation rate of 1.60 kg m-2 h-1, leveraging its structural stability and excellent photothermal conversion. Increasing the cold evaporation surface (adjusting exposure height from 0 cm to 4 cm) of ACP-7LM aerogel maintained a lower temperature compared to ambient temperature on the side surface during evaporation, which harvest heat energy from environment and minimize energy loss. This enhanced environmental heat absorption boosted the ACP-7LM's evaporation rate to 3.76 kg m-2 h-1, a 2.35-fold increase over the ACP-7LM (0 cm). This solar-driven evaporator offers an efficient, innovative approach to elevate evaporation rates and address the global water crisis by simultaneously enhancing heat absorption capacity and photothermal conversion efficiency.