ABSTRACT
The urgent demand for atomically thin, superlubricating, and super wear-resistant materials in micro/nanoelectromechanical systems has stimulated the research of friction-reducing and antiwear materials. However, the fabrication of subnanometer-thick films with superlubricating and super wear-resistant properties under ambient conditions remains a huge challenge. Herein, high-quality monolayer (ML) NbSe2 (â¼0.8 nm) with ultralow friction and super wear resistance in an atmospheric environment was successfully grown by chemical vapor deposition (CVD) for the first time. Moreover, compared with few-layered (FL) NbSe2, ML NbSe2 has a lower friction coefficient and better wear resistance. On the basis of density function theory (DFT) calculations, the adhesion and the degree of charge transfer between ML NbSe2 and the substrate is larger than that of the topmost layer to the underlying layers of NbSe2 with two or more layers, which can be used to explain that the ML NbSe2 favors ultralow friction and super wear resistance.
ABSTRACT
Liquid superlubricity has attracted much attention, due to its ability to significantly reduce friction on the macroscale. However, the severe wear caused by the long running-in period is still one of the bottlenecks restricting the practical application of liquid superlubricating materials. In this work, the obtained polyethylene glycol-phytic acid (PEG-PA) composite liquid lubricants showed outstanding superlubricating properties (µ ≈ 0.006) for Si3N4/glass friction pairs with an ultrashort running-in period (â¼1 s) under high Hertzian contact pressure of â¼758 MPa. More importantly, even after up to 12 h (â¼700 m of travel), only about 100 nm deep wear scars were found on the surface of the glass sheet (wear rate = 2.51× 10-9 mm3 N-1 m-1). From the molecular point of view, the water molecules anchored between the two friction pairs have extremely low shear force during the friction process, and the strong hydrogen bond interaction between PEG and PA greatly improves the bearing capacity of the lubricant. This work addresses the challenge of liquid superlubricant simultaneously exhibiting low shear force and high load-carrying capacity and makes it possible to obtain liquid superlubrication performance with an extremely short running-in time.
ABSTRACT
Intelligent and highly precise control of liquid-solid triboelectricity is of great significance for energy collection and electrostatic prevention. However, most of the traditional methods are irreversible and complex, greatly limiting their applicability. Here, a reversible thermosensitive liquid-solid triboelectric nanogenerator (L-S TENG) is assembled based on P(NIPAM-MMA) (PNM) copolymer for tunable triboelectrification. Through temperature regulation, the conformation between acylamino and isopropyl groups changes with the interfacial wettability and triboelectricity of PNM. When the temperature rises from 20 to 60 °C, the contact angle of PNM rises from 22.49° to 82.08°, and the output of the PNM-based L-S TENG shows a 27-fold increase. In addition, this transformation is reversible and repeatable with excellent durability for up to 60 days. Other organic liquids, such as glycol, exhibit positive response to temperature for this PNM-based L-S TENG. Polymers including polymethylmethacrylic, polytetrafluoroethylene, and polyimide are verified to not have such thermo-sensitivity properties. In addition, a droplet-based wireless warning system based on PNM is designed and actuated for monitoring specific temperature. The introduction of thermal PNM not only provides new material for reversible manipulation of L-S TENG, but also provides a new method for designing highly sensitive temperature warning sensors.
