ABSTRACT
The copper/nickel-metal on commercial H-Beta zeolite supports was synthesized with different wt % (Ni) of 5, 10, 15, and 20, and was used in the cyclohexene epoxidation process. The synthesized catalyst has been used in a continuous reactor for the cyclohexene epoxidation process, with mild conditions and H2O2 as an oxidant. The catalytic performance was ascertained by adjusting parameters such as the temperature, pressure, WHSV, reaction time, and solvents. The catalytic performance showed the resulting yield in both cyclohexene conversion and selectivity was more than 98.5%. The catalyst's textural attributes, morphology, chemical composition, and stability were determined using FT-IR, XRD, BET, HR-SEM, and TPD. The most active catalyst among those that were synthesized was evaluated, and the reaction parameters were selected to optimize yield and conversion. The H-Beta/Cu/Ni (15%) catalyst has the best conversion (98.5%) and selectivity (100%) for cyclohexene among the catalysts examined. Cu and Ni(15%) metals were successfully added to the H-Beta zeolite, causing little damage to the crystalline structure and resulting in good reusability over five cycles, as well as little loss of catalytic selectivity. Acetonitrile was the solvent that provided the highest conversion and selectivity among the others. These findings show that H-Beta/Cu/Ni bimetallic catalysts have the potential to be effective epoxidation catalysts. Because of their outstanding conversion and selectivity, the continuous reaction technique used in this work makes them appropriate for industrial production-level applications.
ABSTRACT
A wetness impregnation method was used to impregnate the substrate with a substantial quantity of oleic acid together with a metal precursor, leading to significantly dispersed Ni-Fe bimetallic catalysts based on mesoporous SBA-15. Using a wide variety of characterization methods, such as XRD, BET, and TEM Analysis, the physiochemical properties of the catalyst were determined. The addition of the metal does not have any effect on the structural characteristics of the SBA-15 catalyst, as validated by transmission electron microscopy (TEM), which shows that the prepared SBA-15 supported catalyst has a hexagonal mesoporous structure. The catalytic capabilities of the Ni-Fe-SBA-15 catalysts were evaluated in the conversion of BzOH using tert-butyl hydroperoxide (TBHP) as an oxidant and acetonitrile as a solvent. The Ni/Fe-SBA-15 (NFS-15) catalytic composition is the best of the developed catalysts, with a maximum conversion of 98% and a selectivity of 99%. In-depth investigations were conducted into the molar ratio of TBHP to BzOH, the dosage of the catalyst, the reaction rate, temperature, and solvent. The recycling investigations indicate that the synthesized Ni/Fe-SBA-15 (NFS-15) catalyst seems to be more durable up to seven successive cycles.
ABSTRACT
Isomerization is extensively utilized in the petroleum industry, and this study demonstrates an energy-efficient process utilizing an ionic liquid catalyst. 1-Ethyl-3-methylimidazolium triflate [Emim][TFO] as an ionic liquid was immobilized on solid support Fe/SBA-15. Variants of the catalyst were developed with the Fe constant at 5% and different ratios of ionic liquid. In the catalyst Fe/[Emim][TFO]/SBA-15, the metal Fe was loaded via the impregnation method, and subsequently, the ionic liquid variants Fe/[Emim][TFO](10)/SBA-15, Fe/[Emim][TFO](20)/SBA-15, and Fe/[Emim][TFO](30)/SBA-15 were synthesized. The physical properties of the synthesized catalyst were studied using standard characteristic techniques. The process performance was studied for variants of each parameter, which include temperature, hydrogen flow rate, pressure, and weight hourly space velocity. The iso-products of n-heptane and n-octane were obtained with an appreciable conversion of >90% and a selectivity of >95% with the catalyst Fe/[Emim][TFO](20)/SBA-15 among the other synthesized catalysts. The process yielded a high quantum of iso-products with negligible cracked products at a low temperature of 140 °C. The catalyst Fe/[Emim][TFO](20)/SBA-15 at 140 °C delivered the highest yield of iso-alkanes among the three catalysts. Iso-alkanes are instrumental tools for increasing the octane number of a fuel. This study delivers high iso-alkane content fuel, which can provide the best anti knock capability and enhance fuel efficiency for the life of modern high-powered engines. The results demonstrate a process that is energy-efficient, economic, and environmentally friendly.
