Creation of a boron carbide-based Ti3AlBC (312) MAX phase: a route to novel MXenes for energy storage.

A novel boron carbide (B4C)-based Ti3AlBC (312) MAX phase was predicted for the first time via density functional theory (DFT). The stability of the MAX phase was confirmed by mechanical and thermal property analyses. The computational details revealed the attractive properties of Ti3AlBC, indicating its potential as an advanced material with improved characteristics. Its thermodynamic properties are reported as a function of temperature, indicating its potential for energy storage applications.

Green tea and tulsi extracts as efficient green corrosion inhibitor for aluminum alloy in alkaline medium.

Corrosion is a major issue in every industrial system. As a result of its widespread application, aluminum suffers enormous annual losses due to corrosion. Scientists are continually on the lookout for effective anti-corrosion strategies. Corrosion may be reduced in a number of ways, but many of them are harmful to the environment, so it's important to find a green alternative. Corrosion inhibitors in aluminum alloys can be found in green tea and tulsi extract. In this research, we found that aluminum alloy 1100 (Al-1100) ina 10% NaOH solution was inhibited by both green tea and Tulsi extract. Samples of AL alloy are submerged in 10% NaOH solutions with and without an inhibitor for a total of 25 days. The weight-loss technique is used to determine the effectiveness of an inhibitor, with tulsi extract far outperforming green tea with the best efficiency of 83.93% compared to the greatest efficiency of 14.29% for green tea. After being submerged in an inhibitory solution, an aluminum alloy surface developed an adsorbed protective layer, which is chemical adsorption, as seen by FTIR (Fourier-Transform Infrared Spectroscopy) spectroscopy. Green inhibitors those are present on the surface of the aluminum alloys are less corrosive confirmed by the SEM (Scanning Electron Microscopy) analysis. The chemical particles were found to be present as a coating over AL alloy surfaces, as determined by EDS (Energy Dispersion Spectroscopy) testing. In a10% NaOH solution, Al-1100 is inhibited more effectively by tulsi extracts than by green tea extracts.

Advances of plant and biomass extracted zirconium nanoparticles in dental implant application.

Nanoparticles are minimal materials with unique physicochemical features that set them apart from bulk materials of the same composition. These properties make nanoparticles highly desirable for use in commercial and medical research. The primary intention for the development of nanotechnology is to achieve overarching social objectives like bettering our understanding of nature, boosting productivity, improving healthcare, and extending the bounds of sustainable development and human potential. Keeping this as a motivation, Zirconia nanoparticles are becoming the preferred nanostructure for modern biomedical applications. This nanotechnology is exceptionally versatile and has several potential uses in dental research. This review paper concentrated on the various benefits of zirconium nanoparticles in dentistry and how they provide superior strength and flexibility compared to their counterparts. Moreover, the popularity of zirconium nanoparticles is also growing as it has strong biocompatibility potency. Zirconium nanoparticles can be used to develop or address the major difficulty in dentistry. Therefore, this review paper aims to provide a summary of the fundamental research and applications of zirconium nanoparticles in dental implants.

Development and characterization of natural sourced bioplastic for food packaging applications.

Climate change and increased pollution caused by traditional petrochemical plastics made the biodegradable environment-friendly plastic (bioplastic) research more popular. Bioplastics can be manufactured from natural renewable ingredients and used as food packaging material without harming the environment. This research work focuses on developing bioplastic films from natural ingredients such as starch of tamarind seeds, and berry seeds, with licorice root. Attention has been paid to characterizing the material by biodegradability, mechanical testing, Fourier Transformed Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Thermogravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC), antimicrobial analysis tests. Phenolic compounds present in the berry seeds starch increased the soil biodegradability as well as the mechanical and thermal properties of the bioplastic films. The FTIR spectra confirmed the presence of various bio-molecules. Improved antimicrobial performance is also obtained. The results of this research confirm that the prepared bioplastic samples can be used in packaging applications.

Green synthesis and characterization of zirconium nanoparticlefor dental implant applications.

Green synthesis is a promising and cost-effective technique to synthesize nanoparticles from plant extract. The present study shows the green synthesis of zirconium nanoparticles using the extract of ginger, garlic, and zirconium nitride. The obtained nanoparticles were studied for potential dental implant applications. The synthesized nanoparticles were characterized by Fourier Transform Infrared Spectroscopy (FTIR), Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-Ray Spectroscopy (EDX), X-Ray diffraction analysis (XRD), and antibacterial analysis. FTIR analysis confirmed the presence of various organic compounds in the synthesized nanoparticles. The synthesized nanoparticles were spherical, triangular, and irregular, with varying sizes confirmed by FESEM analysis. The nanoparticles synthesized from the combination of garlic and ginger, and zirconium exhibited potent antibacterial activity against S. aureus. Anti-biofilm, anti-microbial activity, biointegration formation, and cell mechanism survival are also mentioned. Thus, the synthesized nanoparticles can be a good candidate for a dental implant because of their excellent antimicrobial properties.

