ABSTRACT
The characterisation of hydrochars derived from Sargassum biomass collected along the Mexican Caribbean coast reveals their favourable morphology and chemical composition for incorporating metal ions, including Cd(II) and Pb(II). Among the synthesized materials, HCS-3, produced at 180 °C with a 2 h residence time, exhibited superior yield, specific area, carbon content, and capacity for removing Cd(II) and Pb(II). Adsorption equilibrium studies demonstrate the presence of adsorption processes during Cd(II) and Pb(II) retention on HCS-3, with adsorption capacities slightly exceeding 140 and 340 mg gâ»1, respectively. Notably, HCS-3 shows a greater affinity for Pb(II) over Cd(II) when both elements are present concurrently. The physicochemical analysis through FTIR spectroscopy, functional group analysis, point of zero charge determination, SEM/EDS, and other techniques evidenced that HCS-3 possesses favourable characteristics to serve as a heavy metal adsorbent. These findings underscore the efficacy of hydrochars from Sargassum biomass in removing heavy metals, suggesting their potential as superior adsorbents compared to traditional or novel materials, and advising its possible versatility for other pollutants. Utilizing these hydrochars could mitigate the economic and environmental impact of Sargassum biomass by repurposing it for valuable applications.
ABSTRACT
Bio-carbon-manganese composites obtained from olive mill wastewater were successfully prepared using manganese acetate as the manganese source and olive wastewater as the carbon precursor. The samples were characterized chemically and texturally by N2 and CO2 adsorption at 77 K and 273 K, respectively, by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction. Electrochemical characterization was carried out by cyclic voltammetry (CV) and linear sweep voltammetry (LSV). The samples were evaluated in the electro-Fenton degradation of tetracycline in a typical three-electrode system under natural conditions of pH and temperature (6.5 and 25 °C). The results show that the catalysts have a high catalytic power capable of degrading tetracycline (about 70%) by a three-electron oxygen reduction pathway in which hydroxyl radicals are generated in situ, thus eliminating the need for two catalysts (ORR and Fenton).
ABSTRACT
Carbon xerogel spheres co-doped with nitrogen and eco-graphene were synthesized using a typical solvothermal method. The results indicate that the incorporation of eco-graphene enhances the electrochemical properties, such as the current density (JK) and the selectivity for the four transferred electrons (n). Additionally, nitrogen doping has a significant effect on the degradation efficiency, varying with the size of the carbon xerogel spheres, which could be attributed to the type of nitrogenous group doped in the carbon material. The degradation efficiency improved in the nanometric spheres (48.3% to 61.6%) but decreased in the micrometric-scale spheres (58.6% to 53.4%). This effect was attributed to the N-functional groups present in each sample, with N-CNS-5 exhibiting a higher percentage of graphitic nitrogen (35.7%) compared to N-CMS-5 (15.3%). These findings highlight the critical role of sphere size in determining the type of N-functional groups present in the sample. leading to enhanced degradation of pollutants as a result of the electro-Fenton process.
ABSTRACT
Until now, black titania has attracted much interest as a potential photocatalyst. In this contribution, we report the first demonstration of the effective strategy to fundamentally improve the photocatalytic performance using a novel sustainable defective titaniumcarbon-phosphorous (TCPH) hybrid nanocomposite. The prepared TCPH was used for photocatalytic degradation of the main organic pollutants, which is methyl orange (MO) dye. The physico-chemical properties of as-prepared samples were characterized by various techniques to observe the transformations after carbonization and the interaction between different composite phases. The existence of Ti+3 and oxygen vacancies at the surface, and a notable increase in surface area, are all demonstrated by TCPH, together with the distinct core-shell structure. These unique properties exhibit excellent photocatalytic performance due to the boosted charge transport and separation. The highest degradation efficiency of methyl orange (MO) was attained in the case of TCPH when compared with titanium-cellulose-phosphorous (TCeP) and titaniumcarbon-phosphorous (TCPN). Accordingly, the highest degradation efficiency was achieved by applying the optimal operational conditions of 1 g/L of TCPH catalyst, 10 mg/L of MO, pH of 7 and the temperature at 25 ± 3 °C after 3 min under LED lamp (365 nm) with light intensity 100 mW/cm2. The degradation mechanism was investigated, and the trapping tests showed the dominance of hydroxyl radicals in the degradation of MO. TCPH showed high stability under a long period of operation in five consecutive cycles, which renders the highly promising on an industrial scale. The fabrication of highly active defective titaniumcarbon-phosphorous opens new opportunities in various areas, including water splitting, and CO2 reduction.
