Emerging waste-to-wealth applications of fly ash for environmental remediation: A review.

The considerable increase in world energy consumption owing to rising global population, intercontinental transportation and industrialization has posed numerous environmental concerns. Particularly, in order to meet the required electricity supply, thermal power plants for electricity generation are widely used in many countries. However, an annually excessive quantity of waste fly ash up to 1 billion tones was globally discarded from the combustion of various carbon-containing feedstocks in thermoelectricity plants. About half of the industrially generated fly ash is dumped into landfills and hence causing soil and water contamination. Nonetheless, fly ash still contains many valuable components and possesses outstanding physicochemical properties. Utilizing waste fly ash for producing value-added products has gained significant interests. Therefore, in this work, we reviewed the current implementation of fly ash-derived materials, namely, zeolite and geopolymer as efficient adsorbents for the environmental treatment of flue gas and polluted water. Additionally, the usage of fly ash as a catalyst support for the photodegradation of organic pollutants and reforming processes for the corresponding wastewater remediation and H2 energy generation is thoroughly covered. In comparison with conventional carbon-based adsorbents, fly ash-derived geopolymer and zeolite materials reportedly exhibited greater heavy metal ions removal and reached the maximum adsorption capacity of about 150 mg g-1. As a support for biogas reforming process, fly ash could enhance the activity of Ni catalyst with 96% and 97% of CO2 and CH4 conversions, respectively.

Statistical analysis by using soft computing methods for seawater biodegradability using ZnO photocatalyst.

Water quality plays a significant role as a key factor in water resource management. The photocatalytic method is widely used for the removal of recalcitrant pollutants present in seawater. Photocatalysis is a cost-effective technology, sustainable, and environmentally friendly treatment process. In the current approach, a batch reactor was utilized experimentally to study the degradation of contaminants present in seawater by utilizing ZnO as a photocatalyst under natural sunlight. The performance of the process was studied by measuring the percentage removal efficiencies of total organic carbon (TOC), chemical oxygen demand (COD), biological oxygen demand (BOD), and biodegradability with respect to photocatalyst dosage, reaction time and pH of the solution. Biodegradability is defined as the ratio of BOD to COD and this parameter significantly removes pollutants from seawater. The higher the biodegradability, the better the performance of the treatment technology. It also significantly reduces the fouling characteristics of seawater during the desalination process. According to experimental values, the maximum percentage removal efficiencies were found to be TOC = 45.6, COD = 65.4, BOD = 20.01% and biodegradability = 0.038 with respect to the initial values of the seawater sample. The response surface methodology based on Box Behnken design (RSM-BBD) and a predictive model based on the MATLAB adaptive neuro-fuzzy inference system (ANFIS) tool were employed for modeling, optimizing, and evaluating the effects of parameters. According to the RSM-BBD and ANFIS models, the determination coefficients were R2 = 0.959 and R2 = 0.99, respectively, which was very close to 1. The maximum percentage removal efficiencies according to the RSM-BBD design were found to be TOC = 40.3; COD = 61.9; BOD = 18.8% and BOD/COD = 0.0390, whereas for the ANFIS model, the maximum reduction were found to be TOC = 46.5; COD = 65.4; BOD = 20.4% and BOD/COD = 0.040. In process optimization, the ANFIS model was shown better prediction than RSM-BBD in the process's optimization.

Microalgal-induced remediation of wastewaters loaded with organic and inorganic pollutants: An overview.

The recent surge in industrialization has intensified the accumulation of various types of organic and inorganic pollutants due to the illegal dumping of partially and/or untreated wastewater effluents in the environment. The pollutants emitted by several industries pose serious risk to the environment, animals and human beings. Management and diminution of these hazardous organic pollutants have become an incipient research interest. Traditional physiochemical methods are energy intensive and produce secondary pollutants. So, bioremediation via microalgae has appeared to be an eco-friendly and sustainable technique to curb the adverse effects of organic and inorganic contaminants because microalgae can degrade complex organic compounds and convert them into simpler and non-toxic substances without the release of secondary pollutants. Even some of the organic pollutants can be exploited by microalgae as a source of carbon in mixotrophic cultivation. Literature survey has revealed that use of the latest modification techniques for microalgae such as immobilization (on alginate, carrageena and agar), pigment-extraction, and pretreatment (with acids) have enhaced their bioremedial potential. Moreover, microalgal components i.e., biopolymers and extracellular polymeric substances (EPS) can potentially be exploited in the biosorption of pollutants. Though bioremediation of wastewaters by microalgae is quite well-studied realm but some aspects like structural and functional responses of microalgae toward pollutant derivatives/by-products (formed during biodegradation), use of genetic engineering to improve the tolerance of microalgae against higher concentrations of polluatans, and harvesting cost reduction, and monitoring of parameters at large-scale still need more focus. This review discusses the accumulation of different types of pollutants into the environment through various sources and the mechanisms used by microalgae to degrade commonly occurring organic and inorganic pollutants.

A review on the sustainable procurement of microalgal biomass from wastewaters for the production of biofuels.

The feasibility of microalgal biomass as one of the most promising and renewable sources for the production of biofuels is being studied extensively. Microalgal biomass can be cultivated under photoautotrophic, heterotrophic, photoheterotrophic, and mixotrophic cultivation conditions. Photoautotrophic cultivation is the most common way of microalgal biomass production. Under mixotrophic cultivation, microalgae can utilize both organic carbon and CO2 simultaneously. Mixotrophic cultivation depicts higher biomass productivity as compared to photoautotrophic cultivation. It is evident from the literature that mixotrophic cultivation yields higher quantities of polyunsaturated fatty acids as compared to that photoautotrophic cultivation. In this context, for economical biomass production, the organic carbon of industrial wastewaters can be valorized for the mixotrophic cultivation of microalgae. Following the way, contaminants' load of wastewaters can be reduced while concomitantly producing highly productive microalgal biomass. This review focuses on different aspects covering the sustainable cultivation of different microalgal species in different types of wastewaters.

