PM2.5-bound trace metals in an urban area of Northern Mexico during the COVID-19 pandemic: characterization, sources, and health risk.

Abstract: A field study was carried out in the Metropolitan Area of Monterrey (MAM), the second most populated city in Mexico, characterized by increasing urbanization, high traffic density, and intense industrial activity. These characteristics commonly present high concentrations of air pollutants leading to the degradation of air quality. PM2.5 was analyzed for heavy metals at two urban sites located within the MAM (Juarez and San Bernabe) in order to determine sources, health risk, morphology, and elemental content during the COVID-19 pandemic (autumn 2020 and spring 2021). Twenty-four-hour samples of PM2.5 were collected at each site during 30-day periods using high-volume equipment. Gravimetric concentrations and 11 metals were measured (Ca, Cd, Co, Cu, Fe, K, Mg, Mn, Ni, Cr, and Pb) by different analytical techniques (flame atomic absorption spectroscopy, graphite furnace atomic absorption spectroscopy, and inductively coupled plasma optical emission spectroscopy). Selected samples were analyzed by scanning electron microscopy-energy-disperse spectroscopy in order to characterize their morphology and elemental content. PM2.5 concentrations exceeded the Mexican standard and WHO guidelines in Juarez during spring 2021. Cu, Cd, and Co were highly enriched by anthropogenic sources, and Ni, K, Cr, and Pb had a moderate enrichment. Mg, Mn, and Ca were of crustal origin. Bivariate statistics and PCA confirmed that alkaline metals originated from crustal sources and that the main sources of trace metals included traffic emissions, resuspension from soil/road dust, steel industry, smelting, and non-exhaust emissions at both sites. Lifetime cancer risk coefficients did not exceed the permissible levels established by EPA and WHO, implying that local residents are not at risk of developing cancer. Non-carcinogenic risk coefficients revealed that there is a possible risk of suffering cardiovascular and respiratory diseases due to inhalation of cobalt at the study sites. Supplementary Information: The online version contains supplementary material available at 10.1007/s11869-023-01372-7.

Atmospheric dispersion of methane emissions from sugarcane burning in Mexico.

Methane is a potent greenhouse gas whose atmospheric dispersion may have different implications at distinct scales. One significant contributor to methane emissions is sugarcane farming in tropical areas like in Mexico, which has the sixth highest production level in the world. A consequence of the industrial use of this resource is that sugarcane preharvest burning emits large quantities of methane and other pollutants. The objective of this research is to estimate the methane emissions by sugarcane burning and to analyze their atmospheric dispersion under the influence of meteorological parameters, according to different concentration scenarios generated during a period. The methane emissions were investigated using the methodology of Seiler and Crutzen, based on the stage production during the harvest periods of 2011/2012, 2012/2013 and 2013/2014. Average of total emissions (1.4 × 103 Mg) at the national level was comparable in magnitude to those of other relevant sugarcane-producing countries such as India and Brazil. Satellite images and statistical methods were used to validate the spatial distribution of methane, which was obtained with the WRF model. The results show a dominant wind circulation pattern toward the east in the San Luis Potosi area, to the west in Jalisco, and the north in Tabasco. In the first two areas, wind convergence at a certain height causes a downward flow, preventing methane dispersion. The concentrations in these areas varied from 9.22 × 10-5 to 1.22 × 102 ppmv and 32 × 10-5 to 2.36 × 102 ppmv, respectively. Wind conditions in Tabasco contributed to high dispersion and low concentrations of methane, varying from 8.74 × 105 to 0.33 × 102 ppmv. Methane is a potent greenhouse gas for which it is essential to study and understand their dispersion at different geographic locations and atmospheric conditions.