Bacteria Contaminants Detected by Organic Inverter-Based Biosensors.

The importance of bacteria detection lies in its role in enabling early intervention, disease prevention, environmental protection, and effective treatment strategies. Advancements in technology continually enhance the speed, accuracy, and sensitivity of detection methods, aiding in addressing these critical issues. This study first reports the fabrication of an inverter constructed using crosslinked-poly(4-vinylphenol) (C-PVP) as the dielectric layer and an organic complementary metal-oxide semiconductor (O-CMOS) based on pentacene and N,N'-ditridecylperylene-3,4,9,10-tetracarboxylic diimide (PTCDI-C13) as a diagnostic biosensor to rapidly detect bacterial concentration. Bacteria including Escherichia coli O157, Staphylococcus aureus ATCC25922, and Enterococcus faecalis SH-1051210 were analysed on the inverters at an ultra-low operating voltage of 2 V. The high density of negative charge on bacteria surfaces strongly modulates the accumulated negative carriers within the inverter channel, resulting in a shift of the switching voltage. The inverter-based bacteria sensor exhibits a linear-like response to bacteria concentrations ranging from 102 to 108 CFU/mL, with a sensitivity above 60%. Compared to other bacterial detectors, the advantage of using an inverter lies in its ability to directly read the switching voltage without requiring an external computing device. This facilitates rapid and accurate bacterial concentration measurement, offering significant ease of use and potential for mass production.

Effects of external light in the magnetic field-modulated photocatalytic reactions in a microfluidic chip reactor.

Photocatalytic reactions and their magnetic-field enhancement present significant potential for practical applications in green chemistry. This work presents the mutual enhancement of plasmonic photocatalytic reaction by externally applied magnetic field and plasmonic enhancement in a micro optofluidic chip reactor. The tiny gold (Au) nanoparticles of only a few atoms fixed on the surface of titanium dioxide (TiO2) nanoparticles lead to mutually boosted enhancement photocatalytic reactions under an external magnetic field and plasmonic effects. The dominant factor of adding green light to the photocatalytic reaction leads to the understanding that it is a plasmonic effect. The positive results of adding ethanol alcohol (EA) in the experiments further present that it is a hot electron dominant path photocatalytic reaction that is positively enhanced by both the external magnetic field and plasmonic effects. This work offers great potential for utilizing magnetic field enhancement in plasmonic photocatalytic reactions.

Special Issue on the State-of-the-Art Optical Properties and Applications of Metallic Nanostructures in Asia.

With developments in nanofabrication technology, the optical properties and applications of metallic nanostructures have attracted increased research interest in recent years [...].

Investigation of low pulse repetition passively mode-locked Nd:YVO4 lasers via multi-pass periodic trajectories in a confocal cavity.

We derive the parametric equations for the geometric rays of a periodic orbit inside a confocal cavity. Based on the derived formula, we demonstrate a passively mode-locked solid-state laser with a low pulse repetition rate to obtain a pulse train traveling along zigzag multi-pass trajectories. We achieve a stable mode-locked pulse train with a pulse repetition rate of 18 MHz by designing the cavity to satisfy the dual-M trajectory. Furthermore, by precisely adjusting cavity mirrors under the same experimental setup, we can reach pulse repetition rates of 12 and 9 MHz for the mode-locked laser. It is believed that the numerical calculation and the developed experiment can provide a straightforward and convenient way to achieve a low pulse repetition rate for passively mode-locked lasers.

Enhancement of luminous efficacy of polymer light-emitting diodes with silver-nanoparticles by oxygen-plasma treatment.

Silver-nanoparticles deposited on indium tin oxide (AgNPs/ITO) with different O2 -plasma treatment times are used as the anode window substrate for polymer light-emitting diodes (PLED). When AgNPs/ITO with an O2 -plasma treatment time of 10 min is used for PLED, a maximum current efficiency of 3.33 cd/A is realized, which is notably higher than that of a reference PLED (1.00 cd/A). Compared to those of the reference PLED, the mean current efficiency and electroluminescence intensity of the optimal PLED are enhanced by 3.24 times and 480%, respectively. O2 -plasma treatment is an easy method for optimizing the localized surface plasmon resonance effect of metal nanoparticles, exhibiting advantages of scalable mass production and high suitability for applications in related optoelectronic components.