Synthesis and Characterization of Eco-Friendly Bio-Composite from Fenugreek as a Natural Resource.

The present study show the usability of starch (tamarind) based-bio-composite film reinforced by fenugreek by various percentages to replace the traditional petrochemical plastics. The prepared bio-composite films were systematically characterized using the universal testing machine (UTM), soil degradation, scanning electron microscope (SEM), X-ray diffraction (XRD), thermogravimetric analyzer (TGA), and antibacterial tests. The experiments showed that a lower percentage of fenugreek improves biodegradation and mechanical strength. More than 60% of biodegradation occurred in only 30 days. Almost 3 N/mm2 tensile strength and 6.5% tensile strain were obtained. The presence of micropores confirmed by SEM images may accelerate the biodegradation process. Antibacterial activity was observed with two samples of synthesized bio-composite, due to photoactive compounds confirmed by FTIR spectra. The glass transition temperature was shown to be higher than the room temperature, with the help of thermal analysis. The prepared bio-composite containing 5% and 10% fenugreek showed antibacterial activities.

Antibacterial multicomponent electrospun nanofibrous mat through the synergistic effect of biopolymers.

The endeavor was to adopt a facile bi-layered approach to fabricate a novel PVA-chitosan-collagen-licorice nanofibrous mat (PCCLNM) with maintaining the spinning parameters and conditions to assess the synergistic antibacterial action of two biopolymers and having properties for repairing tissues. Bonding behavior, morphological orientation, antibacterial activity, and moisture management features of the electrospun nanofibrous mat were investigated using various characterization techniques. The FTIR analysis of the manufactured nanofibrous mat revealed characteristic peaks of licorice, chitosan, collagen, and PVA polymer, confirming the presence of all polymers in the sample. Additionally, a scanning electron microscopy (SEM) image attributes the development of nanofibers with an average diameter for top and bottom sides were 219 and 188 nm respectively. Furthermore, moisture management tests (MMT) confirm PCCLNM's slow absorption and drying capabilities. Apart from that, a disk diffusion method was used to investigate antibacterial activity against the bacteria Staphylococcus aureus (S. aureus), which revealed a strong presence of antibacterial activity with a 20 mm zone of inhibition due to the chemical constituents of licorice and chitosan compound. The developed bio-nanocomposite could have a potential application as wound healing material.

Development of SiC-TiO2-Graphene neem extracted antimicrobial nano membrane for enhancement of multiphysical properties and future prospect in dental implant applications.

This paper presents the coating technology on Nano membrane using SiC-TiO2-Graphene with varying percentages of Azadirachta indica (Neem) extract with an objective to develop new coating materials. The nanomembranes have been synthesized by electrospinning machine over aluminum foil paper using the raw materials PVA grain, SiC, TiO2, Graphene, and neem. The nanomembranes have been characterized by SEM, XRD, FTIR, Surface Roughness, antibacterial, and Cytotoxicity test. FTIR analysis established the presence of PVA and neem indicating the formation of different organic compounds. It also confirmed that no chemical reaction occurred during the synthesis process. The membrane's roughness analysis obtained average roughness values from 1.15 to 3.84. The formation of homogeneous and smooth membranes with the formation of micropores was confirmed by SEM analysis. Miller Indices identified different types of crystal structures in XRD analysis. Antibacterial activity increased with the increase of the percentage of neem confirmed by the antibacterial test. No toxic effects were observed from the membrane during the cytotoxicity test. The obtained data confirmed that the synthesized nanomembrane could be used in different biomedical applications.

Synthesis and characterization of plant extracted silver nanoparticles and advances in dental implant applications.

Dental implantology has always emphasized silver nanoparticles (AgNPs) for various applications due to their biocompatibility, antibacterial activity, and increased surface volume ratio offered by these particles. It is utilized to a large extent in the dental implant industry as a surface modification, biocompatible constituent and composite material. AgNPs may be produced inexpensively, sustainably, and environmentally responsibly by utilizing technologies that extract the plant material. The phytochemical components that are contained in plants make them a better, non-toxic, and more cost-effective alternative to both physical and chemical approaches. Because the size and shape of AgNP depend on their synthesis method and technique, and because the efficacy and toxicity of AgNP depend on both size and shape, synthesis methods and techniques have recently become the focus of a significant amount of research attention. In this review, we discussed Plant Extracted Ag-NP's whose sizes range up to 100nm. This review also focuses on recent research advancements in the Plant Extracted synthesis of AgNPs, as well as their characterization methodologies, current obstacles, future possibilities, and applications in dental implantology.