Subject(s)
Carbon , Cellulose , Phosphorus , Titanium , Titanium/chemistry , Carbon/chemistry , Catalysis , Phosphorus/chemistry , Cellulose/chemistry , Azo Compounds/chemistry , Nanocomposites/chemistry , Photochemical ProcessesABSTRACT
An increasing number of studies focus on organic flow batteries (OFBs) as possible substitutes for the vanadium flow battery (VFB), featuring anthraquinone derivatives, such as anthraquinone-2,7-disulfonic acid (2,7-AQDS). VFBs have been postulated as a promising energy storage technology. However, the fluctuating cost of vanadium minerals and risky supply chains have hampered their implementation, while OFBs could be prepared from renewable raw materials. A critical component of flow batteries is the electrode material, which can determine the power density and energy efficiency. Yet, and in contrast to VFBs, studies on electrodes tailored for OFBs are scarce. Hence, in this work, we propose the modification of commercial carbon felts with reduced graphene oxide (rGO) and poly(ethylene glycol) for the 2,7-AQDS redox couple and to preliminarily assess its effects on the efficiency of a 2,7-AQDS/ferrocyanide flow battery. Results are compared to those of a VFB to evaluate if the benefits of the modification are transferable to OFBs. The modification of carbon felts with surface oxygen groups introduced by the presence of rGO enhanced both its hydrophilicity and surface area, favoring the catalytic activity toward VFB and OFB reactions. The results are promising, given the improved behavior of the modified electrodes. Parallels are established between the electrodes of both FB technologies.
ABSTRACT
In this study, the effect of the cell density of monolithic catalysts was investigated and further mathematically modeled on cordierite supports used in CO2 methanation. Commercial cordierite monoliths with 200, 400, and 500 cpsi cell densities were coated by immersion into an ethanolic suspension of Ni/CeO2 active phase. SEM-EDS analysis confirmed that, owing to the low porosity of cordierite (surface area < 1 m2 g-1), the Ni/CeO2 diffusion into the walls was limited, especially in the case of low and intermediate cell density monoliths; thus, active phase was predominantly loaded onto the channels' external surface. Nevertheless, despite the larger exposed surface area in the monolith with high cell density, which would allow for better distribution and accessibility of Ni/CeO2, its higher macro-pore volume resulted in some introduction of the active phase into the walls. As a result, the catalytic evaluation showed that it was more influenced by increments in volumetric flow rates. The low cell density monolith displayed diffusional control at flow rates below 500 mL min-1. In contrast, intermediate and high cell density monoliths presented this behavior up to 300 mL min-1. These findings suggest that the interaction reactants-catalyst is considerably more affected by a forced non-uniform flow when increasing the injection rate. This condition reduced the transport of reactants and products within the catalyst channels and, in turn, increased the minimum temperature required for the reaction. Moreover, a slight diminution of selectivity to CH4 was observed and ascribed to the possible formation of hot spots that activate the reverse water-gas shift reaction. Finally, a mathematical model based on fundamental momentum and mass transfer equations coupled with the kinetics of CO2 methanation was successfully derived and solved to analyze the fluid dynamics of the monolithic support. The results showed a radial profile with maximum fluid velocity located at the center of the channel. A reactive zone close to the inlet was obtained, and maximum methane production (4.5 mol m-3) throughout the monolith was attained at 350 °C. Then, linear streamlines of the chemical species were developed along the channel.