Breaking the Symmetry of a Metal-Insulator-Metal-Based Resonator for Sensing Applications.

This article designed a novel multi-mode plasmonic sensor based on a metal-insulator-metal waveguide side-coupled to a circular-shaped resonator containing an air path in the resonator. The electromagnet field distributions and transmittance spectra are investigated using finite element method-based simulations. Simulation results show that an air path in the resonator's core would impact the transmittance spectrum of SPPs. Besides, the air path is crucial in offering efficient coupling and generating multiple plasmon modes in the sensor system. The proposed structure has the advantage of multi-channel, and its sensitivity, figure of merit, and dipping strength can reach 2800 nm/RIU, 333.3 1/RIU, and 86.97%, respectively. The achieved plasmonic sensor can also apply for lab-on-chip in biochemical analysis for detecting the existence or nonappearance of diabetes through the human glucose concentration in urine.

Enhanced photoluminescence and shortened lifetime of DCJTB by photoinduced metal deposition on a ferroelectric lithography substrate.

The photodeposition of metallic nanostructures onto ferroelectric surfaces could enable new applications based on the assembly of molecules and patterning local surface reactivity by enhancing surface field intensity. DCJTB (4-(dicyanomethylene)-2-t-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran) is an excellent fluorescent dye and dopant material with a high quantum efficiency used for OLED displays on the market. However, how to raise the photoluminescence (PL) and reduce the lifetime of DCJTB in a substrate remain extraordinary challenges for its application. Here, we demonstrate a tunable ferroelectric lithography plasmon-enhanced substrate to generate photo-reduced silver nanoparticles (AgNPs) and achieve enhanced PL with a shortened lifetime depending on the substrate's annealing time. The enhanced PL with shortened lifetimes can attribute to the localized electromagnetic (EM) wave produced by the nanotextured AgNPs layers' surface and gap plasmon resonances. The simulation is based on the three-dimensional finite element method to explain the mechanism of experimental results. Since the absorption increases, the remarkable enhanced PL of DCJTB can attain in the fabricated periodically proton exchanged (PPE) lithium niobate (LiNbO3) substrate. Furthermore, the proposed fabrication method demonstrates to help tune the surface EM wave distribution in the substrate, which can simultaneously achieve the significantly shortened lifetime and high PL intensity of DCJTB in the substrate. Compared with the un-annealed substrate, the PL intensity of DCJTB in the assembly metallic nanostructures is enhanced 13.70 times, and the PL's lifetime is reduced by 12.50%, respectively. Thus, the fabricated substrate can be a promising candidate, verifying chemically patterned ferroelectrics' satisfaction as a PL-active substrate.

Theoretical Study of CO Adsorption Interactions with Cr-Doped Tungsten Oxide/Graphene Composites for Gas Sensor Application.

The present study explores the CO adsorption properties with graphene, tungsten oxide/graphene composite, and Cr-doped tungsten oxide/graphene composite using density functional theory (DFT) calculations. The results of the study reveal the Cr-doped tungsten oxide/graphene composites, g-CrW n-1O3n (n = 2 to 4), to have a lowered highest occupied molecular orbital-lowest unoccupied molecular orbital (HOMO-LUMO) energy gap, high surface reactivity, and a strong cluster-graphene binding energy, hence exhibiting a strong adsorption interaction with CO. The CO adsorption interaction shows physisorption properties by having a greater tendency for Mulliken and natural bond orbital (NBO) charge transfer supported by a strong physisorption interaction toward the g-CrW n-1O3n (n = 2 to 4) composite with HOMO-LUMO energy gaps of -0.638, -0.486, and -0.327 eV, respectively. The calculated photoelectron spectroscopy (PES) and infrared spectra combined with the visualized electrostatic potential and contour line confirm the population density of the physisorption interaction. The calculated results show that the g-CrW n-1O3n composite achieves a greater sensing ability by possessing the highest sensitivity, adsorption, and desorption characteristics for n = 2 (g-CrWO6 composite). In conclusion, Cr-doped tungsten oxide/graphene has high sensitivity toward CO gas.

