Assessing Radiation Hardness of Silicon Photonic Sensors.

In recent years, silicon photonic platforms have undergone rapid maturation enabling not only optical communication but complex scientific experiments ranging from sensors applications to fundamental physics investigations. There is considerable interest in deploying photonics-based communication and science instruments in harsh environments such as outer space, where radiation damage is a significant concern. In this study, we have examined the impact of cobalt-60 γ-ray radiation up to 1 megagray (MGy) absorbed dose on silicon photonic devices. We do not find any systematic impact of radiation on passivated devices, indicating the durability of passivated silicon devices under harsh conditions.

Uranium removal from seawater by means of polymeric fabrics grafted with diallyl oxalate through a single-step, solvent-free process.

In order to test the effectiveness of oxalate-based polymeric adsorbents in the recovery of uranium from seawater, diallyl oxalate (DAOx) was grafted onto nylon 6 fabrics by exposing the fabric, immersed in pure liquid DAOx or in a surfactant-stabilized dispersion of DAOx in water, to electron beam or gamma radiation. Following drying and weighing to determine the degree of grafting (DoG), the presence of oxalate in the fabrics was verified using XPS. Zeta potential measurements showed the fabric surfaces to be negatively charged. The fabrics were tested by rotating them for 7 days in a rotary agitator with actual seawater spiked with 0.2 or 1.0 mg∙L-1 uranium. The fraction of uranium in the solution which was removed due to uptake on the fabrics was found to rise with increasing DoG at both uranium concentrations. EDS measurements were used to map the distribution of adsorbed uranium on the polymeric fibers.