Subject(s)
Carbon Dioxide , Cerium , Nickel , Catalysis , Nickel/chemistry , Carbon Dioxide/chemistry , Cerium/chemistry , Methane , Models, TheoreticalABSTRACT
The electro-Fenton process is based on the generation of hydroxyl radicals (OHâ¢) from hydroxide peroxide (H2O2) generated in situ by an oxygen reduction reaction (ORR). Catalysts based on carbon gels have aroused the interest of researchers as ORR catalysts due to their textural, chemical and even electrical properties. In this work, we synthesized metal-free electrocatalysts based on carbon gels doped with graphene oxide, which were conformed to a working electrode. The catalysts were prepared from organic-gel-based inks using painted (brush) and screen-printed methods free of binders. These new methods of electrode preparation were compared with the conventional pasted method on graphite supports using a binder. All these materials were tested for the electro-Fenton degradation of amoxicillin using a homemade magnetite coated with carbon (Fe3O4/C) as a Fenton catalyst. All catalysts showed very good behavior, but the one prepared by ink painting (brush) was the best one. The degradation of amoxicillin was close to 90% under optimal conditions ([Fe3O4/C] = 100 mg L-1, -0.55 V) with the catalyst prepared using the painted method with a brush, which had 14.59 mA cm-2 as JK and a H2O2 electrogeneration close to 100% at the optimal voltage. These results show that carbon-gel-based electrocatalysts are not only very good at this type of application but can be adhered to graphite free of binders, thus enhancing all their catalytic properties.
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This study investigated the application of adsorption with activated carbons (ACs) and photodegradation to reduce the concentration of triclosan (TCS) in aqueous solutions. Concerning adsorption, ACs (Darco, Norit, and F400) were characterised and batch experiments were performed to elucidate the effect of pH on equilibrium. The results showed that at pH = 7, the maximum adsorption capacity of TCS onto the ACs was 18.5 mg g-1 for Darco, 16.0 mg g-1 for Norit, and 15.5 mg g-1 for F400. The diffusional kinetic model allowed an adequate interpretation of the experimental data. The effective diffusivity varied and increased with the amount of TCS adsorbed, from 1.06 to 1.68 × 10-8 cm2 s-1. In the case of photodegradation, it was possible to ensure that the triclosan molecule was sensitive to UV light of 254 nm because the removal was over 80 % using UV light. The removal of TCS increased in the presence of sulfate radicals. It was possible to identify 2,4-dichlorophenol as one of the photolytic degradation products of triclosan, which does not represent an environmental hazard at low concentrations of triclosan in water. These results confirm that the use of AC Darco, Norit, and F400 and that photodegradation processes with UV light and persulfate radicals are effective in removing TCS from water, reaching concentration levels that do not constitute a risk to human health or environmental hazard. Both methods effectively eliminate pollutants with relatively easy techniques to implement.