Biosensing on a Plasmonic Dual-Band Perfect Absorber Using Intersection Nanostructure.

Optical absorbers with multiple absorption channels are required in integrated optical circuits and have always been a challenge in visible and near-infrared (NIR) region. This paper proposes a perfect plasmonic absorber (PPA) that consists of a closed loop and a linked intersection in a unit cell for sensitive biosensing applications. We elucidate the physical nature of finite element method simulations through the absorptance spectrum, electric field intensity, magnetic flux density, and surface charge distribution. The designed PPA achieves triple channels, and the recorded dual-band absorptance reaches 99.64 and 99.00% nm, respectively. Besides, the sensitivity can get 1000.00 and 650 nm/RIU for mode 1 and mode 2, respectively. Our design has a strong electric and magnetic field coupling arising from the mutual inductance and the capacitive coupling in the proposed plasmonic system. Therefore, the designed structure can serve as a promising option for biosensors and other optical devices. Here, we illustrated two examples, i.e., detecting cancerous cells and diabetes cells.

Ultrahigh Sensitivity of a Plasmonic Pressure Sensor with a Compact Size.

This study proposes a compact plasmonic metal-insulator-metal pressure sensor comprising a bus waveguide and a resonator, including one horizontal slot and several stubs. We calculate the transmittance spectrum and the electromagnetic field distribution using the finite element method. When the resonator's top layer undergoes pressure, the resonance wavelength redshifts with increasing deformation, and their relation is nearly linear. The designed pressure sensor possesses the merits of ultrahigh sensitivity, multiple modes, and a simple structure. The maximum sensitivity and resonance wavelength shift can achieve 592.44 nm/MPa and 364 nm, respectively, which are the highest values to our knowledge. The obtained sensitivity shows 23.32 times compared to the highest one reported in the literature. The modeled design paves a promising path for applications in the nanophotonic field.

A multichannel color filter with the functions of optical sensor and switch.

This paper reports a multichannel color filter with the functions of optical sensor and switch. The proposed structure comprises a metal-insulator-metal (MIM) bus waveguide side-couples to six circular cavities with different sizes for filtering ultra-violet and visible lights into individual colors in the wavelength range of 350-700 nm. We used the finite element method to analyze the electromagnetic field distributions and transmittance properties by varying the structural parameters in detail. The designed plasmonic filter takes advantage of filtering out different colors since the light-matter resonance and interference between the surface plasmon polaritons (SPPs) modes within the six cavities. Results show that the designed structure can preferentially select the desired colors and confine the SPPS modes in one of the cavities. This designed structure can filter eleven color channels with a small full width at half maximum (FWHM) ~ 2 nm. Furthermore, the maximum values of sensitivity, figure of merit, quality factor, dipping strength, and extinction ratio can achieve of 700 nm/RIU, 350 1/RIU, 349.0, 65.04%, and 174.50 dB, respectively, revealing the excellent functions of sensor performance and optical switch, and offering a chance for designing a beneficial nanophotonic device.

Significantly enhanced coupling effect and gap plasmon resonance in a MIM-cavity based sensing structure.

Herein, we design a high sensitivity with a multi-mode plasmonic sensor based on the square ring-shaped resonators containing silver nanorods together with a metal-insulator-metal bus waveguide. The finite element method can analyze the structure's transmittance properties and electromagnetic field distributions in detail. Results show that the coupling effect between the bus waveguide and the side-coupled resonator can enhance by generating gap plasmon resonance among the silver nanorods, increasing the cavity plasmon mode in the resonator. The suggested structure obtained a relatively high sensitivity and acceptable figure of merit and quality factor of about 2473 nm/RIU (refractive index unit), 34.18 1/RIU, and 56.35, respectively. Thus, the plasmonic sensor is ideal for lab-on-chip in gas and biochemical analysis and can significantly enhance the sensitivity by 177% compared to the regular one. Furthermore, the designed structure can apply in nanophotonic devices, and the range of the detected refractive index is suitable for gases and fluids (e.g., gas, isopropanol, optical oil, and glucose solution).

