ABSTRACT
We show that molecular aggregation can strongly influence the nonradiative decay (NRD) lifetime of an electronic excitation. As a demonstrative example, we consider a transition-dipole-dipole-interacting dimer whose monomers have harmonic potential energy surfaces (PESs). Depending on the position of the NRD channel (qnr), we find that the NRD lifetime (τnrdim) can exhibit a completely different dependence on the intermolecular-interaction strength. We observe that (i) for qnr near the Franck-Condon region, τnrdim increases with the interaction strength; (ii) for qnr near the minimum of the monomer excited PES, the intermolecular interaction has little influence on τnrdim; and (iii) for qnr near the classical turning point of the monomer nuclear dynamics, on the other side of the minimum, τnrdim decreases with the interaction strength. Our findings suggest design principles for molecular systems where a specific fluorescence quantum yield is desired.