Subject(s)
Triclosan , Water Pollutants, Chemical , Humans , Triclosan/chemistry , Charcoal/chemistry , Adsorption , Photolysis , Water , Water Pollutants, Chemical/analysisABSTRACT
Six Functionalized Activated Carbon Cloths (FACCs) were designed to obtain fundamental information for training a Bayesian Regularized Artificial Neural Network (BRANN) capable of predicting adsorption capacity of the FACCs to synthesize tailor-made materials with potential application as dialysis membranes. Characterization studies showed that FACCs have a high surface area (1354-2073 m2 g-1) associated with increased microporosity (W0, average: 0.57 cm3 g-1). Materials are carbonaceous, with a carbon content between 69 and 92%. Chemical treatments modify the pHpzc of materials between 4.1 and 7.8 due to incorporating functional groups on the surface (C=O, -COOH, -OH, -NH, -NH2). Uremic toxins tests showed a high elimination rate of p-cresol (73 mg g-1) and creatinine (90 mg g-1) which is not affected by the matrix (aqueous solution and simulated serum). However, in the case of uric acid, adsorption capacity decreased from 143 mg g-1 to 71 mg g-1, respectively. When comparing the kinetic constants of the adsorption studies in simulated serum versus the studies in aqueous solution, it can be seen that this does not undergo significant changes (0.02 min-1), evidencing the versatility of the material to work in different matrices. The previous studies, in combination with characterization of the materials, allowed to establish the adsorption mechanism. Thus, it permitted to train the BRANN to obtain mathematical models capable to predict the kinetic adsorption of the toxins studied. It is concluded that the predominant adsorption mechanism is due to π-π interactions between the adsorbate unsaturations with the material's pseudo-graphitic planes. Results show that FACCs are promising materials for hemodialysis membranes. Finally, taking into consideration the adsorption capacities and rates, as well as the semiquantitative analysis of the environmental impact associated with the preparation of the adsorbents, the best adsorbent (CC, Eco-Scale = 91.5) was selected. The studies presented show that the material is eco-friendly and highly efficient in the elimination of uremic toxins.
Subject(s)
Uremic Toxins , Water Pollutants, Chemical , Adsorption , Artificial Intelligence , Bayes Theorem , Charcoal , Renal Dialysis/methods , Kinetics , WaterABSTRACT
The Electro-Fenton (EF) process has emerged as a promising technology for pollutant removal. However, the EF process requires the use of two catalysts: one acting as an electrocatalyst for the reduction of oxygen to H2O2 and another Fenton-type catalyst for the generation of ·OH radicals from H2O2. Thus, the search for materials with bifunctionality for both processes is required for a practical and real application of the EF process. Thus, in this work, bifunctional electrocatalysts were obtained via doping carbon microspheres with Eco-graphene, a form of graphene produced using eco-friendly methods. The incorporation of Eco-graphene offers numerous advantages to the catalysts, including enhanced conductivity, leading to more efficient electron transfer during the Electro-Fenton process. Additionally, the synthesis induced structural defects that serve as active sites, promoting the direct production of hydroxyl radicals via a 3-electron pathway. Furthermore, the spherical morphology of carbon xerogels enhances the accessibility of the reagents to the active sites. This combination of factors results in the effective degradation of Tetracycline (TTC) using metal-free catalysts in the Electro-Fenton process, achieving up to an impressive 83% degradation without requiring any other external or additional catalyst.
ABSTRACT
Supercapacitors have the potential to be used in a variety of fields, including electric vehicles, and a lot of research is focused on unique electrode materials to enhance capacitance and stability. Herein, we prepared nickel molybdate/activated carbon (AC) nanocomposites using a facile impregnation method that preserved the carbon surface area. In order to study how the nickel-to-molybdenum ratio affects the efficiency of the electrode, different ratios between Ni-Mo were prepared and tested as supercapacitor electrodes, namely in the following ratios: 1:1, 1:2, 1:3, 1:4, and 1:5. X-ray diffraction, X-ray photoelectron spectroscopy, FESEM, HRTEM, and BET devices were extensively used to analyze the structure of the nanocomposites. The structure of the prepared nickel molybdates was discovered to be 2D hierarchical nanosheets, which functionalized the carbon surface. Among all of the electrodes, the best molar ratio between Ni-Mo was found to be 1:3 NiMo3/AC reaching (541 F·g-1) of specific capacitance at a current density of 1 A·g-1, and 67 W·h·Kg-1 of energy density at a power density of 487 W·Kg-1. Furthermore, after 4000 repetitive cycles at a large current density of 4 A·g-1, an amazing capacitance stability of 97.7% was maintained. This remarkable electrochemical activity for NiMo3/AC could be credited towards its 2D hierarchical structure, which has a huge surface area of 1703 m2·g-1, high pore volume of 0.925 cm3·g-1, and large particle size distribution.