Improved Refractive Index-Sensing Performance of Multimode Fano-Resonance-Based Metal-Insulator-Metal Nanostructures.

This work proposed a multiple mode Fano resonance-based refractive index sensor with high sensitivity that is a rarely investigated structure. The designed device consists of a metal-insulator-metal (MIM) waveguide with two rectangular stubs side-coupled with an elliptical resonator embedded with an air path in the resonator and several metal defects set in the bus waveguide. We systematically studied three types of sensor structures employing the finite element method. Results show that the surface plasmon mode's splitting is affected by the geometry of the sensor. We found that the transmittance dips and peaks can dramatically change by adding the dual air stubs, and the light-matter interaction can effectively enhance by embedding an air path in the resonator and the metal defects in the bus waveguide. The double air stubs and an air path contribute to the cavity plasmon resonance, and the metal defects facilitate the gap plasmon resonance in the proposed plasmonic sensor, resulting in remarkable characteristics compared with those of plasmonic sensors. The high sensitivity of 2600 nm/RIU and 1200 nm/RIU can simultaneously achieve in mode 1 and mode 2 of the proposed type 3 structure, which considerably raises the sensitivity by 216.67% for mode 1 and 133.33% for mode 2 compared to its regular counterpart, i.e., type 2 structure. The designed sensing structure can detect the material's refractive index in a wide range of gas, liquids, and biomaterials (e.g., hemoglobin concentration).

Ultrawide Bandgap and High Sensitivity of a Plasmonic Metal-Insulator-Metal Waveguide Filter with Cavity and Baffles.

A plasmonic metal-insulator-metal waveguide filter consisting of one rectangular cavity and three silver baffles is numerically investigated using the finite element method and theoretically described by the cavity resonance mode theory. The proposed structure shows a simple shape with a small number of structural parameters that can function as a plasmonic sensor with a filter property, high sensitivity and figure of merit, and wide bandgap. Simulation results demonstrate that a cavity with three silver baffles could significantly affect the resonance condition and remarkably enhance the sensor performance compared to its counterpart without baffles. The calculated sensitivity (S) and figure of merit (FOM) in the first mode can reach 3300.00 nm/RIU and 170.00 RIU-1. Besides, S and FOM values can simultaneously get above 2000.00 nm/RIU and 110.00 RIU-1 in the first and second modes by varying a broad range of the structural parameters, which are not attainable in the reported literature. The proposed structure can realize multiple modes operating in a wide wavelength range, which may have potential applications in the on-chip plasmonic sensor, filter, and other optical integrated circuits.

Highly Sensitive and Tunable Plasmonic Sensor Based on a Nanoring Resonator with Silver Nanorods.

We numerically and theoretically investigate a highly sensitive and tunable plasmonic refractive index sensor that is composed of a metal-insulator-metal waveguide with a side-coupled nanoring, containing silver nanorods using the finite element method. Results reveal that the presence of silver nanorods in the nanoring has a significant impact on sensitivity and tunability performance. It gives a flexible way to tune the system response in the proposed structure. Our designed sensor has a sensitivity of 2080 nm/RIU (RIU is the refractive index unit) along with a figure of merit and a quality factor of 29.92 and 29.67, respectively. The adequate refractive index sensitivity can increase by adding the silver nanorods in a nanoring, which can induce new surface plasmon polaritons (SPPs) modes that cannot be found by a regular nanoring. For a practical application, a valid introduction of silver nanorods in the nanoring can dramatically reduce the dimension of the proposed structure without sacrificing performance.

Reusable TiN Substrate for Surface Plasmon Resonance Heterodyne Phase Interrogation Sensor.

A TiN-based substrate with high reusability presented high-sensitivity refractive index measurements in a home-built surface plasmon resonance (SPR) heterodyne phase interrogation system. TiN layers with and without additional inclined-deposited TiN (i-TiN) layers on glass substrates reached high bulk charge carrier densities of 1.28 × 1022 and 1.91 × 1022 cm-3, respectively. The additional 1.4 nm i-TiN layer of the nanorod array presented a detection limit of 6.1 × 10-7 RIU and was higher than that of the 46 nm TiN layer at 1.2 × 10-6 RIU when measuring the refractive index of a glucose solution. Furthermore, the long-term durability of the TiN-based substrate demonstrated by multiple processing experiments presented a high potential for various practical sensing applications.