Effects of Self-Lubricant Coating and Motion on Reduction of Friction and Wear of Mild Steel and Data Analysis from Machine Learning Approach.

The applications of coated mild steels are gaining significant attention in versatile industrial areas because of their better mechanical properties, anticorrosive behavior, and reproducibility. The life period of this steel reduces significantly under relative motion in the presence of friction, which is associated with the loss of billion-dollar every year in industry. Productivity is hampered, and economic growth is declined. Several pieces of research have been conducted throughout the industries to seeking the processes of frictional reduction. This study is attributed to the tribological behavior of electroplated mild steel under various operating parameters. The efficiency of commercial lubricant and self-lubrication characteristics of coated layer plays a significant role in the reduction of friction. The reciprocating and simultaneous motion in relation to pin as well as disc are considered during experimentation. The lubricating effects in conjunction with motions are responsible for compensating the friction and wear at the desired level. During frictional tests, the sliding velocity and loads are changed differently. The changes in roughness after frictional tests are observed. The coated and rubbing surfaces are characterized using SEM (Scanning Electron Microscopy) analysis. The coating characteristics are analyzed by EDS (Energy Disperse Spectroscopy), FTIR (Fourier-transform Infrared Spectroscopy), and XRD (X-ray diffraction analysis) methods. The lubrication, reciprocating motion, and low velocity result in low friction and wear. The larger the imposed loads, the smaller the frictional force, and the larger the wear rate. The machine learning (ML) concept is incorporated in this study to identify the patterns of datasets spontaneously and generate a prediction model for forecasting the data, which are out of the experimental range. It can be desired that the outcomes of this research will contribute to the improvement in versatile engineering fields, such as automotive, robotics, and complex motion-based mechanisms where multidimensional motion cannot be ignored.

3D-Printed Objects for Multipurpose Applications.

3D printing is a popular nonconventional manufacturing technique used to print 3D objects by using conventional and nonconventional materials. The application and uses of 3D printing are rapidly increasing in each dimension of the engineering and medical sectors. This article overviews the multipurpose applications of 3D printing based on current research. In the beginning, various popular methods including fused deposition method, stereolithography 3D printing method, powder bed fusion method, digital light processing method, and metal transfer dynamic method used in 3D printing are discussed. Popular materials utilized randomly in printing techniques such as hydrogel, ABS, steel, silver, and epoxy are overviewed. Engineering applications under the current development of the printing technique which include electrode, 4D printing technique, twisting object, photosensitive polymer, and engines are focused. Printing of medical equipment including artificial tissues, scaffolds, bioprinted model, prostheses, surgical instruments, COVID-19, skull, and heart is of major focus. Characterization techniques of the printed 3D products are mentioned. In addition, potential challenges and future prospects are evaluated based on the current scenario. This review article will work as a masterpiece for the researchers interested to work in this field.

Multiphysical analysis of nanoparticles and their effects on plants.

Nanoparticles are the magic bullets and at the leading edge in the field of nanotechnology, and their unique properties make these materials indispensable and superior in many areas, including the electronic field. Extensive applications of nanomaterials are incontrovertibly entering our living system. The increasing use of nanomaterials into the ecosystem is one of the crucial environmental factors that human being is facing. Nanomaterials raise noticeable toxicological concerns; particularly their accumulation in plants and the resultant toxicity may affect the food chain. Here, we analyzed the characterization of nanomaterials, such as graphene, Al2 O3 , TiO2 , and semi-insulating or conducting nanoparticles. Quantitative evaluation of the nanomaterials was conducted and their commercialization aspects were discussed. Various characterization techniques, scanning electron microscopy, X-ray diffraction, and ultraviolet rays were utilized to identify the morphology, phase, absorbance, and crystallinity. In addition, we analyzed the effects of nanomaterials on plants. The toxicity of nanoparticles has severe effects on loss of morphology of the plants. Potential mechanisms including physical and physiological effects were analyzed. In future studies, it is indispensable to assess widely accepted toxicity evaluation for safe production and use of nanomaterials.

Prospect of biobased antiviral face mask to limit the coronavirus outbreak.