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Sargassum algae has become a major environmental issue due to its abundance in the Pacific Ocean with hundreds of tons reaching the beaches of the Mexican Caribbean every year. This generates large quantities of decomposing organic matter that have a negative impact on the region's economy and ecosystems. Sargassum valorization has turned out to be a fundamental aspect to mitigate its environmental impact. This study proposes the use and application of untreated Sargassum biomass for the decontamination of waters polluted with lead (Pb) and cadmium (Cd) through single and binary adsorption tests. Physicochemical and textural properties examined by SEM, XRD, and FT-IR elucidated that Sargassum biomass is viable to be used as a potential environmental benign adsorbent, exhibiting Cd(II) and Pb(II) adsorption capacities as high as 240 mg g-1 and 350 mg g-1, respectively, outperforming conventionally used adsorbents. This is attributed to its morphology, favorable surface charge distribution, and the presence of -OH and -COH groups. A strong affinity between the biomass and metal pollutants was evidenced by a thermodynamics study, showing a spontaneous and endothermic process. This work sets a practical route for the utilization of the Sargassum biomass, demonstrating its applicability as a potential material for heavy-metal-polluted water remediation, making a substantial contribution to a circular economy system.
Subject(s)
Metals, Heavy , Sargassum , Water Pollutants, Chemical , Cadmium , Biomass , Ecosystem , Spectroscopy, Fourier Transform Infrared , Lead , Metals, Heavy/chemistry , Adsorption , Water Pollutants, Chemical/chemistryABSTRACT
Organic xerogel microspheres (SX) were synthesized by inverse emulsion sol-gel polymerization and carbonized to obtain carbon xerogel spheres (SXCs). The catalyst was K2CO3 or Fe(C2H3O2)2, and the clay sodium sepiolite (SNa) or exfoliated vermiculite (Vexf) was added during the synthesis. Depending on the catalyst and clays, the SXCs were designated SXC-K, SXC-Fe, Vexf-K, Vexf-Fe, SNa-Fe, and SNa-K. At pH = 7 and T = 25 °C, the SXCs' adsorption capacities towards diclofenac (DCF) in water increased as follows: SXC-K < Vexf-Fe < SXC-Fe < SNa-Fe < SNa-K < Vexf-K and this order is associated with the SXCs' surface area and mesopore volume. The Vexf-K displayed the highest capacity for DCF due to its optimal textural and chemical properties, and the DCF maximum uptake was 560 mg/g at pH = 6 and T = 35 °C. The adsorption capacity towards Cd2+ and Pb2+ decreased as SX-K > SX-Fe > SXC-K > SXC-Fe, indicating that the non-carbonized materials (SX) presented higher adsorption capacity than the SXCs because the SXs had a higher acidic site content. Adding SNa or Vexf to SXs enhanced the adsorption capacity towards Cd(II), and SNa-SX-K presented an exceptionally high capacity of 182.7 mg/g. This synergistic effect revealed that the Cd2+ was adsorbed on the SX-K acidic sites and by cation exchange on the SNa.
Subject(s)
Metals, Heavy , Water Pollutants, Chemical , Clay , Diclofenac/chemistry , Microspheres , Cadmium , Metals, Heavy/chemistry , Water , Adsorption , Water Pollutants, Chemical/chemistryABSTRACT
In the present research work, the use of agro-industrial waste such as agave bagasse from the tequila industry was carried out. The agave bagasse was treated to obtain biosorbent and hydrochar materials. Direct Blue 86 was used as an adsorbate model to evaluate the performance of both materials. The adsorption studies showed an adsorption capacity of 6.49 mg g−1 in static and 17.7 mg g−1 in dynamic, associated with a physisorption process between functional groups of the material and the dye. The characterization of the biosorbent showed that the material was mainly composed of macroporous fibers with a surface area <5.0 m2 g−1. Elemental analysis showed a majority composition of C (57.19 wt%) and O (37.49 wt%). FTIR and XPS analyses showed that the material had C-O, C=O, -OH, O-C=O, and -NH2 surface groups. RAMAN and TGA were used to evaluate the composition, being cellulose (40.94%), lignin (20.15%), and hemicellulose (3.35%). Finally, the life-cycle assessment at a laboratory scale showed that the proposed biosorbent presents a 17% reduction in several environmental aspects compared to hydrochar, showing promise as an eco-friendly and highly efficient method for the remediation of water contaminated with dye, as well as being a promising alternative for the responsible management of solid waste generated by the tequila industry.
