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1.
Chem Commun (Camb) ; 51(46): 9511-4, 2015 Jun 11.
Article in English | MEDLINE | ID: mdl-25967276

ABSTRACT

Nanostructured Ni(x)Co(3-x)O4 films serve as effective electrocatalysts for both the oxygen reduction and oxygen evolution reactions in alkaline electrolyte.

2.
Chem Commun (Camb) ; 48(64): 7931-3, 2012 Aug 18.
Article in English | MEDLINE | ID: mdl-22763608

ABSTRACT

Graphene-like carbon-Ni-α-MnO(2) and -Cu-α-MnO(2) blends can serve as effective catalysts for the oxygen reduction reaction with activities comparable to Pt/C.

3.
ACS Nano ; 6(4): 3573-9, 2012 Apr 24.
Article in English | MEDLINE | ID: mdl-22404283

ABSTRACT

A simple and facile method to fabricate 3D graphene architectures is presented. Pyrolyzed photoresist films (PPF) can easily be patterned into a variety of 2D and 3D structures. We demonstrate how prestructured PPF can be chemically converted into hollow, interconnected 3D multilayered graphene structures having pore sizes around 500 nm. Electrodes formed from these structures exhibit excellent electrochemical properties including high surface area and steady-state mass transport profiles due to a unique combination of 3D pore structure and the intrinsic advantages of electron transport in graphene, which makes this material a promising candidate for microbattery and sensing applications.

4.
Chem Commun (Camb) ; 47(34): 9597-9, 2011 Sep 14.
Article in English | MEDLINE | ID: mdl-21805005

ABSTRACT

Nanoscale vanadium phosphides can serve as new high capacity anodes in alkaline aqueous electrolytes. Competing corrosion reaction(s) are mitigated with the novel use of an anion exchange membrane providing for capacities as high as 2800 mAh g(-1) @ 100 mA g(-1) discharge rate.

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