Biorefining and biotechnology prospects of low-cost fish feed on Red tilapia production with different feeding regime.

This study aimed to decrease the production cost and increase tilapia yield with a feeding regime. The trial was divided into four treatments with three replications followed by the feeding frequency in monosex male Nile tilapia with an average initial weight of 17.86-18.40 g/fish cultured on a net cage in the earth pond for three months. Fish fed with 18% protein supplemented with 5% protein concentrate. The first month was used by 32% protein feed twice per day (T1, control), fish were fed twice per day every other week (T2), fish were fed twice per day per week (T3), and fish were fed twice per day per week (T3). Fish fed twice per day per week are now fed twice per day (T4). These results revealed that T2 fish had the highest growth performance and most protein consumption (P < 0.05). Moreover, fish in T2 has the lowest production cost and highest benefit-cost ratio (B/C ratio) (P < 0.05). The highest percentage of edible meat in T2 was P < 0.05, but the proximate analysis was close for all three groups (P > 0.05). As a result, it is necessary to ensure that Nile Tilapia culture has sufficient protein and nutrition control. This will allow for both high growth and low cost. Fish health and quality were positively affected by a perfect protein-containing feeding regimen. In fish fed with 18% protein and 5% protein concentrate for the first month, followed by 32% protein feed twice every other day and then with 18% protein.

Metanil Yellow dye adsorption using green and chemical mediated synthesized manganese ferrite: An insight into equilibrium, kinetics and thermodynamics.

Green Manganese Ferrite (GMF) and Chemical mediated Manganese Ferrite (CMF) were designed and prepared via in situ co-precipitation method and their adsorption potential was compared using the model dye, Metanil Yellow (MY). Previously, an extract of aquatic macrophyte and metal chloride were employed for the development of ecofriendly GMF. Alternatively, CMF has been synthesized through chemical co-precipitation from metal chloride precursors. Several characterization methods, including PSA, BET, TGA, DSC, FTIR, SEM, VSM, EDX, and XRD, were analyzed to reveal the structural and functional properties of the as-synthesized GMF and CMF. Their MY adsorption performances were tested as the function of the operational conditions such as initial solution pH, temperature, nanocomposite dosage, and dye concentration in a batch mode of operation. The pseudo-second order MY adsorption process fits best in Langmuir model which yielded the maximal monolayer adsorption capacity (qmax) of 391.34 mg/g for GMF and 271.89 mg/g for CMF. This outperformance of GMF over CMF was observed due to the augmentation of specified surface functional moieties derived from the phyto-constituents of macrophages. Further, the thermodynamic studies confirmed the chemisorptive and exothermic nature of adsorption processes. Conclusively, with the ease of regeneration and reuse potential, GMF and CMF could be viable contenders for scale up and industrial applications.

Assessment of single slope solar still using block and disc magnets via productivity, economic, and enviro-economic perspectives: a comparative study.

In this research, the productivity, economic, and enviro-economic analysis of single slope solar stills using block magnets (BMSS) and disc magnets (DMSS) were performed under the climatic conditions of Coimbatore city (latitude, 11° 01' 68″ N, and longitude, 76° 95' 58″ E), in India, 2019. The results observed in BMSS and DMSS were compared with conventional solar still (CSS) under the same climatic conditions. The usage of block and disc magnets in basin of solar still was improved the daily productivity significantly. The results showed that the performance observed in BMSS was notably higher than the performance of DMSS. The hourly productivity in BMSS was 5.8% and 13.7% higher when compared to DMSS and CSS, respectively. The cumulative productivity in BMSS, DMSS, and CSS were found to be about 3.15 kg/m2, 2.82 kg/m2, and 2.15 kg/m2, respectively, for 12h observations. In economic analysis, the estimated payback period (PBP) of BMSS, DMSS, and CSS were about 3.6 months, 3.5 months, and 4.5 months, respectively. Furthermore, the CO2 emission of BMSS, DMSS, and CSS were observed to be about 11.04 tons, 9.37 tons, and 6.45 tons, respectively. The overall observations showed that the magnetization of saline water has significantly improved the solar still performances.

Recent Progress in Nanomaterials Modified Electrochemical Biosensors for the Detection of MicroRNA.

MicroRNAs (miRNAs) are important non-coding, single-stranded RNAs possessing crucial regulating roles in human body. Therefore, miRNAs have received extensive attention from various disciplines as the aberrant expression of miRNAs are tightly related to different types of diseases. Furthermore, the exceptional stability of miRNAs has presented them as biomarker with high specificity and sensitivity. However, small size, high sequence similarity, low abundance of miRNAs impose difficulty in their detection. Hence, it is of utmost importance to develop accurate and sensitive method for miRNA biosensing. Electrochemical biosensors have been demonstrated as promising solution for miRNA detection as they are highly sensitive, facile, and low-cost with ease of miniaturization. The incorporation of nanomaterials to electrochemical biosensor offers excellent prospects for converting biological recognition events to electronic signal for the development of biosensing platform with desired sensing properties due to their unique properties. This review introduces the signal amplification strategies employed in miRNA electrochemical biosensor and presents the feasibility of different strategies. The recent advances in nanomaterial-based electrochemical biosensor for the detection of miRNA were also discussed and summarized based on different types of miRNAs, opening new approaches in biological analysis and early disease diagnosis. Lastly, the challenges and future prospects are discussed.