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This work shows the preparation of carbon nanospheres with a high superficial nitrogen content (7 wt.%), obtained by a simple hydrothermal method, from pyrocatechol and formaldehyde, around which tungsten nanophases have been formed. One of these nanophases is tungsten carbide, whose electro-catalytic behavior in the ORR has been evaluated together with the presence of nitrogen surface groups. Both current and potential kinetic density values improve considerably with the presence of tungsten, despite the significant nitrogen loss detected during the carbonization treatment. However, the synergetic effect that the WC has with other electro-catalytic metals in this reaction cannot be easily evaluated with the nitrogen in these materials, since both contents vary in opposite ways. Nevertheless, all the prepared materials carried out oxygen electro-reduction by a mixed pathway of two and four electrons, showing remarkable electro-catalytic behavior.
ABSTRACT
In this study, two alternative synthesis routes for magnetic adsorbents were evaluated to remove Pb(II) and Cd(II) in an aqueous solution. First, activated carbon was prepared from argan shells (C). One portion was doped with magnetite (Fe3O4+C) and the other with cobalt ferrite (CoFe2O4+C). Characterization studies showed that C has a high surface area (1635 m2 g-1) due to the development of microporosity. For Fe3O4+C the magnetic particles were nano-sized and penetrated the material's texture, saturating the micropores. In contrast, CoFe2O4+C conserves the mesoporosity developed because most of the cobalt ferrite particles adhered to the exposed surface of the material. The adsorption capacity for Pb(II) was 389 mg g-1 (1.88 mmol g-1) and 249 mg g-1 (1.20 mmol g-1); while for Cd(II) was 269 mg g-1 (2.39 mmol g-1) and 264 mg g-1 (2.35 mmol g-1) for the Fe3O4+C and CoFe2O4+C, respectively. The predominant adsorption mechanism is the interaction between -FeOH groups with the cations in the solution, which are the main reason these adsorption capacities remain high in repeated adsorption cycles after regeneration with HNO3. The results obtained are superior to studies previously reported in the literature, making these new materials a promising alternative for large-scale wastewater treatment processes using batch-type reactors.
ABSTRACT
The current study provides a novel insight into the role of synergism of the changes in Mg2+/ Al3+ in the best catalytic activity of indol-3-yl derivatives. A series of Co-Mg-Al layered triple hydroxides (LTHs) catalysts were produced by altering the Al3+/Mg2+ ratio with respect to Co2+. The physicochemical properties of LTHs were well characterized by ICP-AES, XRD, FTIR, FE-SEM, BET, Zeta-sizer, and VSM. The results show that the sample CMA4 (Co2+:Mg2+:Al3+ 2:4:4) is an exception to the physicochemical characteristics of the produced Co-Mg-Al LTHs, which is due to the synergism between the changes in Mg2+ and Al3+. To the best of our knowledge, this is the first study to report the synthesis of indol-3-yl derivatives from indole-3-carbaldehyde using Co-Mg-Al LTHs as highly efficient heterogeneous catalysts, which is an extremely appealing path. The selectivity of the synthesis was studied by condensing various nucleophiles through the one-pot method that established superior reactivity under mild conditions. Notably, the results show that the Co-Mg-Al LTHs system exhibited an extraordinarily catalytic activity, with the highest yield (98%) being obtained under the following optimal conditions: the concentration of Co-Mg-Al LTHs = 5 mol%, 30 min., water/ethanol as solvent. Furthermore, the reusable studies exhibited that the catalysts were found to be stable and reusable for up to six cycles without substantial loss of catalytic activity. Finally, a plausible reaction mechanism of the Co-Mg-Al LTHs system for indol-3-yl derivatives was put forward according to our comprehensive analysis. Our work illuminates a cheap and flexible strategy for the synthesis of indol-3-yl derivatives using Co-Mg-Al LTHs.