Perfect Dual-Band Absorber Based on Plasmonic Effect with the Cross-Hair/Nanorod Combination.

Plasmonic effect using a cross-hair can convey strongly localized surface plasmon modes among the separated composite nanostructures. Compared to its counterpart without the cross-hair, this characteristic has the remarkable merit of enhancing absorptance at resonance and can make the structure carry out a dual-band plasmonic perfect absorber (PPA). In this paper, we propose and design a novel dual-band PPA with a gathering of four metal-shell nanorods using a cross-hair operating at visible and near-infrared regions. Two absorptance peaks at 1050 nm and 750 nm with maximal absorptance of 99.59% and 99.89% for modes 1 and 2, respectively, are detected. High sensitivity of 1200 nm refractive unit (1/RIU), figure of merit of 26.67 and Q factor of 23.33 are acquired, which are very remarkable compared with the other PPAs. In addition, the absorptance in mode 1 is about nine times compared to its counterpart without the cross-hair. The proposed structure gives a novel inspiration for the design of a tunable dual-band PPA, which can be exploited for plasmonic sensor and other nanophotonic devices.

Fabrication and Characterization of a Metallic-Dielectric Nanorod Array by Nanosphere Lithography for Plasmonic Sensing Application.

In this paper, a periodic metallic-dielectric nanorod array which consists of Si nanorods coated with 30 nm Ag thin film set in a hexagonal configuration is fabricated and characterized. The fabrication procedure is performed by using nanosphere lithography with reactive ion etching, followed by Ag thin-film deposition. The mechanism of the surface and gap plasmon modes supported by the fabricated structure is numerically demonstrated by the three-dimensional finite element method. The measured and simulated absorptance spectra are observed to have a same trend and a qualitative fit. Our fabricated plasmonic sensor shows an average sensitivity of 340.0 nm/RIU when applied to a refractive index sensor ranging from 1.0 to 1.6. The proposed substrates provide a practical plasmonic nanorod-based sensing platform, and the fabrication methods used are technically effective and low-cost.

Magnetic Field-Enhancing Photocatalytic Reaction in Micro Optofluidic Chip Reactor.

A small external magnetic field (100-1000 Oe) was demonstrated to enhance the photocatalytic degradation of methyl orange (MO) using TiO2 NPs in micro optofluidic chip (MOFC) reactors. The rectangular shape of the fluidic channel and TiO2 deposited only onto the lower glass substrate leads to a selectively enhancing photocatalytic reactions by magnetic field in specific directions. Utilizing ethyl alcohol as a scavenger presented the difference between generated hot-hole (hVB+) and hot-electron (eCB-) pathways of photocatalytic reactions. Effects of dissolved oxygen (DO) and hydroxyl ions (OH-) are all demonstrated in a magnetic field-enhancing photocatalytic reaction. The experimental results demonstrate great potential for practical applications utilizing low-price fixed magnets in the field of green chemistry.

Ultra-High Refractive Index Sensing Structure Based on a Metal-Insulator-Metal Waveguide-Coupled T-Shape Cavity with Metal Nanorod Defects.

An ultra-high plasmonic refractive index sensing structure composed of a metal-insulator-metal (MIM) waveguide coupled to a T-shape cavity and several metal nanorod defects is proposed and investigated by using finite element method. The designed plasmonic MIM waveguide can constitute a cavity resonance zone and the metal nanorod defects can effectively trap the light in the T-shape cavity. The results reveal that both the size of defects in wider rectangular cavity and the length of narrower rectangular cavity are primary factors increasing the sensitivity performance. The sensitivity can achieve as high as 8280 nm/RIU (RIU denotes the refractive index unit), which is the highest sensitivity reported in plasmonic MIM waveguide-based sensors to our knowledge. In addition, the proposed structure can also serve as a temperature sensor with temperature sensitivity as high as 3.30 nm/°C. The designed structure with simplicity and ease of fabrication can be applied in sensitivity nanometer scale refractive index sensor and may potentially be used in optical on-chip nanosensor.