Photochromic Diarylethenes Designed for Surface Deposition: From Self-Assembled Monolayers to Single Molecules.

The efficient switching that can occur between two stable isomers of diarylethenes makes them particularly promising targets for opto- and molecular electronics. To examine these classes of molecules for electronics applications, they have been subjected to a series of scanning tunneling microscopy (STM) experiments, which are the focus of this Review. A brief introduction to the chemical design of diarylethenes in terms of their switching capabilities along with the basics of STM are presented. Next, initial STM studies on these compounds under ambient conditions are discussed. An overview of how molecular design affects the isomerization and self-assembly of diarylethenes at the solid-liquid interface as investigated by STM is then presented, as well as single-molecule studies under ultrahigh vacuum. The last section presents further prospects for molecular design in the field.

Terarylenes as Photoactivatable Hydride Donors.

Terarylene frameworks containing benzothiazole as a photoprecursor of hydride donors are presented. We here report on two new scaffolds along with their photoreactivity in solution. Through use of selected external oxidants, the photogeneration of hydride donors is monitored using UV-visible, NMR, and TEM methods. As a proof-of-concept, photogeneration of hydride in the presence of Ag+ gave rise to the formation of Ag nanoparticles.