ABSTRACT
Introducing new inexpensive materials for supercapacitors application with high energy density and stability, is the current research challenge. In this work, Silver doped carbon xerogels have been synthesized via a simple sol-gel method. The silver doped carbon xerogels are further surface functionalized with different loadings of nickel cobaltite (1 wt.%, 5 wt.%, and 10 wt.%) using a facile impregnation process. The morphology and textural properties of the obtained composites are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and nitrogen physisorption analysis. The silver doped carbon xerogels display a higher surface area and larger mesopore volume compared to the un-doped carbon xerogels and hierarchically porous structure is obtained for all materials. The hybrid composites have been utilized as electrode materials for symmetric supercapacitors in 6 M KOH electrolyte. Among all the hybrid composites, silver doped carbon xerogel functionalized with 1 wt.% nickel cobaltite (NiCo1/Ag-CX) shows the best supercapacitor performance: high specific capacitance (368 F g-1 at 0.1 A g-1), low equivalent series resistance (1.9 Ω), high rate capability (99% capacitance retention after 2000 cycles at 1 A g-1), and high energy and power densities (50 Wh/Kg, 200 W/Kg at 0.1 A g-1). It is found that the specific capacitance does not only depend on surface area, but also on others factors such as particle size, uniform particle distribution, micro-mesoporous structure, which contribute to abundant active sites and fast charge, and ion transfer rates between the electrolyte and the active sites.
ABSTRACT
A series of carbon xerogels doped with cobalt, nickel, and iron have been prepared through the sol-gel method. The doped carbon xerogels were further functionalized with binary and ternary transition metal oxides containing Co, Ni, and Zn oxides by the hydrothermal method. A development in the mesopore volume is achieved for functionalized carbon xerogel doped with iron. However, in the functionalization of carbon xerogel with ternary metal oxides, a reduction in pore diameter and mesopore volume is found. In addition, all functionalized metal oxides/carbon are in the form of 3D nanobundles with different lengths and widths. The prepared samples have been tested as electrocatalysts for oxygen reduction reaction (ORR) in basic medium. All composites showed excellent oxygen reduction reaction activity; the low equivalent series resistance of the Zn-Ni-Co/Co-CX composite was especially remarkable, indicating high electronic conductivity. It has been established that the role of Zn in this type of metal oxides nanobundles-based ORR catalyst is not only positive, but its effect could be enhanced by the presence of Ni.
ABSTRACT
In the present paper, micro-mesoporous Fe-MIL-101/OAC composite using in situ incorporation of Fe-MIL-101 into oxidized activated carbon was synthesized and characterized by XRD, FT-IR, SEM, EDS, and BET techniques. The adsorption performances of toluene onto adsorbents in the gas phase were studied using a laboratory-scale dynamic adsorption system under moist ambience. The toluene adsorption capacity of Fe-MIL-101/OAC composite and Fe-MIL-101 were 127 and 97.6 mg g-1, severally. Results revealed that the larger pores in micro-mesoporous Fe-MIL-101/OAC enhanced the molecular diffusion rate. The findings indicated that micro-mesoporous structures played key roles in the capture of toluene molecules. The initial toluene concentration positively affected on toluene adsorption capacity while temperature and humidity negatively affected on toluene adsorption capacity. The Langmuir model and the pseudo-second-order kinetics model described better adsorption process of Fe-MIL-101/OAC composite. Thermodynamic findings determined that toluene adsorption over Fe-MIL-101/OAC was spontaneous, exothermic physisorption. The regeneration of the composite was still up to 72.6% after six cycles. The micro-mesoporous Fe-MIL-101/OAC composite proposes a promising support for the high toluene removal for future. Graphical abstract.