ABSTRACT
Sustainable water management is essential to guaranteeing access to safe water and addressing the challenges posed by climate change, urbanization, and population growth. In a typical household, greywater, which includes everything but toilet waste, constitutes 50-80% of daily wastewater generation and is characterized by low organic strength and high volume. This can be an issue for large urban wastewater treatment plants designed for high-strength operations. Segregation of greywater at the source for decentralized wastewater treatment is therefore necessary for its proper management using separate treatment strategies. Greywater reuse may thus lead to increased resilience and adaptability of local water systems, reduction in transport costs, and achievement of fit-for-purpose reuse. After covering greywater characteristics, we present an overview of existing and upcoming technologies for greywater treatment. Biological treatment technologies, such as nature-based technologies, biofilm technologies, and membrane bioreactors (MBR), conjugate with physicochemical treatment methods, such as membrane filtration, sorption and ion exchange technologies, and ultraviolet (UV) disinfection, may be able to produce treated water within the allowable parameters for reuse. We also provide a novel way to tackle challenges like the demographic variance of greywater quality, lack of a legal framework for greywater management, monitoring and control systems, and the consumer perspective on greywater reuse. Finally, benefits, such as the potential water and energy savings and sustainable future of greywater reuse in an urban context, are discussed.
ABSTRACT
Noble metal nanoparticles are known to electrocatalyze various redox reactions by improving the electron transfer kinetics. In the present study, we have introduced a facile bioinspired synthesis of PtNPs and their integration for the formation of PtNPs/graphene nanocomposite using Psidium guajava (guava) leaves extract. Graphene used in nanocomposite formulation was synthesized by exfoliation of graphite in water/acetone (25:75 v/v) mixture followed by mechanical shearing using ultrasonication and microwave irradiation. PtNPs/graphene nanocomposite was drop-cast onto a glassy carbon electrode (GCE, 3 mm dia). The electrocatalytic activity of PtNPs/graphene nanocomposite was tested in a three-electrode system for sensing of metabolic products of dipyrone (DIP) formed through 1 e- and 2 e- transfer reactions. The modified electrode exhibited almost 50% reduction in electrode resistance. The limit of detection was found to be 0.142 µM with sensitivities of 0.820 and 0.445 µA⤵M-1cm-2 for DIP concentration below and above 100 µM, respectively, using square wave voltammetry. The signal of sensing of metabolites of DIP was almost invariant in the presence of glucose, dopamine, uric acid, and ciprofloxacin; however, the response current was decayed by 20% within the 10th cycle. The sensing of DIP spiked in treated sewage-water and running tap-water samples was â¼100% recoverable and comparable with HPLC.