The rapid spread of COVID-19 has led to nationwide lockdowns in many countries. The COVID-19 pandemic has played serious havoc on economic activities throughout the world. Researchers are immensely curious about how to give the best protection to people before a vaccine becomes available. The coronavirus spreads principally through saliva droplets. Thus, it would be a great opportunity if the virus spread could be controlled at an early stage. The face mask can limit virus spread from both inside and outside the mask. This is the first study that has endeavoured to explore the design and fabrication of an antiviral face mask using licorice root extract, which has antimicrobial properties due to glycyrrhetinic acid (GA) and glycyrrhizin (GL). An electrospinning process was utilized to fabricate nanofibrous membrane and virus deactivation mechanisms discussed. The nanofiber mask material was characterized by SEM and airflow rate testing. SEM results indicated that the nanofibers from electrospinning are about 15-30 µm in diameter with random porosity and orientation which have the potential to capture and kill the virus. Theoretical estimation signifies that an 85 L/min rate of airflow through the face mask is possible which ensures good breathability over an extensive range of pressure drops and pore sizes. Finally, it can be concluded that licorice root membrane may be used to produce a biobased face mask to control COVID-19 spread.

Immune response in COVID-19: A review.

The immune system protects against viruses and diseases and produces antibodies to kill pathogens. This review presents a brief overview of the immune system regarding its protection of the human body from COVID-19; illustrates the process of the immune system, how it works, and its mechanism to fight virus; and presents information on the most recent COVID-19 treatments and experimental data. Various types of potential challenges for the immunes system are also discussed. At the end of the article, foods to consume and avoid are suggested, and physical exercise is encouraged. This article can be used worldwide as a state of the art in this critical moment for promising alternative solutions related to surviving the coronavirus.

Fretting & friction induced fatigue failure: damage criterion of polytetrafluoroethylene.

Biomedical implants like the hip joint with cup work under continuous friction and wear phenomena where soft materials are suitable for the low coefficient of friction. As continuous, joints go under dynamic fatigue that should be accelerated by the fretting action generated from contact pairs and the inclination angle of the femur. In this research, the fatigue behavior of PTFE has been studied and compared under friction along with fretting action. A FE based Numerical model justified the experimental results. It showed that fretting and friction influence the fatigue life of PTFE by various angles. Fretting pressure optimization was identified as the determinant factor, while the loading point ratio was remarked as an effective parameter for both fretting and friction fatigue. Penetration depths proportionality to corresponding stress observed the effect of fretting fatigue where friction acts in different degrees depending on the geometry (collar/notch)-loading (friction) position. The fractographical demonstration revealed a relation between crack orientation and fretting action. Predefined loading action on test samples justified the singularity of fretting-friction fatigue characteristics on the damage mechanism of PTFE.

Characterization and performance analysis of composite bioplastics synthesized using titanium dioxide nanoparticles with corn starch.

Plastic is an amazing material, and wonderful invention, it has changed the world. Plastic is used everywhere and every day across the globe. But despite its varied uses, its disposal has threatened the environment. Biodegradable plastics can meet these needs and can easily be disposed to the environment. This work focuses on the characterization and performance analysis of starch bioplastics and composite bioplastic to reduce the plastic pollution by its various uses. TGA, DSC, SEM, FTIR, and surface roughness analyses were used to characterize, the mechanical properties, thermal properties and the morphology of the starch bioplastics and composite bioplastic. Starch bioplastics were fabricated using starch vinegar and glycerol. Composite bioplastics ware fabricated using starch, vinegar, glycerol and titanium dioxide. The addition of titanium dioxide improved the tensile strength of the bioplastics from 3.55 to 3.95 MPa and decreased elongation from 88% to 62%. According to Differential Scanning Calorimetry (DSC) Test, the melting point (Tm) and Glass Transition Temperature (Tg) significantly affected by the presence of titanium dioxide (TiO2). The degree of nano-composite crystallinity was formed by the strong interfacial interaction between the titanium dioxide nanoparticles and the amorphous region of the chain. The decomposition temperature of starch bioplastic was increased by mixing with titanium dioxide nanoparticles. The results gained from SEM showed that better compatible morphologies in composite bioplastic compared to starch bioplastic for its fewer voids, holes, and crack. The functional group O-H, C-H, C=O, and C-O indicate the formation of starch bioplastics and composite bioplastics has already occurred which was confirmed by FTIR spectroscopy. The result is also verified with the available results of other researchers. Therefore, composite bioplastic is a modified elevation of a starch bioplastic with a modified upgrade feature. It can be an alternative to existing conventional plastic, especially packaging applications.